A method for determining a safe density window of a hydrate formation considering a mud cake under an action of drilling fluids is provided. The method establishes a heat-fluid-solid-chemical multi-field coupling model considering the seepage effect of the mud cake at the well wall and the influence of natural gashydratedecomposition. The simulation results show the distribution of pore pressure, temperature, and solute concentration in the drilling fluid around the well after the drilling fluid invades. Based on the determination of multi-field coupling model, the determination results, combined with a Cullen-Moore criterion, and manner for calculating a safe density window of a hydrate formation considering the mud cake under the action of the drilling fluid is further established.
This invention relates to a highly efficient co-production system and method for deep-water shallow gas and natural gas hydrates, belonging to the field of deep-water oil and gas and natural gashydrate development. It employs a one-injection-four-production well network, deploying one central well and four surrounding production wells in the target reservoir area. The central well is initially used for fracturing and fracture creation and participates in production; later, based on production decline or reservoir temperature reduction, it is converted from production to injection, used to inject anhydrous self-generating heat materials into the artificial fracture network. The four surrounding production wells are respectively deployed in the natural gashydrate reservoir and the shallow gas reservoir, used for depressurization production in the target reservoir, achieving the co-production of shallow gas and hydratedecomposition gas. This invention solves problems existing in the development of deep-water shallow gas and natural gas hydrates, such as low reservoir permeability, difficult gas migration, significant reservoir temperature drop in the later stages of simple depressurization production, rapid gas production decline, easy secondary formation of natural gas hydrates, and difficulty in the co-production and efficient extraction of shallow gas and hydrates.
The present application relates to hydrate depressurization production numerical simulation technical field, specifically relates to hydratedecomposition method and system considering pressure wavetime lag and pore structure entropy, the method includes the following steps: calculating pore structure entropy, constructing saturation and structure entropy dependent time memory kernel, combining decomposition rate threshold, pressure drop threshold, forming the decomposition front indicator function with prediction-correction mechanism;The time memory kernel, space-time inseparable causal kernel and threshold response function are subjected to space-time convolution operation, based on the decomposition front indicator function, an integral form of non-local memory hydrate decomposition rate model is established;The Peacley number is calculated by grid Darcy velocity, the scalar characteristic memory time is extended to the second-order symmetric anisotropic memory time tensor, the second-order tensor type memory variable is constructed and the evolution equation is established, the non-local memory hydrate decomposition rate model is coupled to the energy conservation equation and two-phase Darcy seepage pressure equation, and the decomposition result is obtained by iterative solution.
The present application belongs to the technical field of hydrate exploitation and CO2 storage, and discloses a continuous and synchronous method for hydrate exploitation and CO2 storage based on pressure distribution, which measures the related basic parameters of a reservoir, determines the phase equilibrium pressure of natural gashydrate and CO2 hydrate in the hydrate reservoir, determines the exploitation scheme of the hydrate reservoir, determines the formation method of the CO2 cap layer, determines the dynamic change of the gas phase permeability in the hydrate decomposition reservoir, couples the related parameters such as effective stress and hydrate saturation, combines the control equation, determines the position of the pressure decomposition front in the hydrate reservoir, compares the position of the CO2 cap layer, optimizes and adjusts the position of the cap layer, determines the decomposition degree of the hydrate decomposition reservoir, and completes the high-density storage of CO2 in the abandoned natural gas reservoir. The present application realizes the continuous and synchronous operation of hydrate exploitation and CO2 storage, and greatly improves the efficiency of hydrate exploitation and CO2 storage.
The invention relates to the technical field of petroleumengineering drilling safety, and discloses a drilling well wall stability prediction method considering a hydrate reservoir creep effect, and the method comprises the following steps: S1, building hydrate reservoir initial heat flow field distribution based on TOUGH + HYDRATEsoftware; s2, establishing an initial mechanical field of the hydrate reservoir by adopting FLAC3D software; s3, the TOUGH + HYDRATEsoftware and the FLAC3D software are subjected to data interfacecoupling, and a multi-field coupling model is constructed; s4, carrying out a triaxial creep test, obtaining a strain-time curve, carrying out fitting analysis, preferably selecting a creep constitutive model, and carrying out parameter calibration; s5, fitting by utilizing origin software to obtain a function model of the creep parameters changing along with the saturation degree of the hydrate; and S6, well periphery parameter monitoring is conducted in the drilling simulation process. The method is suitable for borehole wall instability risk analysis under the synergistic effect of hydrate decomposition and reservoir creep.
