Phosphorus-free scale and corrosion inhibitor simultaneously effective for copper and carbon steel

A technology of scale and corrosion inhibitors and scale inhibitors, which is applied in the directions of scale removal and water softening, chemical instruments and methods, complexes/solubilizing agents, etc., can solve the problems of low scale inhibition rate, achieve low cost, and Scale effect good effect

Active Publication Date: 2017-11-24
TIANJIN SEA WATER DESALINATION & COMPLEX UTILIZATION INST STATE OCEANOGRAPHI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Patent 201010512464.2 discloses a phosphorus-free composite scale and corrosion inhibitor, containing sodium tetraborate, zinc gluconate, polyaspartic acid, polyepoxysuccinic acid, acrylic acid-hydroxypropyl acrylate c

Method used

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  • Phosphorus-free scale and corrosion inhibitor simultaneously effective for copper and carbon steel
  • Phosphorus-free scale and corrosion inhibitor simultaneously effective for copper and carbon steel

Examples

Experimental program
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Effect test

Embodiment 1

[0049] Tolyltriazole 0.5g, sodium tetraborate 15g, zinc gluconate 10g, zinc sulfate 8g, polyaspartic acid 3g, polyepoxysuccinic acid 10g and Tween-800.1g, other ingredients are deionized water , and made into a 200mL solution to obtain the corrosion and scale inhibitor of the present invention.

[0050] When the amount of corrosion and scale inhibitor is 4ml / L, the corrosion rate of copper is 0.0048mm / a, the corrosion rate of carbon steel is 0.072mm / a, and the scale inhibition rate is 92% when concentrated four times.

Embodiment 2

[0052] Dissolve 5g of sodium tetraborate, 15g of sodium gluconate, 10g of zinc chloride, 3g of acrylic acid, 10g of polyepoxysuccinic acid and Tween-601g in 200mL of deionized water to obtain component A; Dissolve 1 g in 10 mL of absolute ethanol to obtain component B, and then use it together with component A to obtain the corrosion and scale inhibitor of the present invention.

[0053] Under the condition that the dosage of corrosion and scale inhibitor is 4ml / L of component A and 0.01ml / L of component B, the corrosion rate of copper is tested to be 0.0033mm / a, the corrosion rate of carbon steel is 0.0149mm / a, and the concentration is four times The measured scale inhibition rate is 98%.

Embodiment 3

[0055] Dissolve 5g of sodium tetraborate, 10g of potassium gluconate, 12g of zinc sulfate, 8g of polyepoxysuccinic acid scale inhibitor and OP-100.5g in 200mL of deionized water to obtain component A; dissolve 2g of tolyltriazole Obtain component B in 15mL of absolute ethanol, and use it together with component A to obtain the corrosion and scale inhibitor of the present invention.

[0056] Under the condition that the dosage of corrosion and scale inhibitor is 4ml / L of component A and 0.01ml / L of component B, the corrosion rate of copper is tested to be 0.0025mm / a, the corrosion rate of carbon steel is 0.062mm / a, and the concentration is four times The measured scale inhibition rate was 91%.

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Abstract

The invention relates to a phosphorus-free scale and corrosion inhibitor simultaneously effective for copper and carbon steel. The scale and corrosion inhibitor comprises the following components in parts by weight: 5 to 15 parts of borate, 10 to 18 parts of gluconate, 8 to 12 parts of inorganic zinc salt, 0.5 to 2 parts of methyl benzotriazole, 8 to 19 parts of scale inhibitor, and 0.1 to 1 part of surfactant. The scale and corrosion inhibitor can protect copper and carbon steel of a system at the same time. After the scale and corrosion inhibitor is used, the corrosion speed of carbon steel is reduced to less than 0.02 mm/a, the corrosion speed of copper is reduced to less than 0.005 mm/a, and the inhibition rate can reach 98% or more. The scale and corrosion inhibitor has a good scale inhibition performance, and the scale inhibition rate is more than 90% in a fourfold concentration experiment. The provided scale and corrosion inhibitor solves the problems of scaling and corrosion of a system, the corrosion inhibiting performance and scale inhibiting effect are both better than national and industrial standards, moreover, the scale and corrosion inhibitor does not contain any phosphorus or rare earth element, zero discharge of phosphorus is realized, and the scale and corrosion inhibitor has a very high industrial value and generates good environment protection benefits.

Description

technical field [0001] The invention relates to the field of metal corrosion and protection and the field of industrial water treatment, in particular to a phosphorus-free scale and corrosion inhibitor which is effective for both copper and carbon steel. Background technique [0002] The recently released survey results show that the total cost of corrosion in my country's entire industry accounts for about 3.34% of the gross domestic product (GDP), reaching 2,127.82 billion yuan, which is equivalent to more than 1,555 yuan in corrosion costs for each citizen. Corrosion is a safety problem and a resource conservation problem, which needs to be solved urgently. Corrosion inhibitor is a chemical substance or a mixture of several chemical substances that can prevent or slow down the corrosion of metal surfaces when it exists in the environment (medium) in an appropriate concentration and form, and has been widely used in industrial water treatment. With the improvement of envi...

Claims

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Application Information

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IPC IPC(8): C02F5/12C02F5/10C02F5/08C23F11/08
CPCC02F5/105C02F5/125C23F11/08C23F14/02
Inventor 侯相钰
Owner TIANJIN SEA WATER DESALINATION & COMPLEX UTILIZATION INST STATE OCEANOGRAPHI
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