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Efficient arsenic removal method for sewage of sulfuric acid workshop

A sewage and workshop technology, applied in water/sewage treatment, multi-stage water/sewage treatment, oxidized water/sewage treatment, etc., can solve the problems of poor arsenic removal effect and long treatment time in sewage, and solve the problem of suspended floc objects, improve processing speed, and improve the effect of removal effect

Inactive Publication Date: 2017-05-24
铜陵铜冠环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to solve the problems in the prior art that the effect of removing arsenic from sewage is not good and the treatment time is long, and to provide a method for removing arsenic from sewage in a sulfuric acid workshop

Method used

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  • Efficient arsenic removal method for sewage of sulfuric acid workshop

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Embodiment 1

[0017] Embodiment 1, a high-efficiency arsenic removal method for sulfuric acid workshop sewage, comprising the following steps:

[0018] Step 1. Introduce sewage into a section of reaction pool, and add Na to the section of reaction pool 2 The S solution carries out arsenic precipitation once, and the pH value of the sewage is adjusted to be 2, and the time is 45 minutes, and the Na 2 The concentration of S solution is 0.0056g / ml;

[0019] Step 2. After press filtration, filtrate and washing, the sewage in the first-stage reaction pool is introduced into the second-stage reaction pool, and Na is added to the second-stage reaction pool. 2 The S solution carries out secondary arsenic precipitation, and the pH value of the sewage is adjusted to be 2, and the time is 10 minutes, and the Na 2 The concentration of S solution is 0.056g / ml;

[0020] Step 3, introducing the sewage in the second-stage reaction pool into the third-stage reaction pool after pressure filtration, filtra...

Embodiment 2

[0024] Embodiment 2, a method for efficiently removing arsenic from sulfuric acid workshop sewage, comprising the following steps:

[0025] Step 1. Introduce sewage into a section of reaction pool, and add Na to the section of reaction pool 2 The S solution carries out arsenic precipitation once, and the pH value of the sewage is adjusted to be 2, and the time is 50 minutes, and the Na 2 The concentration of S solution is 0.0058g / ml;

[0026] Step 2. After press filtration, filtrate and washing, the sewage in the first-stage reaction pool is introduced into the second-stage reaction pool, and Na is added to the second-stage reaction pool. 2 The S solution carries out secondary arsenic precipitation, and the pH value of the sewage is adjusted to be 2, and the time is 15 minutes, and the Na 2 The concentration of S solution is 0.058g / ml;

[0027] Step 3, introducing the sewage in the second-stage reaction pool into the third-stage reaction pool after pressure filtration, filt...

Embodiment 3

[0033] Embodiment 3, a method for efficiently removing arsenic from sulfuric acid workshop sewage, comprising the following steps:

[0034] Step 1. Introduce sewage into a section of reaction pool, and add Na to the section of reaction pool 2 The S solution carries out arsenic precipitation once, and the pH value of the sewage is adjusted to be 2, and the time is 47 minutes, and the Na 2 The concentration of S solution is 0.0057g / ml;

[0035] Step 2. After press filtration, filtrate and washing, the sewage in the first-stage reaction pool is introduced into the second-stage reaction pool, and Na is added to the second-stage reaction pool. 2 The S solution carried out secondary arsenic precipitation, and the pH value of the sewage was adjusted to be 2, and the time was 12 minutes, and the Na 2 The concentration of S solution is 0.057g / ml;

[0036] Step 3, introducing the sewage in the second-stage reaction pool into the third-stage reaction pool after pressure filtration, fi...

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Abstract

The invention discloses an efficient arsenic removal method for sewage of a sulfuric acid workshop. By adopting the efficient arsenic removal method disclosed by the invention, arsenic in sewage discharged from the sulfuric acid workshop can be rapidly and effectively removed, so that the treatment speed can be effectively increased; and meanwhile, the problem of suspended floccules can be solved, so that the removal effect can be improved. The efficient arsenic removal method is efficient and energy-saving, and zero emission is achieved; and meanwhile, byproducts can be generated in the removal process, and thus the cost can be effectively lowered.

Description

technical field [0001] The invention relates to the field of industrial wastewater treatment, in particular to a method for quickly and efficiently removing arsenic from sulfuric acid workshop sewage. Background technique [0002] The waste water of the sewage station mainly comes from the sulfuric acid workshop, with high acidity, the pH of the waste water is between 1 and 2, the mass concentration of sulfuric acid is between 0.49g / L and 4.9 g / L, and the arsenic in it is mainly arsenous acid. Most of the existing treatment methods use sodium sulfide lime precipitation to remove arsenic. The sewage is directly added with sodium sulfide for a precipitation and lime neutralization. The requirements for the arsenic content of external drainage in the Waste Discharge Standard. In recent years, sodium sulfide-lime and iron salts have also been used to remove arsenic, but when treating sewage, a large amount of reddish-brown suspended flocs will be continuously rolled, and a laye...

Claims

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Application Information

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IPC IPC(8): C02F9/04
CPCC02F9/00C02F1/001C02F1/281C02F1/5236C02F1/5245C02F1/56C02F1/72C02F2301/08
Inventor 戴正亮唐雁宋晓轩
Owner 铜陵铜冠环保科技有限公司