Halogen-free flame-retardant polycarbonate material and preparation method thereof

A technology of flame retardant polycarbonate and polycarbonate resin, applied in the field of polycarbonate modified materials, can solve problems such as gaps, and achieve the effects of good processability, excellent transparency and high impact resistance.

Inactive Publication Date: 2017-07-07
广州市寅源新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the light transmittance of this flame retardant material is only 83%,

Method used

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  • Halogen-free flame-retardant polycarbonate material and preparation method thereof
  • Halogen-free flame-retardant polycarbonate material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Embodiment 1, the preparation of halogen-free flame-retardant polycarbonate material

[0029] The following components in parts by weight: 97.4 parts of ET3117, 0.2 parts of sulfonate flame retardant HR-3025, 2 parts of silicone flame retardant KR-2710, 0.1 part of antioxidant 168, 0.1 part of antioxidant Agent 1076, 0.1 part of lubricant, 0.1 part of anti-ultraviolet additive are mixed in a high-speed mixer for 3 minutes, then extruded through a twin-screw extruder at 260-280 ° C, cooled, and pelletized, and the resulting pellets are dried at 120 ° C After 4 hours, it is injected into a standard spline at 260-280°C to obtain

Embodiment 2

[0030] Embodiment 2, the preparation of halogen-free flame-retardant polycarbonate material

[0031] The following components in parts by weight: 99 parts of ET3117, 0.1 part of sulfonate flame retardant HR-3025, 0.5 part of silicone flame retardant KR-2710, 0.1 part of antioxidant 168, 0.1 part of antioxidant Agent 1076, 0.1 part of lubricant, 0.1 part of anti-ultraviolet additive are mixed in a high-speed mixer for 3 minutes, then extruded through a twin-screw extruder at 260-280 ° C, cooled, and pelletized, and the resulting pellets are dried at 120 ° C After 4 hours, it is injection molded into a standard spline at 260-280°C, and it is ready.

Embodiment 3

[0032] Embodiment 3, the preparation of halogen-free flame-retardant polycarbonate material

[0033] The following components in parts by weight: 94.4 parts of ET3117, 0.2 parts of sulfonate flame retardant HR-3025, 5 parts of silicone flame retardant KR-2710, 0.1 part of antioxidant 168, 0.1 part of antioxidant Agent 1076, 0.1 part of lubricant, 0.1 part of anti-ultraviolet additive are mixed in a high-speed mixer for 3 minutes, then extruded through a twin-screw extruder at 260-280 ° C, cooled, and pelletized, and the resulting pellets are dried at 120 ° C After 4 hours, it is injected into a standard spline at 260-280°C to obtain

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PUM

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Abstract

The invention discloses a halogen-free flame-retardant polycarbonate composite material and a preparation method thereof. The halogen-free flame-retardant polycarbonate composite material is characterized by having high transparency, and the flame retardance can reach 1mm UL94V-0 level. The polycarbonate composite material comprises the following components in parts by weight: 92.5 to 99 parts of polycarbonate resin, 0.5 to 5 parts of an organosilicone flame retardant, 0.1 to 0.5 part of a sulfonate flame retardant and 0.4 to 2 parts of aids. The preparation method comprises the following steps: mixing the polycarbonate resin, the organosilicone flame retardant, the sulfonate flame retardant and the aids in a high mixing machine, extruding and pelleting by double screws, drying and performing injection molding to obtain the polycarbonate composite material. The halogen-free flame-retardant polycarbonate composite material can reach 1.0 mm UL94V-0 level, has high transparency, is halogen-free and environment-friendly, and has excellent mechanical property, thermal property and processing property.

Description

technical field [0001] The invention relates to the technical field of polycarbonate modified materials, in particular to a halogen-free flame-retardant polycarbonate material and a preparation method thereof. Background technique [0002] Polycarbonate (PC) is a kind of thermoplastic engineering plastic with excellent comprehensive properties. Because of its excellent weather resistance, high impact resistance, and excellent electrical insulation, it is widely used in the automotive industry, instrumentation, electronic appliances and other fields. Polycarbonate itself has certain flame retardancy, but it cannot meet the occasions that require high or very high flame retardancy. Commonly used halogen-free flame retardants (phosphate ester flame retardants, sulfonate flame retardants, silicon-based flame retardants) flame-retardant polycarbonate can only achieve 1.5mm V0 transparency and 1.0mmV2, and cannot achieve ultra-thin 1.0mm V0 is transparent. Adding anti-dripping a...

Claims

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Application Information

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IPC IPC(8): C08L69/00C08L83/04C08K5/42
CPCC08L69/00C08L2201/02C08L2201/10C08L2201/22C08L2205/025C08L2205/03C08L2205/035C08L83/04C08K5/42
Inventor 赵国栋
Owner 广州市寅源新材料股份有限公司
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