Preparation method of mesoporous composite material and high-temperature-resisting thermal insulating material prepared by preparation method
A technology of composite materials and mesoporous materials, applied in the field of materials, can solve problems such as the inability to meet the thermal insulation environment and thermal insulation requirements
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[0044] Preparation method of mesoporous composite material
[0045] One aspect of the present invention provides a method for preparing a mesoporous composite material, comprising the following steps: mixing the mesoporous material with fibers and / or fiber products, and heat-treating to prepare the mesoporous composite material, the mesoporous material is composed of Silicon mesoporous material.
[0046] In the preparation method of mesoporous composite materials provided by the present invention, the heat treatment usually refers to controlling the temperature of the reaction system at 25-50°C, 50-100°C, 100-150°C, 150-200°C, 200-250°C , 250-300°C, 300-350°C, 350-400°C, 400-450°C, 450-500°C, 500-550°C, 550-600°C, 600-650°C, 650-700°C, 700-750°C , 750-800°C, 800-850°C, 850-900°C, 900-950°C, or 950-1000°C. There is no particular limitation on the manner of adjusting the temperature of the reaction system, as long as it does not limit the purpose of the invention. Those skill...
Embodiment 1
[0090] Add tetraethyl orthosilicate (TEOS), cetyltrimethylammonium bromide (CTAB), ammonia water, and deionized water into the reaction vessel, and the molar composition of the mixture is TEOS:CTAB:NH 4 OH:H 2 O=1:0.03:0.25:200; Stir at 60±10°C for 10 hours to obtain a mixed solution, which is treated by filtration and washing to obtain a mesoporous material. Aluminum silicate fiber (apparent density 0.09g / cm 3 , diameter 3μm) (according to the mass ratio of mesoporous material: aluminum silicate fiber = 0.15: 1) soaked in the solution dispersed with mesoporous material, after compounding fully, sintered at 800±20°C for 4h, and finally obtained Si-O-Si Mesoporous composite insulation materials. The obtained mesoporous material has a pore volume of 0.18ml / g, a pore diameter of 6.4nm, a pore wall of 2.9nm, and a porosity of 37.27%. The Si-O-Si bond is detected by a Fourier transform infrared spectrometer (FTIR), and the FTIR analysis shows that, The Si-O-Si bond of uncomposit...
Embodiment 2
[0092] SiO 2 、Na 2 O, cetyltrimethylammonium chloride (CTAC), HCl, deionized water are added to the reaction vessel, the molar composition of the mixture is SiO 2 : Na 2 O:CTAC:HCl:H 2 O=1: 0.33: 0.25: 0.8: 100; Stir at 80±10°C for 12 hours to obtain a mixed solution, filter, wash and other methods to obtain a mesoporous material. Aluminum silicate fiber (apparent density 0.09g / cm 3 , diameter 3μm) (according to the mass ratio of mesoporous material: aluminum silicate fiber = 0.15:1) soaked in the solution dispersed with mesoporous material, sintered at 600±10°C for 5h after compounding fully, and finally obtained Si-O-Si Mesoporous composite insulation materials. The obtained mesoporous material has a pore volume of 0.21ml / g, a pore diameter of 5.8nm, a pore wall of 1.5nm, and a porosity of 40.94%. The Si-O-Si bond is detected by a Fourier transform infrared spectrometer (FTIR), and the FTIR analysis shows that, The Si-O-Si bond of uncomposited silicon-based mesoporous ...
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