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Method for dispersion of nanocrystalline cellulose powder in waterborne medium

A technology of nanocrystalline cellulose and aqueous medium, which is applied in the field of dispersing nanocrystalline cellulose powder in aqueous medium, can solve the problems of poor dispersion and agglomeration of nanocrystalline cellulose, achieve narrow particle size distribution, simple method, and easy operation easy effect

Active Publication Date: 2017-06-16
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to overcome the shortcomings and deficiencies of the prior art, and provide a method for dispersing nanocrystalline cellulose powder in an aqueous medium without changing the process of preparing nanocrystalline cellulose by acid hydrolysis, so as to solve the problem of acid hydrolysis preparation. The problem of poor dispersion and serious agglomeration of nanocrystalline cellulose in aqueous media after drying treatment provides conditions for the wide application of nanocrystalline cellulose powder

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Take a clean and dry 200ml beaker, add 100ml of pure water, place it on a magnetic stirrer, add 1g of nanocrystalline cellulose powder prepared by the acid hydrolysis method into the center of the vortex at a speed of 800r / min in 20 times, and wait until the powder is dispersed to Continue to add until it is invisible to the naked eye until the nanocrystalline cellulose is completely added to the aqueous system; seal the beaker to prevent air from entering, increase the magnetic stirrer speed to 2000r / min, and continue stirring for 3h; The cellulose was placed in an ultrasonic cell breaker for treatment, the temperature was controlled at 20°C, and the specific energy was 12kJ / g; finally, a nanocrystalline cellulose solution with a mass volume ratio of 1% was obtained. Take an appropriate amount of nanocrystalline cellulose solution after ultrasonic treatment and send it to the Malvern laser particle size analyzer. After testing, the average particle size of the dispersed...

Embodiment 2

[0027] Take a clean and dry 200ml beaker, add 100ml of pure water, place it on an overhead stirrer, add 3g of nanocrystalline cellulose powder prepared by acid hydrolysis to the center of the vortex at a speed of 300r / min in 25 times, and wait for the powder to disperse Continue to add until it is invisible to the naked eye until the nanocrystalline cellulose is completely added to the aqueous phase system; seal the beaker to prevent air from entering, increase the speed of the overhead stirrer to 1000r / min, and continue stirring for 4h; The crystalline cellulose was processed in an ultrasonic cell breaker, the temperature was controlled at 15°C, the specific energy was 25kJ / g, and finally a nanocrystalline cellulose solution with a mass volume ratio of 3% was obtained. Take an appropriate amount of nanocrystalline cellulose solution after ultrasonic treatment and send it to the Malvern laser particle size analyzer. After testing, the average particle size of the dispersed nano...

Embodiment 3

[0029] Take a clean and dry 200ml beaker, add 100ml of pure water, place it on a magnetic stirrer, add 5g of nanocrystalline cellulose powder prepared by the acid hydrolysis method into the center of the vortex at a speed of 1500r / min for 30 times, and wait until the powder is dispersed to Then continue to add until the nanocrystalline cellulose is completely added to the water phase system; then place the beaker under the high-speed disperser, adjust the speed to 8000r / min, stir intermittently twice, each time for 2min; then stir evenly The nanocrystalline cellulose was placed in an ultrasonic cell breaker for treatment, the temperature was controlled at 10°C, the specific energy was 40kJ / g, and finally a nanocrystalline cellulose solution with a mass volume ratio of 5% was obtained. Take an appropriate amount of nanocrystalline cellulose solution after ultrasonic treatment and send it to the Malvern laser particle size analyzer. After testing, the average particle size of the...

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Abstract

The invention discloses a method for dispersion of nanocrystalline cellulose powder in a waterborne medium. The method can achieve dispersion of powder nanocrystalline cellulose under the circumstances of no use of a dispersant and input of lower energy, and solves the technical problems of poor dispersion in water and serious agglomeration of acid hydrolysis method prepared nanocrystalline cellulose subjected to drying treatment. The method specifically includes the steps of: slowly adding a certain amount of nanocrystalline cellulose powder into water under stirring to conduct mechanical stirring treatment, and then performing ultrasonic treatment under temperature control so as to obtain a nanocrystalline cellulose solution. The method provided by the invention can achieve dispersion of nanocrystalline cellulose powder in water, the operation is simple, the method is easy, the obtained solution has narrow particle size distribution, and an original nanoscale can be restored.

Description

technical field [0001] The invention relates to the field of dispersion of nanocrystalline cellulose powder, in particular to a method for dispersing nanocrystalline cellulose powder in an aqueous medium. Background technique [0002] Cellulose is the most abundant degradable biopolymer compound in natural resources. It consists of disordered amorphous regions and nematic closely ordered crystalline regions. After the cellulose is treated with an inorganic acid, the transverse splitting of the amorphous region occurs and is removed by a large amount of hydrolysis, while the crystalline region is retained, and nanocrystalline cellulose can be prepared. Sulfuric acid, hydrochloric acid, etc. can be used to hydrolyze cellulose to prepare nanocrystalline cellulose. Nanocrystalline cellulose prepared by sulfuric acid method has large specific surface area, high strength, and excellent thermal stability, acid and alkali resistance, mechanical and optical properties. It can be wi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J3/05C08L1/04
CPCC08J3/05C08J2301/04
Inventor 徐峻朱师云高文花陈克复李军
Owner SOUTH CHINA UNIV OF TECH