Gel electrolyte, battery cell containing same, paper shell battery and preparation method of paper shell battery
A gel electrolyte and cell technology, which is applied in the direction of electrolyte immobilization/gelation, secondary batteries, battery pack components, etc., can solve the problem of PP melting in the inner layer of aluminum-plastic film, easy generation of small holes, and poor sealing performance Good and other problems, to achieve the effect of reducing internal resistance, easy edge sealing, and reducing battery internal resistance
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Embodiment 1
[0047] A gel electrolyte, mixed by PVDF-HFP, LiPF6 and a solvent in a mass ratio of 3:0.076:10; the viscosity is 4000 centipoise; the solvent is N-methylpyrrolidine and acetone in a mass ratio of 7:3 Mixed mixed solution; the concentration of LiPF6 electrolyte is 1mol / L.
[0048] A solid battery cell containing the above-mentioned gel electrolyte, comprising a positive electrode sheet and a negative electrode sheet; a gel electrolyte layer is provided between the positive electrode sheet and the negative electrode sheet; the positive electrode sheet and the negative electrode sheet are respectively attached to the gel The upper surface and the lower surface of the electrolyte layer; the thickness of the gel electrolyte layer is 30 μm.
[0049] Such as figure 1 , figure 2 As shown, a paper-shell thin-sheet lithium-ion battery containing the above-mentioned solid electric core includes a casing 1 and an electric core 3 packaged inside it;
[0050] The inner wall of the housi...
Embodiment 2
[0066] A gel electrolyte is formed by mixing PVDF-HFP, LiPF6 and a solvent at a mass ratio of 2.5:0.089:11; the viscosity is 3900 centipoise; the solvent is N-methylpyrrolidine and acetone at a mass ratio of 7:3 Mixed mixed solution; the concentration of LiPF6 electrolyte is 1mol / L.
[0067] A solid battery cell containing the above-mentioned gel electrolyte, comprising a positive electrode sheet and a negative electrode sheet; a gel electrolyte layer is provided between the positive electrode sheet and the negative electrode sheet; the positive electrode sheet and the negative electrode sheet are respectively attached to the gel The upper surface and the lower surface of the electrolyte layer; the thickness of the gel electrolyte layer is 35 μm.
[0068] A paper shell sheet lithium-ion battery containing the above-mentioned solid electric core, including a casing and an electric core encapsulated inside it;
[0069] An anti-corrosion layer is provided on the inner wall of th...
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