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Biomass-base hydrogel as well as preparation method and application thereof

A biomass and hydrogel technology, applied in chemical instruments and methods, water pollutants, water/sewage treatment, etc., can solve the difficulties in meeting the requirements of various application fields, hinder the progress of biomass-based hydrogel research, Biomass-based hydrogel does not have performance and other problems, and achieves the effects of short preparation time, solving difficult degradation problems, and easy operation

Active Publication Date: 2017-11-24
SOUTH CHINA AGRI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although some progress has been made in the research of biomass-based hydrogels, there are still many challenges in material preparation and practical application.
First, the current research on biomass-based hydrogels basically takes a single type of biomass as the research object, so the prepared biomass-based hydrogels do not have good performance for comprehensive applications in many aspects
Second, in terms of preparation, there are many factors that affect the preparation reaction of biomass resin materials, but there are few and inconsistent studies on this aspect, and there is still no systematic reference for the factors that affect the preparation of biomass-based hydrogels. Third, the performance of the currently researched biomass-based hydrogels has relatively large limitations, and it is difficult to meet the requirements of various application fields, the application range is limited, and the application cost is high.

Method used

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  • Biomass-base hydrogel as well as preparation method and application thereof
  • Biomass-base hydrogel as well as preparation method and application thereof
  • Biomass-base hydrogel as well as preparation method and application thereof

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Embodiment 1

[0054] 1 Pre-experiment

[0055] Before starting this subject research, a batch of biomimetic-based hydrogels synthesized with acrylamide and biomass or biochar as monomers under the action of initiator and cross-linking agent were selected. , CV, MB, MG) and heavy metal solutions (Cu 2+ , Pb 2+ , Zn 2+ 、Cd2+ ) carried out adsorption assay experiments, and finally screened out products that synthesized pseudo-biomass-based hydrogels from biomass with good adsorption effects on dyes and heavy metals.

[0056] 1.1 Preparation method of pseudo-biomass-based hydrogel

[0057] A brief description of the preparation method of the pseudo-biomass-based hydrogel used in the preliminary experiment is as follows:

[0058] Weigh 21g of acrylamide and 10g of biomass (or biochar) with a particle size of 200 mesh in a large beaker with a mass ratio of acrylamide and biomass (or biochar) of 2:1, add 100mL distilled water, stir well. Then place it on a constant temperature stirrer to hea...

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Abstract

The invention discloses biomass-base hydrogel as well as a preparation method and application thereof. The method comprises the following steps: sequentially mixing acrylic acid, a neutralizer, acrylamide and biomass, adding deionized water for dissolving, and carrying out constant-temperature stirring so as to obtain mixed liquid; and adding a mixed solution of an initiator and a cross-linking agent into the obtained mixed liquid, stirring, heating to 90-100 DEG C, naturally cooling and forming (or the solution naturally swells and forms after the temperature is heated to be above 100 DEG C while stirring), sequentially washing with deionized water, absolute ethanol and deionized water until the pH value of cleaned wastewater is nearly neutral, and carrying out constant-temperature drying, so as to obtain the biomass-base hydrogel. The method is simple and convenient in operation, a used instrument is simple, the time required by the preparation is short, the preparation cost is low, and the method has wide popularization basis; and by adding biomasses such as bamboos, cassava and eucalyptus sawdust, the problem that pure hydrogel is difficult to be degraded is solved, meanwhile, the production cost of the product is lowered, and the mechanical properties of the hydrogel are improved.

Description

technical field [0001] The invention belongs to the field of hydrogels, and in particular relates to a biomass-based hydrogel and its preparation method and application. Background technique [0002] Bio-based materials refer to a new class of materials manufactured by biological, chemical and physical means using renewable biomass, including crops, trees and other plants and their residues and contents as raw materials. It mainly includes bioplastics, bio-based platform compounds, biomass functional polymer materials, functional sugar products, wood-based engineering materials and other products, which are green, environmentally friendly, renewable and biodegradable. [0003] Hydrogels are a kind of polymers that are hydrophilic but insoluble in water. They swell rapidly in water to equilibrium, and dehydrate and deswell under certain conditions while still maintaining their original shape. A functional polymer material that combines water absorption, water retention and s...

Claims

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Application Information

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IPC IPC(8): C08J3/075C08F289/00C08F292/00C08F220/56C08F220/06C02F1/28C02F101/30C02F101/20C08L51/00C08L51/08
CPCC02F1/288C02F2101/20C02F2101/308C08F289/00C08F292/00C08J3/075C08J2351/00C08J2351/08C08F220/06C08F220/56
Inventor 许细薇蒋恩臣骆睿王明峰任永志孙焱李治宇
Owner SOUTH CHINA AGRI UNIV