Phosphonic acid-based polymer with strong adaptability and slump retention properties and its preparation method and application

An adaptable, phosphonic acid-based technology, which is applied in the field of phosphonic acid-based polymers and its preparation, can solve problems such as insufficient initial dispersion efficiency of concrete, low water-reducing rate slump performance, and slump damage.

An adaptable, phosphonic acid-based technology, which is applied in the field of phosphonic acid-based polymers and its preparation, can solve problems such as insufficient initial dispersion efficiency of concrete, low water-reducing rate slump performance, and slump damage.

CN107337765BActive Publication Date: 2020-10-23JIANGSU SOBUTE NEW MATERIALS +2
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  • Phosphonic acid-based polymer with strong adaptability and slump retention properties and its preparation method and application
  • Phosphonic acid-based polymer with strong adaptability and slump retention properties and its preparation method and application
  • Phosphonic acid-based polymer with strong adaptability and slump retention properties and its preparation method and application

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Experimental program
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preparation example Construction

[0063] (1) Preparation of ether polycarboxylate A

[0064] Mix 200g (0.2mol) of prenol-based polyoxyethylene ether (Mw=1000) and 60g of water into a 1000mL three-necked flask, raise the temperature to 55°C, and slowly add 51.4g of acrylic acid solution (70% concentration, 0.5 mol), hydrogen peroxide solution 5.0g (30% concentration), thioglycolic acid 14.1g, dropwise time 2h, after dropwise, continue reaction 4h, obtain ether type polycarboxylic acid mother liquor A, be colorless transparent solution, through Test, the conversion ratio of monomer a reaches 96%, and the weight average molecular weight of ether type polycarboxylate A is 22000.

[0065] (2) Pretreatment of Phosphonic Acid Monomer B

[0066] Take 23.4g (0.15mol) of compound I in a 200ml round bottom flask, add 10% water, stir evenly, slowly add caustic soda NaOH, adjust the pH value to 4.0, and obtain the solution of the key component phosphonic acid monomer B.

[0067] (3) Preparation of phosphonic acid-based p...

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Abstract

The invention discloses a phosphonate-base polymer with high adaptability and slump retaining properties, and a preparation method and application thereof. The phosphonate-base polymer has the following structural characteristics: the side chain is an ether type chain segment; and the polymer has two stages of adsorption groups, the primary adsorption group is a phosphonate or phosphite functional group, the secondary adsorption group is carboxyl, and the two functional groups are connected by an ester bond or amido bond. The weight average molecular weight of the phosphonate-base polymer with high adaptability and slump retaining properties is 10000-50000. The phosphonate-base polymer has a novel molecular structure, and thus, has the advantages of low doping amount, high water reducing rate, excellent slump retaining properties, and high sulfate and clay interference resistance. The preparation technique can implement industrialization, and thus, has broad market application space.

Description

technical field [0001] The invention relates to a phosphonic acid-based polymer with strong adaptability and slump-preserving performance and a preparation method thereof, belonging to the technical field of concrete admixtures. Background technique [0002] With the country's large-scale infrastructure construction, resources such as natural river sand and high-quality fly ash are increasingly depleted, artificial aggregates, coal gangue, desulfurization ash and other low-activity industrial wastes are gradually used in modern concrete, and polycondensed with sulfonic acid groups The traditional first and second generation water reducers based on substances and the third generation of high performance admixtures based on carboxyl polymers have increasingly prominent adaptability problems in new complex component systems, such as low initial dispersion efficiency, Due to a series of application problems such as large slump loss and high system viscosity, the control of concr...

Claims

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Application Information

Patent Timeline
23 Oct 2020
Publication
CN107337765B
IPC
C08F283/06; C08F220/06; C08F8/40; C04B24/26; C04B103/22; C04B103/30
CPC
C04B24/246; C04B2103/22; C04B2103/302; C04B2103/308; C08F8/40; C08F283/065; C08F220/06
Inventors
王涛; 冉千平