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34results about How to "Strong conversion rate" patented technology

Polyformaldehyde dimethyl ether synthesis method

The invention relates to a polyformaldehyde dimethyl ether synthesis method which mainly solves the problems of difficult catalyst separation, low raw material conversion rate and poor product selectivity in the prior art. The technical scheme of the polyformaldehyde dimethyl ether synthesis method comprises the following steps: by taking methanol, methylal and polyformaldehyde as raw materials, under the conditions that the reaction temperature is 70-200 DEG C and the reaction pressure is 0.2-6 MPa, enabling the raw materials to be in contact with a catalyst, and reacting to generate polyformaldehyde dimethyl ether, wherein the weight ratio of the methanol, the methylal and the polyformaldehyde is (0-10):(0-10):1, and the amounts of the methanol and the methylal can not be 0 at the same time; the amount of the catalyst accounts for 0.1-5.0% of the weight of the raw materials; and the used catalyst comprises the following components in parts by weight: a) 30-80 parts of carrier, which is at least one selected from SBA-15, MCM-41 or MCM-22 molecular sieve, and b) 20-70 parts of solid super-strong acid carried thereon, which is at least one selected from SO4<2->/ZrO2, SO4<2->/Fe2O3, Cl<->/TiO2 or Cl<->/Fe2O3. Thus, the problems are well solved; and the polyformaldehyde dimethyl ether synthesis method can be used for industrial production of polyformaldehyde dimethyl ether.
Owner:CHINA PETROLEUM & CHEM CORP +1

Preparation method of rhodium-ruthenium composite catalyst for preparing ethyl alcohol through acetic acid hydrogenation

The invention provides a preparation method of a rhodium-ruthenium composite catalyst for preparing ethyl alcohol through acetic acid hydrogenation. According to the method, rhodium and ruthenium or oxide thereof is adopted as a main catalyst, metal or oxide thereof is adopted as a promoter, and any one or more of silicon dioxide, aluminum oxide, titanium dioxide, cerium dioxide, zirconium dioxide and silicon carbide are adopted as carriers. The preparation method is a deposition-precipitation method and includes the steps that an alkaline solution is dropwise added into a mixed solution prepared from rhodium, ruthenium and M salt, precipitates are formed, the carriers are added into the solution, and precipitation substances are adsorbed on the carriers after the materials are evenly stirred for a period of time; filtering and washing are carried out to filter out impurities; drying and calcining are carried out, and supported metal oxide is obtained. A hydrogenation reaction is carried out in a tubular fixed bed reactor, firstly, the catalyst is reduced in the reducing atmosphere, and then the high conversion rate and selectivity are obtained by controlling the reaction temperature and pressure, the volume air speed, the hydrogen-acid ratio and other parameters. The preparation method is simple, high repeatability is achieved, and the catalytic effect is high.
Owner:ZHONGRONG TECH CORP LTD

Organic liquid material for hydrogen storage, catalytic hydrogen storage system and hydrogen storage method

PendingCN114497630AIncreased theoretical hydrogen storage capacityImprove liquidityReactant parameters controlDibenzyltoluenePtru catalyst
The invention discloses an organic liquid material for hydrogen storage, a catalytic hydrogen storage system and a hydrogen storage method.The organic liquid material is composed of a hydrogen storage raw material A and a hydrogen storage raw material B. The hydrogen storage raw material A is one or two of benzyl toluene and dibenzyl toluene, the mass content of the dibenzyl toluene is not larger than 80%, and the mass content of the hydrogen storage raw material B is not larger than 80%. The hydrogen storage raw material B is one or more of naphthalene, 1-methylnaphthalene and 2-methylnaphthalene. The catalytic hydrogen storage system comprises an organic liquid material for hydrogen storage and a hydrogen storage reaction catalyst, and the hydrogen storage reaction catalyst is a supported metal catalyst and comprises a catalyst carrier and a catalyst active metal component. The invention solves the problem of lack of hydrogen storage technology based on organic liquid materials in the technical field at present, and has the advantages of low raw material cost, large scale, low-temperature liquid property, low catalyst cost in the hydrogen storage process, large hydrogen storage capacity, relatively mild hydrogen storage conditions and the like.
Owner:DONGFANG HONGSHENG NEW ENERGY APPL TECH RES INST

Denitration catalyst with low SO2/SO3 conversion rate and preparation method thereof

