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Ferricinium ion type high-nitrogen metal complex and preparation method thereof

A metal complex, ionic technology, applied in the field of ferrocene ion type high nitrogen metal complex and its preparation, can solve the problems of volatile, non-volatile, easy migration of ferrocene catalysts and the like, and achieves vapor pressure and The effect of low volatility, increased energy, and simple preparation method

Active Publication Date: 2017-06-13
SHAANXI NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to reduce the problems of easy migration and volatilization of existing ferrocene catalysts, and provide a ferrocene catalyst that is not volatile under natural conditions, has good thermal stability, and has relatively high heat of formation and combustion. A ferrocenium ion-type high-nitrogen metal complex with adjustable catalytic performance, and provides a preparation method for the complex with simple operation and low cost

Method used

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  • Ferricinium ion type high-nitrogen metal complex and preparation method thereof
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  • Ferricinium ion type high-nitrogen metal complex and preparation method thereof

Examples

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Effect test

Embodiment 1

[0028] Preparation of ferrocenemethyl triazole manganese complex with picric acid radical as negative ion with the following structural formula

[0029]

[0030] 0.0845g (0.5mmol) MnSO 4 ·H 2 O was completely dissolved in a 50mL round-bottom flask filled with 15mL of distilled water, and when the temperature rose to 70°C, 0.542g (2.0mmol) of ferrocenylmethyl triazide completely dissolved in 20mL of absolute ethanol was added dropwise to it at the same time The azole solution and 0.252g (1.0mmol) sodium picrate solution completely dissolved in 20mL distilled water were refluxed for 3 hours, a brownish-red precipitate was formed, filtered, and the filter cake was rinsed with distilled water and anhydrous ether in turn, and vacuum-dried at 40°C , obtained ferrocenemethyl triazole manganese complex with picric acid radical as anion, the yield was 78%, and the structural characterization data was: IR(KBr,cm -1 ):3507(s,br),3094(w),1626(vs),1565(m),1474(m),1332(vs),1263(m),1125...

Embodiment 2

[0033] Preparation of ferrocenylmethyltriazole cobalt complex with picric acid radical as anion with the following structural formula

[0034]

[0035] In Example 1, the MnSO used 4 ·H 2 O with equimolar CoSO 4 ·7H 2O was replaced, and the other steps were the same as in Example 1 to obtain a red ferrocenylmethyltriazole cobalt complex with picrate as an anion, with a yield of 85%.

[0036] The single crystal structure of the prepared ferrocenemethyltriazole cobalt complex is shown in figure 2 , belongs to the triclinic crystal system, space group P-1(2), and the unit cell parameter a is b for c for α is 92.21(4)°, β is 100.15(4)°, and γ is 95.2(4)°. There is an independent Co(II) ion, four neutral ferrocenylmethyltriazoles and two water molecules in the independent unit of the complex, in which ferrocenylmethyltriazole and water molecules are connected with the central Co (II) The ions participate in the coordination, and the other two picric acid groups are fr...

Embodiment 3

[0038] Preparation of ferrocenylmethyl triazole copper complex with picric acid radical as an anion with the following structural formula

[0039]

[0040] In Example 1, the MnSO used 4 ·H 2 O with equimolar CuSO 4 ·5H 2 O was replaced, and the other steps were the same as in Example 1 to obtain a brown-yellow ferrocenemethyltriazole copper complex with picrate as an anion, with a yield of 85%.

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Abstract

The invention discloses a ferricinium ion type high-nitrogen metal complex and a preparation method thereof. The structural formula of the complex is as shown in the description; and in the formula, M represents any one of Mn<2+>, Co<2+>, Cu<2+>, Ni<2+> and Pb<2+>, X represents C or N, and L represents picrate or trinitroresorcin divalent anion, wherein n is equal to 2 when the L represents the picrate, and n is equal to 1 when L represents the trinitroresorcin divalent anion. Metal ions are introduced into the complex provided by the invention, so the anti-mobility of the complex is improved and the volatility of the complex is reduced; the introduced ligand and polynitrophenol anion have high formation heat and combustion heat, so the combustion catalyst performance of the complex on the thermal decomposition process of ammonium perchlorate is improved; and the preparation method of the complex provided by the invention is simple.

Description

technical field [0001] The invention belongs to the technical field of solid propellants, and in particular relates to a ferrocene ion-type high-nitrogen metal complex and a preparation method thereof. Background technique [0002] Ferrocene and its derivatives, because of their excellent combustion regulation function, have been widely used in strategic and tactical weapon systems as the most important burning rate catalysts of solid propellants (especially composite propellants). Ballistic missiles (including theater, short-range, medium-range, intercontinental ballistic missiles, etc.), airborne tactical missiles, anti-missile high-speed kinetic energy missiles and sea-based mines, torpedoes and other weapons play a huge role. [0003] Ferrocene-based burning rate catalysts have been widely used in solid propellants since the 1960s and 1970s. In a US patent published by Huskins in 1972, it was proposed that the allyl alcohol structure be introduced into ferrocene to prepa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F17/02C07C201/12C07C205/24
CPCC07C205/24C07F17/02
Inventor 张国防张娜刘漫漫贾铎李婷邵二莎高子伟张伟强
Owner SHAANXI NORMAL UNIV
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