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1083results about How to "Improve removal effect" patented technology

A global optimization method for ultra-low emission multi-pollutant cooperative removal system

The invention relates to a global optimization method of an ultra-low emission multi-pollutant cooperative removal system, which obtains an accurate description of a multi-pollutant generation, migration, conversion and removal process in a multi-device through an accurate modeling of a multi-device multi-pollutant cooperative removal process in an ultra-low emission system. The multi-pollutant emission reduction cost under different load, coal quality, pollutant concentration and operation parameters is evaluated accurately by the global operation cost evaluation method in ultra-low emissionsystem. Minute-level planning and optimization of emission reduction of global pollution reduction devices under different emission targets are realized by global operation optimization method of multi-pollutant multi-objective and multi-operating conditions. Reliable emission reduction and side-by-side control of pollutants are ensured through advanced control methods with low emission and multi-pollutant emission meeting the standards reliably. The invention innovates the modeling, optimization and control method of the ultra-low emission system from the aspects of model, architecture and algorithm, improves the controllability and adjustability of the system, and guides the efficient, reliable and economic operation of the ultra-low emission system.
Owner:ZHEJIANG UNIV

Gas outburst spinning dive desulfurization dust cleaning apparatus

The invention discloses a gas outburst cyclone desulfurization dust removal device, comprising a cooling defluorination device, a desulfuration absorbing tower and a defogger. The flue gas containing SO2 is first introduced into the cooling defluorination device to be eliminated most of HF gas by the sprayed alkaline liquor spray and fresh water, and the temperature is then reduced to below 80 DEG C. The cooled defluorination flue gas is sent into the desulfuration absorbing tower; after obtaining strong rotating momentum in a cyclone gas outburst pipe with a cyclone device, the flue gas is dashed into a slurry pond in tangential direction of the vents at the bottom of the pipe; the optimally distributed array form enhances the effect of rotary gas spraying into slurry liquid, strengthens the process of gas and liquid transformation, improves efficiency of desulfurization dust removal and reduces resistance loss. The flue gas after purification is emitted out after a multi-pipe cyclone centrifugal defogger. The gas outburst cyclone desulfurization dust removal device can realize efficiency of desulfurization above 95 percent and dust removal efficiency of higher than 90 percent, which can be used in purification process of flue gas in power plant, sintering smoke and other gases containing SO2.
Owner:BAOSHAN IRON & STEEL CO LTD +1

Preparation method of adsorbent for purifying hydrogen sulfide, hydrogen phosphide and arsenic hydride simultaneously

The invention relates to a preparation method of an adsorbent for purifying hydrogen sulfide, hydrogen phosphide and arsenic hydride simultaneously, and belongs to the technical field of adsorbent preparation. The method comprises the steps that P123 or F127 is dissolved in a dilute acid solution and stirred till being dissolved, a certain number of pore-enlarging agents are added, stirring and even mixing are carried out, ethyl orthosilicate is added, the mixture is poured into a reaction kettle after being stirred for 1-6 h, powder obtained after crystallization is washed with distilled water till the color of test paper is not changed, the dry powder obtained after drying is placed into a roaster to be roasted, temperature is naturally decreased to indoor temperature, an adsorbent carrier is obtained, the obtained carrier is dissolved in water, a certain amount of metal salt is added, filtering, drying and roasting are carried out, and then the large-aperture adsorbent is obtained. The preparation method is easy to implement, the metal salt impregnant is low in cost and easy to obtain, the desorption effect is good even at low temperature, and a wide development prospect is provided for simultaneous desulfurization, dephosphorization and dearsenization through a dry method.
Owner:KUNMING UNIV OF SCI & TECH

Ultrahigh cross-linked macro-porous adsorption resin applicable to removal of patulin