The invention relates to the technical field of selective catalytic reduction catalysts, in particular to a denitration catalyst with a low SO2/SO3 conversion rate and a preparation method thereof. The preparation method comprises the following steps of putting a metal nitrate, glycine and an inorganic salt auxiliary in a solvent, conducting stirring for dissolution, and conducting calcination to obtain a powder A; dipping titanium dioxide in a mixed solution of ammonium metavanadate and ammonium heptamolybdate, conducting stirring and dissolving, and conducting calcining to obtain a powder B; and mixing the powder A and the powder B, and performing high-shear dispersion to obtain the denitration catalyst. The metal oxide is prepared by adopting a glycine combustion method, and the prepared metal oxide is small in particle size, uniform in particle size distribution, multiple in pore channels, high in adsorption capacity and capable of adsorbing SO2 and SO3 on the catalyst in the SCR reaction process, so that the SO2/SO3 conversion rate of the catalyst is reduced; and the powder A and the powder B can be highly and uniformly mixed under the actions of centrifugal extrusion, high-speed cutting, impacting, grinding and the like generated in the high-shear dispersion process, so that the high denitration activity of the catalyst is guaranteed.
Owner:DATANG NANJING ENVIRONMENTAL PROTECTION TECH

Composite solid super acidic catalyst, preparation method thereof and method for catalytically synthesizing N,N-diethylaniline by using solid super acidic catalyst

The invention discloses a composite solid super acidic catalyst, a preparation method thereof and a method for catalytically synthesizing N,N-diethylaniline by using the solid super acidic catalyst. The composite solid super acidic catalyst is composed of a composite carrier CeO2-WO3-ZrO2 and SO4<2-> supported on the surface; the preparation comprises the following steps: preparing a precursor ofthe carrier, placing the precursor into a (NH4)2SO4 solution for immersion, performing drying, and performing calcination to obtain the super acidic catalyst; and the method for catalytically synthesizing the N,N-diethylaniline by adopting the catalyst comprises the following steps: putting the solid super acidic catalyst into a fixed bed tubular reactor, adding a mixed solution of aniline and ethanol, and performing a reaction to obtain the N,N-diethylaniline. The solid super acidic catalyst provided by the invention has strong acidity and a high acid center density, and the presence of oxygen vacancies can enhance activity of the catalyst; at the same time, the preparation method is simple and convenient, and has strong operability; and according to the N,N-diethylaniline catalytically synthesized by adopting the catalyst, the conversion rate of aniline is higher, and the selectivity of the N,N-diethylaniline is higher.
Owner:NANJING NORMAL UNIVERSITY

Novel efficient, healthy and safe feed for breeding pigeons

The invention belongs to the technical field of feeds, and particularly relates to a novel efficient, healthy and safe feed for breeding pigeons. The novel efficient, healthy and safe feed comprises the following raw materials in percentage by mass: 65%-70% of an energy feed, 25%-30% of a protein feed, 2% of a mineral feed, 1% of a trace element feed, 1% of a vitamin feed and 1% of a health-care preparation feed. According to the growth demand characteristics of the breeding pigeons and meat pigeons, a corresponding feed formula is provided. Components of the feed formula are common feeds, sothat the cost is low, the purchase is convenient, and the feed conversion rate is high. Health-care preparation for preventing the breeding pigeons from getting sick is pertinently added, so that thediseases easily occurring in the growth process of the breeding pigeons are effectively prevented, the survival rate of the breeding pigeons and the meat pigeons is greatly increased, and the yield ofthe meat pigeons is increased. The feed is fully cured through high-temperature tempering and fully matured, so that the harm of pathogenic microorganisms such as mycotoxin is obviously reduced. Thefeed does not contain any antibiotics, no drug residues exist after the pigeons eat the feed, and pigeon meat is safer.
Owner:金钱饲料(东莞)有限公司