The present application relates to the field of gas separation, in particular to a method for separating gas mixture by using hydrate. The method for separating gas mixture by using hydrate comprises the following steps: loading a specific ice medium into a reactor, controlling the loading amount and the length-diameter ratio of the pipeline in the reactor, then charging the reactor with gas under certain temperature conditions, opening a back pressure valve to discharge gas when the pressure in the reactor reaches the required pressure for separation and hydrate begins to form, controlling the specific exhaust rate to slowly discharge gas, stopping the charging and opening the back pressure valve to accelerate the discharge when the highest temperature in the reactor is reached, closing the back pressure valve and opening another exhaust valve to make the hydrate decompose and release gas when the pressure in the reactor reaches normal pressure, thereby completing the gas separation. The method can improve the separation efficiency of the gas mixture and reduce energy consumption.
A method for dissociating hydrates 7 obstructing a pipeline 4 comprises the step of supplying electromagnetic energy in the form of microwaves 6 to the hydrate, wherein the frequency of the microwaves is varied within a predetermined range rather than being supplied at a single fixed frequency. Thus, the optimum frequency, i.e., that which provides the greatest possible transfer of energy to the water, considering the temperature, pressure and type of hydrate in each particular application, is scanned and the effectiveness and efficiency of the operation is improved. The range preferably encompasses the largest possible number of statistically significant optimum frequencies considering the various operating ranges of the pipeline and various possible types of hydrates. In another aspect, an initial step is provided where an exploratory scan is performed to determine what the specific optimum frequency is for an application. Then the frequency of the microwaves is adjusted and fixed at the determined specific optimum frequency. Also disclosed is a microwave generating device 1 for performing the frequency range scanning.
The application relates to a hydratedecomposition microcosmic gas-liquid migration identification test system, which comprises a lamellar hydrate preparation module, a collection module and a quantitative analysis module. The lamellar hydrate preparation module comprises a transparent experimental soil tank, a lamellar hydrate sample arranged on the transparent experimental soil tank and a transparent soil tank cover plate covered on the lamellar hydrate sample. The lamellar hydrate sample is in the shape of a round cake, and an annular water permeable stone is arranged on the outer side of the lamellar hydrate sample. The collection module collects images and parameters of the lamellar hydrate sample in the process of gas-liquid migration in real time, inputs the images and parameters into the quantitative analysis module for processing, and obtains effective seepage porosity of the lamellar hydrate sample. Compared with the prior art, the application can solve the problems of real-time observation difficulty, low key information extraction efficiency and quantitative analysis difficulty of microcosmic gas-liquid migration in the hydrate decomposition process.
The invention relates to the field of gas separation, in particular to a method for separating a gas mixture by using hydrate. According to the method for separating the gas mixture by utilizing the hydrate, a specific ice medium is filled into a reaction kettle, the filling amount of the ice medium and the length-diameter ratio of a pipeline in the reaction kettle are controlled, then the reaction kettle is inflated under a certain temperature condition, and when the pressure in the reaction kettle reaches the pressure required by separation and the hydrate starts to be generated, the gas mixture is separated. Opening the back pressure valve to exhaust outwards, firstly controlling a specific exhaust rate to slowly exhaust, immediately stopping inflating and opening the back pressure valve to accelerate exhaust along with the generation of the hydrate when the highest temperature is reached in the reaction kettle, and closing the back pressure valve and opening the exhaust valve on the other side after the normal pressure is reached in the reaction kettle, so that the hydrate is decomposed to release gas. Therefore, gas separation is completed. According to the method, the separation efficiency of the gas mixture can be improved, and meanwhile energy consumption is reduced.
The invention discloses a drilling fluidinvasion depth determination method and device considering hydratedecomposition. According to the technical scheme, a bidirectional feedback mechanism of hydratedecomposition and drilling fluid invasion is established, and the hydrate saturation, porosity, permeability and drilling fluid concentration of each reservoir position in each time step are dynamically calculated; the target drilling fluid concentration field on the hydrate reservoir prediction area is determined until the current time step is the preset invasion time, so that the drilling fluid invasion depth is determined according to the target drilling fluid concentration field and the preset concentration threshold value, the defect that a traditional model ignores reservoir physical property dynamic change is overcome, and the prediction accuracy is improved. And the accuracy and the reliability of the drilling fluid invasion depth are improved.
This invention relates to the field of natural gashydrate extraction technology, specifically to a method and system for analyzing near-wellbore reservoir stress state during depressurization extraction of hydrate reservoirs. The method includes: constructing a reservoir heterogeneity index field and a spatiotemporal evolution mode; constructing a cementation weakening coefficient field by combining the spatiotemporal evolution mode and hydratedecomposition kinetic data; determining a constitutive model correction factor based on the cementation weakening coefficient field and reservoir core mechanicstest data; solving for the disturbance stress amplification coefficient field; determining the equivalent stiffness of the wellbore-reservoir interface using wellbore structure data and dynamic pressure data; extracting a multi-field coupled response characteristic parameter set using the reservoir heterogeneity index field, spatiotemporal evolution mode, and equivalent stiffness of the wellbore-reservoir interface; identifying core mechanical control features by combining the cementation weakening coefficient field and the constitutive model correction factor; and completing stress state analysis based on the disturbance stress amplification coefficient field, the multi-field coupled response characteristic parameter set, and the core mechanical control features.