ActiveCN103772573ADense channelsUnique Pore Size DistributionIon-exchange process apparatusOther chemical processesCross-linkFunctional monomer
The invention provides ultrahigh cross-linked macro-porous adsorption resin which is obtained by taking a styrene monomer as a functional monomer, taking a multi-vinyl monomer as a cross-linking agent, suspending and polymerizing in the presence of a pore forming agent to obtain low-cross-linked macro-porous polystyrene white ball, reacting the obtained white ball with chloromethyl ether under the catalysis of lewis acid to obtain chloromethylation macro-porous polystyrene resin, and carrying out a Friedel-Crafts alkylation reaction on the obtained chloromethylation macro-porous polystyrene resin in the presence of a swelling agent by taking the lewis acid as a catalyst. Through adopting a novel cross-linking agent and pore forming agent system, the obtained resin has the advantages of high specific surface area and uniform pore diameter; the specific surface area is up to 1500-1800m<2> / g, the pore diameter distribution is uniform, a pore channel is dense and the average pore diameter is small; the pore diameter of the obtained macro-porous resin is rightly applicable to removal of patulin in juice and the removing efficiency is high; the resin can be used for pointedly removing the patulin which stably exists in the juice and the potential hazards on the human health, caused by the patulin in the juice, are solved; the ultrahigh cross-linked macro-porous adsorption resin has great social and economic benefits.
Owner:AMICOGEN CHINA BIOPHARM CO LTD

Preparation method of rare earth element modified and aldehyde removed resin and application of rare earth element modified and aldehyde removed resin in ethylene glycol refining

The invention relates to a preparation method of rare earth element modified and aldehyde removed resin and an application of the rare earth element modified and aldehyde removed resin in ethylene glycol refining. According to the preparation method, styrene is taken as a monomer, divinylbenzene is taken as a crosslinking agent, benzoyl peroxide is taken as an initiator, polyvinyl alcohol is taken as a suspending agent, water is taken as a reaction medium, and the components react in a suspension polymerization manner at the temperature of 85-95 DEG C; a polymer obtained after reaction is dissolved in dichloroethane for swelling, sulfuric acid is added for a sulfonation reaction, and cation exchange resin is obtained; and a nitric acid solution of the rare earth element is added into the cation exchange resin, and the rare earth element is chemically bonded to the resin to obtain the spherical modified and aldehyde removed resin. A fixed bed reactor is filled with the aldehyde removed resin, ethylene glycol is refined at the temperature of 60-70 DEG C, the density of a resin packing layer heap is 400-600 kg / m<3>, the reaction pressure is 0.4 MPa, under the catalytic action of the modified and aldehyde removed resin, impurity aldehyde and ethylene glycol have a condensation polymerization reaction and produce a product that does not influence an ethylene glycol product, and obtained ethylene glycol has high purity.
Owner:JIANGSU SUQING WATER TREATMENT ENG GROUP +1

Device for integrating ultra-clean emission, desulfurization, denitrification and dedusting of flue gas and process of device

InactiveCN106237814AOvercome the serious problem of escapingPromote oxidationDispersed particle separationFlue gasEmission standard
The invention discloses a device for integrating ultra-clean emission, desulfurization, denitrification and dedusting of flue gas, and a process of the device. The device comprises a tower body, wherein a flue gas inlet and a flue gas outlet are formed in the tower body; the flue gas inlet is formed in a lower side wall of the tower body; the flue gas outlet is formed in the top of the tower body; the device comprises a slurry pool, a desulfurization layer, an oxidation layer, a denitrification layer and a wet electrostatic precipitator from the tower bottom to top sequentially; the flue gas enters the tower body from the flue gas inlet, and is subjected to the desulfurization of a lower spraying layer, the oxidation of a middle oxidation layer, the denitrification of an upper spraying layer and the dedusting of the wet electrostatic precipitator sequentially, so that the flue gas at the outlet reaches ultra-clean emission standards of the flue gas. In the invention, ClO2 is used as an oxidant for oxidizing NO, and MgOH is used as a desulfurization and denitrification agent, to overcome the shortcomings of complicated structure and poor removal effect of a traditional desulfurization and denitrification device; fine particles in the flue gas can be removed in the same device in order by adopting a mode of mounting the wet electrostatic precipitator at the tower top, so as to effectively prevent the formation of 'gypsum rain' and improve the purification efficiency of the flue gas.
Owner:SHANDONG TIANLI DRYING TECH & EQUIP

Efficient multi-field-coordination fine particulate matter removal device and method

