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A kind of universal anti-mud type polycarboxylate superplasticizer and preparation method thereof

An anti-mud type, polycarboxylic acid technology, applied in the field of concrete preparation, can solve the problems of water reduction rate, slump retention, unfavorable concrete water-cement ratio, damage to the good gradation of sand, etc., and achieves good water-reducing and dispersing ability. , Promote vigorous promotion and application, and improve the effect of construction costs

Active Publication Date: 2020-03-17
江苏诚意工程技术研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the actual production of ready-mixed concrete, when the mud content in the aggregate exceeds the standard and obviously affects the quality of the concrete, the problem is generally solved by washing the aggregate or increasing the amount of polycarboxylate superplasticizer, but washing It will pollute the environment and damage the good gradation of sand, which is not conducive to the effective control of the water-cement ratio of concrete; simply increasing the amount of polycarboxylate-based water-reducing agent can not solve the problems of water-reducing rate and slump retention, and will increase Construction cost, which affects the use of polycarboxylate superplasticizers in the ready-mixed concrete industry

Method used

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  • A kind of universal anti-mud type polycarboxylate superplasticizer and preparation method thereof
  • A kind of universal anti-mud type polycarboxylate superplasticizer and preparation method thereof
  • A kind of universal anti-mud type polycarboxylate superplasticizer and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0022] To prepare universal anti-mud type polycarboxylate water reducer, select the following components, macromonomer methallyl glycol monoether, unsaturated acid acrylic acid, functional monomer oxalic acid terminated polyether Scale agent, initiator hydrogen peroxide, reducing agent ascorbic acid, chain transfer agent mercaptopropionic acid, the molar ratio is macromonomer:unsaturated acid:functional monomer=1:4.5:2.5, the initiator is macromonomer and functional monomer mass 10‰ of the total, the reducing agent is 3.0‰ of the total mass of macromonomer and functional monomer, and the chain transfer agent is 4.5‰ of the total mass of macromonomer and functional monomer.

[0023] Step 1: dissolving chain transfer agent mercaptopropionic acid and reducing agent ascorbic acid in water to prepare aqueous solution A, dissolving unsaturated acid acrylic acid and functional monomer in water to obtain aqueous solution B;

[0024] Step 2: Add macromonomer methallyl glycol monoether ...

Embodiment 2

[0044] To prepare universal anti-mud polycarboxylate water reducer, select the following components, macromonomer methallyl glycol monoether, unsaturated acid methacrylic acid, functional monomer alkyl acrylate phosphate , initiator azobisisobutylamidine hydrochloride, reducing agent ferrous sulfate, chain transfer agent mercaptoacetic acid, the molar ratio is macromonomer: unsaturated acid: functional monomer = 1:2.0:1.5, the initiator is 3.0‰ of the total mass of macromonomer and functional monomer, the reducing agent is 1.5‰ of the total mass of macromonomer and functional monomer, and the chain transfer agent is 2.5‰ of the total mass of macromonomer and functional monomer.

[0045] Step 1: dissolving chain transfer agent thioglycolic acid and reducing agent ferrous sulfate in water to prepare aqueous solution A, dissolving unsaturated acid methacrylic acid and functional monomer alkyl acrylate phosphate in water to obtain aqueous solution B;

[0046] Step 2: Add macromonome...

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Abstract

The invention discloses a universal anti-mud polycarboxylic acid water reducer and a preparation method thereof. The universal anti-mud polycarboxylic acid water reducer comprises the following components of a macromonomer, unsaturated acid, a functional monomer, an initiator, a reducing agent and a chain transfer agent, the molar ratio of macromonomer to unsaturated acid to functional monomer is 1:2.0-4.5:1.5-2.5, the initiator is 3.0-10.0%. of that of the total mass of the macromonomer and the functional monomer, the reducing agent is 1.5-3.0%. of that of the total mass of the macromonomer and the functional monomer, and the chain transfer agent is 2.5-4.5%. of that of the total mass of the macromonomer and the functional monomer. The polycarboxylic acid water reducer is based on the molecular structure, the polycarboxylic water reducer suitable for high-mud aggregate is obtained by introducing functional groups, good water reducing dispersion capacity of concrete can be sustained on the premise of not increasing dosage of the water reducer, adsorption of mud on the water reducer is weak, good water reducing dispersion capacity of the water reducer can be sustained, anti-mud slump-retaining effect is good, sufficient strength of hardened concrete can be guaranteed, and normal operation of construction is guaranteed.

Description

technical field [0001] The invention relates to a universal anti-mud type polycarboxylate water reducer and a preparation method thereof, belonging to the field of concrete preparation. Background technique [0002] In recent years, with the increasing demand for construction concrete, there are high requirements for admixtures that must be added to concrete, especially in recent years. Development in the direction of environmental protection, high water reduction, high slump retention, and better adaptability to concrete floors. Polycarboxylate superplasticizer is widely used because of its low dosage, high water reducing rate, low concrete shrinkage, and environmental protection. However, a large number of engineering examples and studies have shown that compared with naphthalene-based, aliphatic and sulfamate-based water-reducers, polycarboxylate-based water-reducers are more sensitive to the clay content of aggregates. Because when the mud content is large, the water-r...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/32C08F283/06C08F220/06C08F2/38C08F4/40
CPCC04B24/32C04B2103/302C08F2/38C08F4/40C08F283/065C08F220/06
Inventor 曹永鹿国强王兆华刘贵双
Owner 江苏诚意工程技术研究院有限公司