Special hoisting tool for breaker

The invention discloses a special hoisting tool for a breaker. A plurality of reinforcing ribs are evenly arranged between a steel pipe and a bottom plate. A base is arranged at the bottom. A winch is installed on the base. One end of a connecting rope of the winch is connected with the upper portion of the steel pipe. A hinge base is arranged on the bottom plate. The bottom plate is hinged to the steel pipe through the hinge base. A limiting block is arranged on the side, facing the winch, of the hinge base and matched with the steel pipe. The special hoisting tool is designed according to a 35 kV equipment area environment and the installation characteristics of a Siemens 3AP1FG series switch, and a single-phase switch of the Siemens 3AP1FG breaker can be hoisted in a narrow space. A cross rod is arranged on the steel pipe, a motor is installed on the cross rod, a base is arranged at the bottom of the motor, a positioning rod is formed in the base and matched with the cross rod, a pinion is installed on an output shaft of the motor, a big gear is installed on a fixing rod and engaged with the pinion, one side of the motor is provided with a pipe clamp, and the pipe clamp is fixed to the steel pipe. According to a manufacturing method, the defect that the yield is low when complex organic micromolecules are synthesized is overcome, and a solvothermal method is used for synthesis; and operation is simple, the special hoisting tool can be obtained easily, and the yield is high. The special hoisting tool for the breaker further has the advantages of being simple and compact in structure, low in manufacturing cost and easy and convenient to use.
Owner:STATE GRID CORP OF CHINA +1

Feed additive for feeding bamboo rats and preparation method thereof

The invention provides a feed additive for feeding bamboo rats. The feed additive comprises, by weight, the following raw materials: 4-7 parts of root of hairy asiabell, 8-10 parts of dandelion, 3-4 parts of longan pulp, 1-2 parts of methionine, 1-2 parts of tryptophan, 10-15 parts of flax meal, 10-15 parts of corn flour, 0.002 part of bifidobacteria and 150 parts of rice washing water. The preparation method of the feed additive for feeding the bamboo rats comprises the steps of crushing, fermenting, filtering and mixing. According to the invention, the root of hairy asiabell, the dandelion,the longan pulp and other raw materials are matched and make the feed additive contain rich nutrient elements and effective active ingredients, so that the absorption of nutrient substances can be promoted, the regeneration capacity and the metabolism capacity of an organism can be enhanced, and the growth and development of the bamboo rat can be promoted; The added biological enzyme bifidobacteria can effectively inhibit harmful bacteria or pathogenic bacteria, achieve the effects of microecological balance in vivo, improve the immunity of organisms, synthesize B vitamins, generate nutrient substances, promote the absorption of the nutrient substances, prevent diseases and treat diseases.
Owner:李海飞

Synthetic method of polyoxymethylene dimethyl ether

The invention relates to a polyformaldehyde dimethyl ether synthesis method which mainly solves the problems of difficult catalyst separation, low raw material conversion rate and poor product selectivity in the prior art. The technical scheme of the polyformaldehyde dimethyl ether synthesis method comprises the following steps: by taking methanol, methylal and polyformaldehyde as raw materials, under the conditions that the reaction temperature is 70-200 DEG C and the reaction pressure is 0.2-6 MPa, enabling the raw materials to be in contact with a catalyst, and reacting to generate polyformaldehyde dimethyl ether, wherein the weight ratio of the methanol, the methylal and the polyformaldehyde is (0-10):(0-10):1, and the amounts of the methanol and the methylal can not be 0 at the same time; the amount of the catalyst accounts for 0.1-5.0% of the weight of the raw materials; and the used catalyst comprises the following components in parts by weight: a) 30-80 parts of carrier, which is at least one selected from SBA-15, MCM-41 or MCM-22 molecular sieve, and b) 20-70 parts of solid super-strong acid carried thereon, which is at least one selected from SO4<2-> / ZrO2, SO4<2-> / Fe2O3, Cl<-> / TiO2 or Cl<-> / Fe2O3. Thus, the problems are well solved; and the polyformaldehyde dimethyl ether synthesis method can be used for industrial production of polyformaldehyde dimethyl ether.
Owner:CHINA PETROLEUM & CHEM CORP +1

Preparation method of epimedium aglycone

The invention relates to a preparation method of epimedium aglycone, which comprises the steps that dried epimedium is pulverized or cut into segments, 30-95% ethanol or 30-100% methanol is added for reflux extraction, the extract solution is decompressed and concentrated to obtain paste, 10-100 ml of acetate-sodium acetate buffer solution with the pH of 3.5-9.0 is added into each gram of paste, snailase is added for hydrolysis, the mass ratio of enzyme to paste is 0.05-5, the reaction temperature is 15 to 80 DEG C, the reaction time is 2 to 72h, the reaction solution is centrifuged, the precipitate is dissolved with an organic solvent, filtration is carried out to obtain filtrate, the solvent is steamed away to obtain crude epimedium aglycone, and pure epimedium aglycone is obtained after recrystallization. The invention has the characteristic that the epimedium extract is directly converted into high-purity aglycone in one step by utilizing the strong enzymic hydrolysis of the snailase so as to simplify the operation steps with strong purposiveness and high conversion rate, and has the advantages of no pollution and large-scale production. The invention overcomes the shortcomings of large destruction on the aglycone, serious pollution, poor purposiveness, low conversion rate, difficult separation and purification and the like of the prior art.
Owner:JIANGSU PROVINCE INST OF TRADITIONAL CHINESE MEDICINE