The invention discloses an efficient multi-field-coordination fine particulate matter removal device and an efficient multi-field-coordination fine particulate matter removal method. The device comprises an outer field coagulation area, a direct current dust pre-collecting area, a pulse charge coagulation area and a direct current dust collecting area which are connected in sequence, wherein water steam and a chemical agglomeration agent are introduced from a nozzle of the outer field coagulation area respectively; the direct current dust pre-collecting area and the direct current dust collecting area are arranged in a line-plate type symmetric structure, a line electrode applies negative direct current high voltage, and a plate electrode is grounded and adopts layout of a water film electrode; the pulse charge coagulation area is arranged in the line-plate type symmetric structure, the line electrode applies positive pulse high voltage, and the plate electrode is grounded and adopts layout of the water film electrode. The device and the method aim at mineral particulate matters discharged by a fixed source; aerosol particulate matters, particularly fine particulate matters, can be subjected to efficient coagulation removal in a structural form of double coagulation areas and double dust collecting areas by using a multi-field-coordination method combined by a phase-change coagulation growth technology, a chemical agglomeration and flocculation mechanism and an electric coagulation technology, so that the phenomena of back corona, re-entrainment of dust, ash deposition and corrosion of the plate electrode are effectively avoided.
Owner:ZHEJIANG UNIV

Treatment method for mixed organic waste gas containing chlorine, hydrogen chloride and oxynitride

The invention discloses a treatment method for mixed organic waste gas containing chlorine, hydrogen chloride and oxynitride. The method is capable of not only achieving a favorable removal effect on oxynitride, but also achieving a favorable removal effect on chlorine. A condensation unit, an absorbing unit and an adsorption unit are adopted in the treatment method, wherein the condensation unit adopts one-grade condensation; the absorbing unit adopts four-grade absorption; the absorption unit adopts two-grade absorption; waste gas firstly passes through a cooler and a demister of the condensation unit, so that VOCs with relatively high boiling points in the waste gas are cooled as much as possible and then recycled; then the waste gas enters into an aqueous urea solution absorption tower of the absorbing unit, and nitric oxides and chlorine in the waste gas are completely oxidized, reduced, decomposed and absorbed by virtue of a catalytic absorption reaction, so that nitrogen and chlorine are removed; the waste gas with nitrogen and chlorine removal enters into an aqueous falling film solution absorption tower of the absorbing unit, so that by-product hydrochloric acid is obtained; finally, the residual waste gas passes through an absorption tower of the absorption unit, so that the residual VOCs are adsorbed, and thus up-to-standard release is achieved.
Owner:NANJING TECH UNIV

Method of treating hexavalent chromium wastewater by immobilized microorganisms

The invention discloses a method of treating hexavalent chromium wastewater by immobilized microorganisms. The method aims at solving the problem that the human health is affected as the environment is severely polluted by the hexavalent chromium wastewater. The method comprises the following steps: a step I of preparing immobilized microorganism particles and a step II of treating wastewater, wherein in the step I, a microbial agent is dissolved into a sodium alginate solution, an additive is added to form a mixed solution, then the mixed solution is added into a calcium chloride solution to obtain embedded particles, and the embedded particles are stewed and immobilized, and washed by normal saline to obtain the immobilized microorganism particles. According to the method of treating hexavalent chromium wastewater by immobilized microorganisms disclosed by the invention, by selecting and matching the additive and a culture medium, the treatment effects and treatment efficiency of the hexavalent chromium wastewater can be greatly improved to meet the needs of industrially treating the hexavalent chromium wastewater. The method of treating hexavalent chromium wastewater by immobilized microorganisms has the advantages of low cost, small equipment investment, convenience in operation, and the like, has a wide market prospect and a high application value, and is worthy of being popularized and applied on a large scale.
Owner:SOUTHWEAT UNIV OF SCI & TECH

Desulfurization and denitrification process utilizing microwave to intermittently irradiate activated carbon

Disclosed is a desulfurization and denitrification process utilizing microwave to intermittently irradiate activated carbon. Two or more adsorption beds filled with activated carbon particles are used for adsorbing or implementing microwave irradiation to flue gas of boilers alternatively. Flue gas is delivered into one of the adsorption beds by an induced draft fan, then the adsorption bed begins to run, and sulfur and nitric oxides in the flue gas are adsorbed by the activated carbon. After the activated carbon in the adsorption bed in running is saturated, the adsorption bed is in a regenerating state so as to be reused. The flue gas is delivered into the other adsorption bed beginning to run so as to be adsorbed, activated carbon particles of the regenerating adsorption bed are irradiated by microwave, sulfur and nitric oxides adsorbed on the surface of the activated carbon are quickly reduced and decomposed into elemental sulfur and nitrogen gas under high temperature, and the different adsorption beds are switched between the running state and the regenerating stage alternatively. Metal oxide is used as a reduction reaction catalyst so as to reduce reduction and decomposition temperature and loss of carbon. By the desulfurization and denitrification process, energy consumption of microwave irradiation can be reduced greatly, loss of carbon can be decreased, and in-situ regeneration of activated carbon is realized. In addition, the desulfurization and denitrification process has the advantages of fine desulfurization and denitrification effect, short time for regeneration of activated carbon, low cost for desulfurization and denitrification, high recovery rate, easiness in industrialized implementing and the like.
Owner:NORTH CHINA ELECTRIC POWER UNIV (BAODING)

