A kind of universal anti-mud type polycarboxylate superplasticizer and preparation method thereof
An anti-mud type, polycarboxylic acid technology, applied in the field of concrete preparation, can solve the problems of water reduction rate, slump retention, unfavorable concrete water-cement ratio, damage to the good gradation of sand, etc., and achieves good water-reducing and dispersing ability. , Promote vigorous promotion and application, and improve the effect of construction costs
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Embodiment 1
[0022] To prepare universal anti-mud type polycarboxylate water reducer, select the following components, macromonomer methallyl glycol monoether, unsaturated acid acrylic acid, functional monomer oxalic acid terminated polyether Scale agent, initiator hydrogen peroxide, reducing agent ascorbic acid, chain transfer agent mercaptopropionic acid, the molar ratio is macromonomer:unsaturated acid:functional monomer=1:4.5:2.5, the initiator is macromonomer and functional monomer mass 10‰ of the total, the reducing agent is 3.0‰ of the total mass of macromonomer and functional monomer, and the chain transfer agent is 4.5‰ of the total mass of macromonomer and functional monomer.
[0023] Step 1: dissolving chain transfer agent mercaptopropionic acid and reducing agent ascorbic acid in water to prepare aqueous solution A, dissolving unsaturated acid acrylic acid and functional monomer in water to obtain aqueous solution B;
[0024] Step 2: Add macromonomer methallyl glycol monoether ...
Embodiment 2
[0044] To prepare universal anti-mud polycarboxylate water reducer, select the following components, macromonomer methallyl glycol monoether, unsaturated acid methacrylic acid, functional monomer alkyl acrylate phosphate , initiator azobisisobutylamidine hydrochloride, reducing agent ferrous sulfate, chain transfer agent mercaptoacetic acid, the molar ratio is macromonomer: unsaturated acid: functional monomer = 1:2.0:1.5, the initiator is 3.0‰ of the total mass of macromonomer and functional monomer, the reducing agent is 1.5‰ of the total mass of macromonomer and functional monomer, and the chain transfer agent is 2.5‰ of the total mass of macromonomer and functional monomer.
[0045] Step 1: dissolving chain transfer agent thioglycolic acid and reducing agent ferrous sulfate in water to prepare aqueous solution A, dissolving unsaturated acid methacrylic acid and functional monomer alkyl acrylate phosphate in water to obtain aqueous solution B;
[0046] Step 2: Add macromonome...
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