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Laminated body and conductive roller

A laminated body and resin layer technology, applied in layered products, shafts and bearings, electrical recording, etc., can solve problems such as deterioration of interlayer adhesion and easy curing shrinkage of the surface layer

Active Publication Date: 2020-06-12
株式会社アーケム
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the case of using a UV-curable resin for the surface layer, there is a possibility that when curing is performed by ultraviolet irradiation, curing shrinkage easily occurs in the surface layer, thus causing strain between the base layer and the surface layer, resulting in deterioration of interlayer adhesion

Method used

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  • Laminated body and conductive roller
  • Laminated body and conductive roller
  • Laminated body and conductive roller

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 to 16 and comparative example 1 to 8

[0139]

[0140] (i) Urethane acrylate oligomer (trade name: NX44-31, manufactured by Asia Industry Co., Ltd.) or ester-based urethane acrylate oligomer synthesized by the following synthesis method 1 was used as polymer components;

[0141] (ii) Use (meth)acrylate represented by any one of the following structural formulas (1) to (3) and general formula (1) (n=1 in general formula (1)) as the energy ray curable Resin (A);

[0142] (iii) using 2-methyl-1-(4-methylthiophenyl)-2-morpholinopropan-1-one (trade name: Irgacure.907, manufactured by BASF) as a photopolymerization initiator; and

[0143] (iv) using acrylamide represented by the following structural formula (4) or (meth)acrylate represented by any one of the following structural formulas (5) to (8) as other components,

[0144] A first resin composition was thus prepared in the compounding amounts shown in Table 1 and Table 2 below.

[0145] >

[0146]First, lactone-based (aliphatic polyester) diol (molecular weigh...

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Abstract

Provided are a laminate having improved interlayer adhesion, and a conductive roller comprising the same. The laminate includes at least two energy ray curable resin layers each formed by curing a resin composition with energy rays, wherein: the laminate includes an energy ray curable resin layer (1) and an energy ray curable resin layer (2 ); the first resin composition for forming the energy ray curable resin layer (1) includes an energy ray curable resin (A) having a hydrocarbon ring skeleton.

Description

technical field [0001] The present disclosure relates to a laminate and a conductive roller. Background technique [0002] Conventionally, in a conductive roller having an elastic layer containing polyurethane, a technique of providing a UV curable resin as a surface layer on a base layer to suppress toner filming and the like is known. In the case of using a UV curable resin for the surface layer, there is a possibility that curing shrinkage easily occurs in the surface layer when it is cured by ultraviolet irradiation, thereby causing strain between the base layer and the surface layer, resulting in deterioration of interlayer adhesion. [0003] In order to improve the interlayer adhesiveness, a technique of using a urethane acrylate oligomer having a weight average molecular weight of 6000 or more and acryloylmorpholine in the surface layer is known (see, for example, PTL 1). In this method, specific materials are used in the surface layer in order to improve the adhesio...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B27/30B32B27/40F16C13/00G03G15/00
CPCB32B27/30B32B27/40G03G15/00B32B27/08F16C13/00B32B2307/202
Inventor 佐野武宏
Owner 株式会社アーケム