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150°C heat-resistant cross-linked low-smoke halogen-free electronic wire material and manufacturing method thereof

An electronic wire, heat-resistant technology, applied in the field of 150 ℃ heat-resistant cross-linked low-smoke halogen-free electronic wire and its production, can solve the problem that tensile strength and elongation at break cannot meet the requirements of practical applications, elongation at break and The problems such as the unsatisfactory elongation rate under load, the reduction of tensile strength and elongation at break, etc., are beneficial to commercial promotion, low cost, and improved stability.

Active Publication Date: 2020-10-09
惠州市展创新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Moreover, its elongation at break and elongation under load have been improved to a certain extent, but for some occasions with special requirements on flexibility, its elongation at break and elongation under load still cannot meet the requirements
[0006] It can be seen from the above published documents that in order to achieve a certain flame retardant effect, the amount of inorganic fillers currently used in wire and cable insulation materials generally exceeds 50%, which brings about the problem that the mechanical properties are not good enough
Wang Yongchang and others also published the article "Research on Irradiation Cross-linked Halogen-free, Low Smoke, High Temperature and Flame Retardant Polyolefin Cable Materials" at the 9th Yangtze River Delta Science and Technology Forum Radiation Processing Sub-forum and 2012 Yangtze River Delta Radiation Federation. It is clearly pointed out that in order to make the material have obvious flame retardant effect without the use of auxiliary flame retardants, the content of magnesium hydroxide must reach more than 50%, but with the increase of magnesium hydroxide content, the tensile strength and elongation at break The rate decreases rapidly, especially when the magnesium hydroxide content is greater than 50%, the tensile strength and elongation at break have been unable to meet the requirements of practical applications.

Method used

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  • 150°C heat-resistant cross-linked low-smoke halogen-free electronic wire material and manufacturing method thereof
  • 150°C heat-resistant cross-linked low-smoke halogen-free electronic wire material and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-18

[0077] 150°C heat-resistant cross-linked low-smoke halogen-free electronic wire material, 18 sets of experiments were carried out according to the orthogonal experiment method, in which the components and weight ratios included in Example 1-Example 18 are listed in Table 1.

[0078] Table 1 Components and weight ratios included in Examples 1-18, wherein the particle size of magnesium hydroxide is 0.8 micron-1.2 micron, and the magnesium hydroxide is produced by chemical synthesis, and the purity is analytically pure.

[0079]

Embodiment 19

[0112] The method for making 150°C heat-resistant cross-linked low-smoke halogen-free electronic wire material, the method for preparing implementation 1 includes the following steps:

[0113] S1 Weigh each component according to the weight ratio and pour it into a high-speed mixer for stirring and preheating, and fully mix the components; the host speed is set at 340 rpm, and the preheating is divided into three stages. The stage temperature is 110°C, the second stage temperature is 120°C, and the third stage temperature is 130°C.

[0114] S2 Plasticize at constant temperature first, and then gradually lower the temperature to enter the next process; the plasticizing process is divided into six stages, the fourth to sixth stages maintain a temperature of 140°C, the seventh stage temperature drops to 130°C, and the second stage Eight stages are at 120°C and the ninth stage is at 110°C.

[0115] S3 Raise the temperature to form, granulate, and sieve to obtain the white electro...

Embodiment 20-36

[0120] The method for making 150°C heat-resistant cross-linked low-smoke halogen-free electronic wire material, Examples 20-36 are the preparation methods of Examples 2-18 respectively, the difference from Example 19 lies in the weight of each component weighed different.

[0121] The preparation method of Comparative Examples 1-3 is the same as that of Example 19, except that the weight of each component is different.

[0122] Examples 1-18 and Comparative Examples 1-3 were tested to obtain the following data.

[0123]

[0124] *Sample after cross-linking

[0125] Among them, the test method for elongation at break is ASTM D638, the test method for tensile residual rate, residual rate at break and thermal deformation after aging is UL1581, and the test method for thermal elongation is IEC 60811-2-1.

[0126] Can find by above test, in the mechanical performance test of the present invention, tensile residual rate and fracture residual rate are all obviously higher than 8...

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Abstract

The invention discloses a 150 DEG C heat-resistant crosslinked low-smoke halogen-free electronic wire material and a preparation method thereof and aims to solve the problem that in order to achieve a certain flame-retardant effect, the usage of inorganic filler in an existing wire and cable insulating material exceeds 50% universally, so that the mechanical property is not good enough, particularly, the flexibility of the electronic wire material is affected as the elongation at break is relatively low. The key point of the technical scheme is as follows: the material comprises the following components in parts by weight: 20-40 parts of EVA, 5-10 parts of PE, 1-5 parts of grafted PE, 30-65 parts of inorganic filler, 0.2-1.8 parts of an antioxidant, 0.2-1.8 parts of a crosslinking agent and 0.2-1.8 parts of a plasticizer. By adopting the formula, the flame retardance of the electronic wire material is improved, the elongation at break of the electronic wire material is improved, and the mechanical property of the electronic wire material is ensured.

Description

technical field [0001] The invention relates to the field of electronic wire materials for special cables, in particular to 150°C heat-resistant cross-linked low-smoke and halogen-free electronic wire materials and a manufacturing method thereof. Background technique [0002] With the rapid development of the economy, wires and cables are widely used in various industries and fields. With the frequent occurrence of electrical fire accidents, the flame retardant problem of wires and cables has gradually attracted the attention of countries all over the world. When the cable burns, it releases a large amount of smoke and toxic and corrosive gas, which is a risk factor in a fire. It hinders people's safe evacuation and fire fighting work during a fire, causing serious loss of life and property. At the same time, with the development of the communication industry, the automobile industry and the computer industry, especially in many occasions such as aviation wires, automobile ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/08C08L23/06C08L51/06C08K13/02C08K3/22C08K5/12C08K5/372C08K5/3492C08J3/28
CPCC08J3/28C08J2323/08C08J2423/06C08K2003/2224C08K2201/003C08L23/0853C08L2201/02C08L2201/08C08L2201/22C08L2203/202C08L2205/03C08L2312/06C08L23/06C08L51/06C08K13/02C08K3/22C08K5/12C08K5/372C08K5/34924
Inventor 李鹏芳胡春林胡伟林
Owner 惠州市展创新材料科技有限公司
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