Photochromic glass with high elasticity modulus and preparation method thereof

A technology of photochromic glass and high elasticity, applied in glass manufacturing equipment, glass molding, manufacturing tools, etc., can solve problems such as unsuitability for large-scale mass production, deterioration and failure, and changes in absorption spectrum, and achieve good photochromic performance , good photochromic performance, and the effect of reducing manufacturing costs

Inactive Publication Date: 2018-01-19
(CNBM) BENGBU DESIGN & RES INST FOR GLASS IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing photochromic glass is to prepare a photochromic film on a glass substrate, but the film material has problems of damage, deterioration and failure, and the process is complicated
[0003] Inorganic photochromic glass materials are formed by adding photosensitive materials to the matrix glass, which are melted and heat-treated. The discoloration mechanism is mainly due to the change of the material structure of the photosensitive material after being irradiated by light, resulting in a change in the absorption spectrum, and then the color is obvious. change, there is no problem of film damage and failure; however, the current inorganic photochromic glass is mainly added with rare earth metals, which is expensive and not suitable for large-scale mass production; and the elastic modulus of the glass is also low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The invention provides a photochromic glass with high modulus of elasticity, which comprises the following components by weight percentage: 8% Li 2 O, 15% Al 2 o 3 , 72% SiO 2 , 4% MgO, 1% CaO and 0.5% WO 3 .

[0026] The present invention also provides a method for preparing photochromic glass with high elastic modulus, comprising the following steps:

[0027] S1, ingredients,

[0028] According to the composition of the above-mentioned present embodiment, glass raw materials are configured;

[0029] S2, mixing and ball milling,

[0030] Put the prepared glass raw materials into a ball mill to fully mix and ball mill, and the ball milling time is controlled at 50 minutes;

[0031] S3, melting,

[0032] Melt the ground glass material in a furnace at a melting temperature of 1400°C and keep it warm for 2 hours to clarify and homogenize the glass material;

[0033] S4, molding,

[0034] Pouring the glass frit liquid into the mold for molding;

[0035] S5, annea...

Embodiment 2

[0038] The invention provides a photochromic glass with a high modulus of elasticity, which comprises the following components by weight percentage: 4% Li 2 O, 20% Al 2 o 3 , 2% B 2 o 3 , 58% SiO 2 , 3.5% K 2 O, 2% MgO, 0.5% CaO, 10% Na 2 O and 2% WO 3 .

[0039] The present invention also provides a method for preparing photochromic glass with high elastic modulus, comprising the following steps:

[0040] S1, ingredients,

[0041] According to the composition of the above-mentioned present embodiment, glass raw materials are configured;

[0042] S2, mixing and ball milling,

[0043] Put the prepared glass raw materials into a ball mill to fully mix and ball mill, and the ball milling time is controlled at 60 minutes;

[0044] S3, melting,

[0045] Melt the ground glass material in a furnace at a melting temperature of 1400°C and keep it warm for 2 hours to clarify and homogenize the glass material;

[0046] S4, molding,

[0047] Pouring the glass frit liquid int...

Embodiment 3

[0051] The invention provides a photochromic glass with a high modulus of elasticity, which comprises the following components by weight percentage: 2% Li 2 O, 15% Al 2 o 3 , 7% B 2 o 3 , 56% SiO 2 , 4% K 2 O, 1% MgO, 15% Na 2 O and 5% WO 3 .

[0052] The present invention also provides a method for preparing photochromic glass with high elastic modulus, comprising the following steps:

[0053] S1, ingredients,

[0054] According to the composition of the above-mentioned present embodiment, glass raw materials are configured;

[0055] S2, mixing and ball milling,

[0056] Put the prepared glass raw materials into a ball mill to fully mix and ball mill, and the ball milling time is controlled at 60 minutes;

[0057] S3, melting,

[0058] Melt the ground glass material in a melting furnace at a melting temperature of 1450°C and keep it warm for 3 hours to clarify and homogenize the glass material liquid;

[0059] S4, molding,

[0060] Pouring the glass frit liquid ...

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PUM

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Abstract

The invention discloses photochromic glass with a high elasticity modulus. The photochromic glass comprises the following components in percentage by weight: 2-8% of Li2O, 15-24% of Al2O3, 0-7% of B2O3, 50-72% of SiO2, 0-8% of K2O, 0-4% of MgO, 0-1% of CaO, 0-15% of Na2O and 0.5-8% of WO3; and the photochromic glass is prepared according to the following steps: preparing materials: preparing the glass raw materials according to the above components; performing mixing and ball milling: loading the prepared glass raw materials into a ball mill, and performing full mixing and ball milling; performing melting: melting the milled glass raw materials in a smelting furnace, and enabling the glass material liquid to be clarified and uniform; performing forming: pouring the glass material liquid into a mold for forming; and performing annealing: placing the formed glass sample into an annealing furnace, and performing annealing to finally obtain the photochromic glass with the high elasticity modulus. The prepared photochromic glass provided by the invention has the characteristics of the high elasticity modulus, excellent color developing effects, fast color change response time, low costs, simple and convenient manufacture and the like.

Description

technical field [0001] The invention relates to the technical field of special glass manufacturing, in particular to a photochromic glass with high elastic modulus and a preparation method thereof. Background technique [0002] Photochromic glass is a glass that changes its color when exposed to light of the appropriate wavelength, and returns to its original color when the light source is removed. In the existing photochromic glass, a photochromic film is prepared on a glass substrate, but the film material has problems of damage, deterioration and failure, and the process is complicated. [0003] Inorganic photochromic glass materials are formed by adding photosensitive materials to the matrix glass, which are melted and heat-treated. The discoloration mechanism is mainly due to the change of the material structure of the photosensitive material after being irradiated by light, resulting in a change in the absorption spectrum, and then the color is obvious. Change, there ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C3/091C03C4/02C03B19/02C03B25/00
Inventor 彭寿马立云王萍萍曹欣石丽芬倪嘉韩娜
Owner (CNBM) BENGBU DESIGN & RES INST FOR GLASS IND CO LTD
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