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Emulsion for cathode electrophoretic paint and preparation method of emulsion

A cathodic electrophoresis and emulsion technology, which is applied in the direction of electrophoretic coatings, coatings, anti-corrosion coatings, etc., can solve the problems of low cross-linking degree of epoxy resin and poor salt spray resistance, so as to increase cross-linking density, enhance resistance Effect of Heat and Salt Spray Resistance

Inactive Publication Date: 2017-08-18
湖北同邦达科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The present invention provides an emulsion for cathodic electrophoretic paint and a preparation method thereof to overcome the above problems or at least partly solve the above problems, so as to solve the problems of low crosslinking degree and poor salt spray resistance of epoxy resin in the emulsion technical problem

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A kind of emulsion that is used for cathodic electrophoretic paint, its main component and preparation process are as follows:

[0037]Put 1128 parts of epoxy resin E-51, 456 parts of bisphenol A, and 80 parts of xylene into the reaction kettle, raise the temperature to 120°C, add 4 parts of dimethylbenzylamine, raise the temperature to 140°C, and detect the obtained The epoxy value of the product, so that its epoxy value is 0.1578 ± 0.01. Cool down, add 400 parts of propylene glycol monomethyl ether, 20 parts of propylene glycol phenyl ether and 180 parts of ethylene glycol butyl ether, cool down to 90 ° C, add 101 parts of N-methylol acrylamide, 0.1 part of hydroquinone, 105 parts of di Ethanolamine, after reacting for 1.5 hours, add 45 parts of monoethanolamine, raise the temperature to 110°C, and react at 110±2°C for 2.5 hours. Cool down to 90°C, add 1000 parts of cross-linking agent (the releasable -NCO content is 2mol); cool down to 70°C, add 2 parts of BYK110, 2...

Embodiment 2

[0040] A kind of emulsion that is used for cathodic electrophoretic paint, its main component and preparation process are as follows:

[0041] Put 1362 parts of epoxy resin E-44, 456 parts of bisphenol A, and 80 parts of xylene into the reaction kettle, raise the temperature to 120°C, add 4 parts of dimethylbenzylamine, raise the temperature to 140°C, and detect the obtained The epoxy value of the product, so that its epoxy value is 0.145 ± 0.01. Cool down, add 400 parts of propylene glycol monomethyl ether, 20 parts of propylene glycol phenyl ether and 180 parts of ethylene glycol butyl ether, cool down to 90 ° C, add 101 parts of N-methylol acrylamide, 0.1 part of hydroquinone, 105 parts of di Ethanolamine, after reacting for 1.5 hours, add 45 parts of monoethanolamine, raise the temperature to 110°C, and react at 110±2°C for 2.5 hours. Cool down to 90°C, add 1000 parts of cross-linking agent (the releasable -NCO content is 2mol); cool down to 70°C, add 2 parts of BYK110, 2...

Embodiment 3

[0044] A kind of emulsion that is used for cathodic electrophoretic paint, its main component and preparation process are as follows:

[0045] Put 862 parts of epoxy resin E-51, 456 parts of bisphenol A, and 80 parts of xylene into the reaction kettle, raise the temperature to 120°C, add 4 parts of dimethylbenzylamine, raise the temperature to 140°C, and detect the obtained The epoxy value of the product, so that its epoxy value is 0.1578 ± 0.01. Cool down, add 400 parts of propylene glycol monomethyl ether, 20 parts of propylene glycol phenyl ether and 180 parts of ethylene glycol butyl ether, cool down to 90 ° C, add 101 parts of N-methylol acrylamide, 0.1 part of hydroquinone, 105 parts of di Ethanolamine, after reacting for 1.5 hours, add 45 parts of monoethanolamine, raise the temperature to 110°C, and react at 110±2°C for 2.5 hours. Cool down to 90°C, add 1000 parts of cross-linking agent (the releasable -NCO content is 2mol); cool down to 70°C, add 2 parts of BYK110, 2...

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PUM

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Abstract

The invention provides an emulsion for cathode electrophoretic paint and a preparation method of the emulsion. The emulsion is prepared from epoxy resin and a double-bond monomer through amination, cross-linking and neutralization reaction in sequence, wherein the mole ratio of epoxy groups in the epoxy resin to the double-bond monomer is (4:1)-(7:1), and preferably is (5:1):(6:1). Compared with the prior art that electrophoretic paint is low in curing degree and poor in salt mist resistance, the emulsion for the cathode electrophoretic paint and the preparation method of the emulsion have the functions that the cross-linking density of the epoxy resin is effectively improved and the salt mist resistance of an electrophoresis paint film is improved after double bonds are introduced into the epoxy resin and are subjected to amination and cross-linking reaction.

Description

technical field [0001] The invention relates to a coating material, more specifically, to an emulsion for cathodic electrophoretic paint and a preparation method thereof. Background technique [0002] Electrophoresis is one of the most common and effective methods of coating metal workpieces. Electrophoretic coating is to immerse the conductive object to be coated in the material tank containing the electrophoretic coating as the cathode / anode, and set the corresponding anode / cathode in the material tank, and pass the current between the two poles for a period of time. A uniform and fine coating film is deposited on the surface of the object. Among them, electrophoretic coating, also known as electrophoretic paint, is an important factor affecting the quality of the final coating film in the electrophoretic coating process. [0003] Electrophoretic coating is widely used in the fields of automobile and various machinery industries. However, due to the influence of climate ...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D5/44C09D5/08C08G59/14
CPCC09D5/4442C08G59/14C09D5/08
Inventor 周雪科徐明兵
Owner 湖北同邦达科技有限公司