The present invention relates to the technical field of natural gashydrate mining and submarinecarbon dioxide storage, and in particular to a device and method suitable for macroscopic and microscopic research on residual cage structures of hydrates. Its technical solution is: including a gas-liquid injectionsystem, a fluid separation-blocking-unblocking core system, a fluid additional injection core system, a horizontal supercooling flow module, a vertical supercooling flow module and a cage structure microscopic research module. The present invention can efficiently manufacture residual cage structures of hydrates in hydratedecomposition water under high-pressure flow conditions, and then study the mechanism of the effect of residual cage structures on the secondary generation and rapid blockage of hydrates and the effective elimination method of residual cage structures; at the same time, it provides key experimental conditions for molecular-scale microscopic optical research on residual cage structures under high-pressure and low-temperature conditions; in addition, the present invention can also effectively simulate and systematically study hydrate-based submarinecarbon dioxide storage technology, providing theoretical support for its engineering application.
This invention belongs to the technical field of natural gashydrate reservoir exploitation, and relates to a method for determining the control mechanism of hydratedecomposition. This invention utilizes the temperature-pressure driving ratio to determine the control mechanism of hydratedecomposition. The steps are as follows: establishing a hydrate reservoir exploitation model; selecting the temperature and pressure at the point of complete decomposition during the hydrate reservoir exploitation process; calculating the temperature difference driving force and pressure difference driving force of hydrate decomposition based on the temperature and pressure; calculating the temperature difference driving coefficient and pressure difference driving coefficient during hydrate decomposition; and calculating the change in the temperature-pressure driving ratio during hydrate decomposition to determine the control mechanism of hydrate decomposition. This invention selects the point of complete hydrate decomposition for study and uses the temperature-pressure driving ratio to determine the control mechanism of hydrate decomposition. The method is simple and easy to implement, better reflects the control mechanism of hydrate decomposition, and can consider the dynamic changes of the control mechanism during hydrate decomposition at different times, which is the foundation for efficient development of hydrate reservoirs.
This invention belongs to the field of research on the landward distribution boundaries of natural gas hydrates. It discloses a method and system for studying the fate of methane at the landward distribution boundaries of marine natural gas hydrates, including: seismic interpretation and attribute analysis of present-day BSRs; seismic interpretation and attribute extraction of ancient BSRs to calculate their development depths; calculation of the hydrostatic pressure at the time of the ancient BSRs; simulation and prediction of the ancient BSR positions to determine the location of the landward distribution boundaries of the ancient hydrates; demarcation of the main areas of the study area; identification of whether submarine seepage features are present near the landward distribution boundaries of the hydrates, and interpretation of possible vertical and lateral fluid migration pathways and free gas accumulation; determination of the fate of methane at the boundaries and analysis of the main controlling factors; and calculation of the hydratedecomposition zone volume at the landward distribution boundaries of the hydrates based on the positions of the ancient and present BSRs. This invention identifies multiple types of methane fates at the landward distribution boundaries of marine natural gas hydrates, enabling a correct understanding of the environmental impacts of different methane fates and their effects on hydrate reservoirs.
The invention relates to a hydrategranulation purification system and method for removing radionuclides in nuclear wastewater. The system comprises a feeding subsystem, a granulationsystem and a detection subsystem, the granulation system is provided with a hydration reactor, the feeding subsystem and the granulation system are coupled at the hydration reactor, and the detection subsystem is arranged below the hydration reactor. The feeding subsystem is used for conveying gas raw materials and nuclear wastewater to the hydration reactor through a first gas pipeline and a first liquid pipeline respectively; the granulation system controls the temperature through a first refrigeration pipeline and outputs hydrate granules through a drain valve and a discharge pipeline; the detection subsystem is used for pushing the granules into a hydratedecomposition container for decomposition to obtain decomposed water, and an ion concentration tester is used for detecting the ion concentration so as to characterize the removal effect. The system realizes integrated operation of feeding, granulation and decomposition detection, has functions of fresh waterrecovery and nuclide removal, has high stability and is convenient for engineering amplification.