Method and device for treating high-concentration nonbiodegradable organic wastewater

The invention discloses a method and device for treating high-concentration nonbiodegradable organic wastewater. The method comprises the following steps: (1) adjusting pH (Potential of Hydrogen) of the wastewater to be 3; (2) feeding the adjusted wastewater into an Fenton reactor, and simultaneously adding an Fenton agent to perform Fenton reaction; (3) enabling the wastewater containing the Fenton agent to flow through an electric flocculation device; continuously performing Fenton reaction under the effect of a pulsed power electric field, and simultaneously performing electrochemical reaction and electric catalytic oxidation reaction, in order to further degrade organic matters in the wastewater as well as generate flocculates and precipitates; scrapping the flocculates through a slag scraper in an air flotation area of the electric flocculation device; and (4) enabling the wastewater with the precipitates to flow into a precipitation tank, adjusting the pH to be 7 to 8, and then removing the precipitated wastewater from the precipitation tank. Compared with the prior art, the method for treating the high-concentration nonbiodegradable organic wastewater, disclosed by the invention, can improve the removal efficiency of nonbiodegradable organic pollutants.
Owner:SICHUAN KAIWO ENVIRONMENTAL PROTECTION TECHCO

Hollow fiber compound nanofiltration membrane and preparation method thereof

The invention relates to a hollow fiber compound nanofiltration membrane. The nanofiltration membrane takes a porous supporting layer as an inner layer and a separating function layer as an outer layer. A casting membrane solution of the porous supporting layer contains an inner layer macromolecular polymer which is selected from one or more of polysulfone, polyether sulfone, polyvinylidene fluoride, polyvinyl chloride and polyacrylonitrile; a casting membrane solution of the separating function layer contains an outer layer macromolecular polymer which is selected from one or more of polyetherimide, polyether-ether-ketone, sulfonated polyether-ether-ketone, polymethyl methacrylate and polyvinyl alcohol; a preparation method comprises the following steps: synchronously extruding and molding the inner layer casting membrane solution and the outer layer casting membrane solution; solidifying to obtain a membrane filament in a nascent state; and carrying out an oxidizing agent aqueous solution to obtain the hollow fiber compound nanofiltration membrane. The invention further provides the preparation method of the nanofiltration membrane correspondingly. According to the hollow fiber compound nanofiltration membrane provided by the invention, the flux of the nanofiltration membrane is remarkably improved, and moreover, the nanofiltration membrane further has the certain desalinization rate.
Owner:HUNAN OVAY TECH CO LTD

Method and apparatus for removing sulfur dioxide from sulfuric acid industrial tail gas, and for recovering sulfuric acid

The invention relates to the methods and apparatuses for treating sulfuric acid industrial tail gas, and discloses a method and an apparatus for removing sulfur dioxide from sulfuric acid industrial tail gas, and for recovering sulfuric acid. The method comprises the steps that: sulfur dioxide in flowing sulfuric acid industrial tail gas is removed in an absorption tower by using a hydrogen peroxide solution, and sulfuric acid is recovered. The apparatus comprises an absorption tower, a spraying apparatus and a demister. The spraying apparatus comprises a circulating pump, a metering pump, a hydrogen peroxide storing tank and a sprayer. The absorption tower is provided with a gas inlet and a gas outlet. The following components are sequentially arranged in the absorption tower from bottom to top: a collecting tank, a gas distributing plate, a diluted-acid-resisting filling material, the sprayer, and the demister. A circulating port and a liquid discharging port are arranged on the bottom of the collecting tank. The circulating port communicates with the sprayer through the circulating pump. A valve is arranged on the liquid discharging port. The hydrogen peroxide storing tank communicates with a liquid inlet port of the circulating pump through the metering pump. According to the invention, effect for removing sulfur dioxide from sulfuric acid industrial tail gas is good, sulfur can be recovered and reused, production cost of sulfuric acid is reduced, and secondary pollution is avoided. The apparatus has advantages of simple structure, easy operation, low investment and low operation cost.
Owner:威海恒邦化工有限公司
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