Prevention and control medicament based on sewage treatment

The invention belongs to the technical field of sewage treatment, and particularly discloses a prevention and control agent based on sewage treatment. The water treatment agent is prepared from the following raw materials in parts by weight: 6-9 parts of bentonite, 3-5 parts of sodium chloride, 3-4 parts of alum, 1.6-2.5 parts of aluminum sulfate, 5-6 parts of calcium oxide, 6-9 parts of magnesium oxide, 1.2-1.8 parts of ferric oxide, 0.6-0.9 part of magnesium oxide, 0.2-0.5 part of sodium oxide, 3-9 parts of silicon dioxide, 5-7 parts of sodium silicate, 4-6 parts of sodium polyacrylate, 9-12 parts of alum, 5-15 parts of additives, 12-18 parts of lithopone, and the remainder being water. By adding the additive, the additive is prepared by mixing menthone, starch, butane, zeolite minerals, activated carbon and diatomite, and impurity particles in sewage are adhered into clusters through the starch and float on the water surface by utilizing the characteristic that the starch is insoluble in water; the zeolite minerals, the activated carbon and the diatomite are combined; so that a good purification effect on the water quality is achieved; the purification treatment effect of the sewage is improved, so that after the prevention and control agent is added into the sewage, suspended solids are flocculated immediately, and precipitation is rapid.
Owner:山东颖慧园环保科技有限公司

Catalytic hydrogen supply system based on organic liquid and hydrogen supply method thereof

The invention discloses a catalytic hydrogen supply system based on organic liquid and a hydrogen supply method thereof.The catalytic hydrogen supply system comprises an organic liquid hydrogen supply material and a hydrogen supply reaction catalyst, and the organic liquid hydrogen supply material is composed of a hydrogen supply raw material A and a hydrogen supply raw material B; wherein the hydrogen supply raw material A is one or two of dodecahydrobenzyltoluene and octadehydrodibenzyltoluene, the mass content of the octadehydrodibenzyltoluene is not more than 80%, and the hydrogen supply raw material B is one or more of decahydronaphthalene, 1-methyl decahydronaphthalene and 2-methyl decahydronaphthalene; the hydrogen-donating reaction catalyst is a supported metal catalyst and comprises a catalyst carrier and a catalyst active metal component. The method solves the problem that a hydrogen supply technology based on an organic liquid material is lacked in the technical field at present, and has the advantages of low raw material cost, large-scale storage and supply states, low-temperature liquid property, low catalyst cost, large hydrogen supply amount, relatively mild reaction process conditions, high hydrogen supply purity and the like.
Owner:DONGFANG HONGSHENG NEW ENERGY APPL TECH RES INST

Special hoisting tool for circuit breaker

The invention discloses a special hoisting tool for a breaker. A plurality of reinforcing ribs are evenly arranged between a steel pipe and a bottom plate. A base is arranged at the bottom. A winch is installed on the base. One end of a connecting rope of the winch is connected with the upper portion of the steel pipe. A hinge base is arranged on the bottom plate. The bottom plate is hinged to the steel pipe through the hinge base. A limiting block is arranged on the side, facing the winch, of the hinge base and matched with the steel pipe. The special hoisting tool is designed according to a 35 kV equipment area environment and the installation characteristics of a Siemens 3AP1FG series switch, and a single-phase switch of the Siemens 3AP1FG breaker can be hoisted in a narrow space. A cross rod is arranged on the steel pipe, a motor is installed on the cross rod, a base is arranged at the bottom of the motor, a positioning rod is formed in the base and matched with the cross rod, a pinion is installed on an output shaft of the motor, a big gear is installed on a fixing rod and engaged with the pinion, one side of the motor is provided with a pipe clamp, and the pipe clamp is fixed to the steel pipe. According to a manufacturing method, the defect that the yield is low when complex organic micromolecules are synthesized is overcome, and a solvothermal method is used for synthesis; and operation is simple, the special hoisting tool can be obtained easily, and the yield is high. The special hoisting tool for the breaker further has the advantages of being simple and compact in structure, low in manufacturing cost and easy and convenient to use.
Owner:STATE GRID CORP OF CHINA +1
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