The application relates to a natural gashydratedecomposition process full-coupling numerical simulation method and device, wherein the method comprises the following steps: establishing a mass conservation model, an energy conservation model, a mechanical equilibrium model and a hydratedecomposition model of soil particles, hydrates, gas and water of natural gas hydrates in a decomposition process, constructing a heat-flow-force-chemistry full-coupling model of natural gas hydrates in the decomposition process, taking gas pressure, water pressure, temperature and displacement in different directions as basic unknown quantities of the model, and establishing a finite element weak integral form of the heat-flow-force-chemistry full-coupling model; performing numerical solution on the finite element weak integral form, and assembling a DEHydrate simulator based on a solution result to simulate an evolution trend of reservoir mechanical behavior of natural gas hydrates in the decomposition process. Therefore, the problems that existing hydrate decomposition simulators cannot realize complete coupling among seepage, hydrate phase change, heat transfer and geomechanics are solved.
The invention discloses a hydratedecompositionkinetic model establishment method which comprises the following steps: step 1, experimental design and data acquisition, calculation of a corresponding relation between the amount of undecomposed methane substances and time, and provision of a data basis for model establishment, step 2, establishment of a basic model, step 3, decomposition promotion correction, establishment of a correction model, and step 4, establishment of a hydratedecompositionkinetic model. The enhancement effect of the accelerant on the decomposition rate is quantified; 4, model verification is carried out; based on a Kim-Bishnoi model and a single-stage depressurization decomposition experiment of the methanehydrate, a decomposition kinetic model of the methane hydrate is deduced, the optimal value of the hydrate particle size D0 is determined by optimizing the methane hydrate depressurization decomposition model, fitting correction is conducted on the established model according to the decomposition experiment result, and the methane hydrate particle size D0 is obtained. And determining an optimal value of a parameter B related to the type and the mass concentration of the injection kinetic accelerator.
The present invention discloses a method for enhancing hydrate production and carbon dioxide storage through dual-horizontal well injection-production coupling, comprising: measuring and confirming target reservoir characteristic data, laying production wells and injection wells at different reservoir depths or in different saturation areas; reducing the reservoir pressure to a set bottom hole pressure through the production well to carry out production; alternately injecting flue gas and a kinetic promoter solution, and controlling the injection rate to maintain the temperature and pressure near the injection well below the methanehydratephase equilibrium line, displacing natural gas in the pores and stimulating hydratedecomposition; producing to the lower limit of the hydrate saturation for reservoir mechanical safety, and shutting down the production well; if the lower limit is not reached, monitoring the output composition, and shutting down the production well and stopping the alternating injection when a serious CO2 breakthrough occurs or the methane content in the produced gas is lower than a preset lower limit; injecting CO2-rich flue gas or liquid CO2 through the injection well to restore the reservoir pressure to the pre-production pressure, generating a mixed hydrate to solid-state seal CO2, and repairing the reservoir sediment skeleton.
The invention relates to a sea area natural gashydratewellbore flow guarantee and reservoir protection drilling fluidsystem and a preparation method and application thereof, and belongs to the technical field of deepwater shallow natural gashydrate exploitation. The drilling fluidsystem comprises the following components: natural seawater, NaCl, KCl, a blocking agent, a clay hydration inhibitor, a filtrate reducer, a flow pattern regulator, a density control agent, a hydrate double-effect inhibitor, a hydrate generation inhibitor and a hydrate decomposition inhibitor. The drilling fluidsystem provided by the invention has good rheological filtration performance at room temperature, the rheological capacity meets production requirements at low temperature, and meanwhile, the drilling fluid system has good clay hydration inhibition performance, can effectively inhibit reservoir hydrate decomposition and prevent secondary generation of wellbore hydrate, can prevent well leakage, reduces well control risks, and has good application prospects. The working efficiency is improved.
The invention provides a discrete element-based simulation method, device and medium for mechanical degradation of hydrate-containing sediment induced by hydratedecomposition, and the simulation method comprises the following steps: carrying out numerical triaxial or biaxial compression test on a hydrate-containing sediment sample, and calibrating mesoscopic parameters associated with a related contact model by combining a trial-and-error method; constructing a mechanical degradation model of the hydrate-containing sediment in the hydrate decomposition process based on discrete elements; in the mechanical degradation model, part of hydrate particles are randomly removed according to a set hydrate decomposition rate to simulate hydrate phase volume reduction, and hydrate cementation damage caused by decomposition is simulated by reducing a parallel cementation radius multiplier. The hydrate phase volume reduction and cementation damage effect are comprehensively considered in the hydrate decomposition process, the mechanical degradation behavior of the hydrate-containing sediment is accurately represented, and the method can be suitable for analyzing the mechanical characteristics of the hydrate-containing sediment with coexisting multiple occurrence forms and can be used for evaluating geological disasters and engineering risks in the hydrate exploitation process.