Reusable water writing paper capable of realizing long-time keeping after color developing
A technology of water writing paper and color development, applied in special paper, papermaking, paper, etc., can solve the problems of unsuitable for long-term reading, short retention time, and non-recyclable paper
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Embodiment 1
[0050] 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene is used as hydrochromic fluoran dye, ethanol is used as organic solvent, and 1,3-propanediol is used as polyhydroxy Moisturizing additive, polyethylene glycol as binder, 2,4-dichloro-6-hydroxy-s-triazine sodium hardener as performance enhancing additive. Dissolve 0.0005g of fluorane hydrochromic dye 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene in 100mL of ethanol; 40g of 1,3-propanediol, Dissolve 20g of polyethylene glycol in 150g of water, then mix and stir the two evenly, and then add 2g of hardening agent 2,4-dichloro-6-hydroxy-s-triazine sodium salt to obtain a pink color developing solution;
[0051] The chromogenic solution is coated on the paper base with a passivation layer, and after the solvent evaporates, a white water writing paper can be obtained. After water writing, the displayed color is rose red, which can last for about 10 minutes.
[0052]The erasing process is through wetting-...
Embodiment 2
[0054] Use 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene as hydrochromic fluoran dye, ethanol as organic solvent, chitosan as polyhydric moisturizing additive , Polyethylene glycol is used as a binder, and 2,4-dichloro-6-hydroxy-s-triazine sodium salt hardening agent is used as a performance-enhancing additive. 0.0005g fluorane hydrochromic dye 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene was dissolved in 50mL ethanol; 20g chitosan, 20g poly Dissolve ethylene glycol in 150g of water, then mix and stir the two evenly, then add 2g hardening agent 2,4-dichloro-6-hydroxy-s-triazine sodium salt to obtain a pink color developing solution;
[0055] The chromogenic solution is coated on the paper base with a passivation layer, and after the solvent evaporates, a white water writing paper can be obtained. After water writing, the color of the display is rose red, which can last for about a day.
[0056] The erasing process is through wetting-heating treatme...
Embodiment 3
[0058] 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene is used as hydrochromic fluoran dye, ethanol is used as organic solvent, and glycerol is used as polyhydric moisturizing additive , polyethylene glycol as a binder, 2,4-dichloro-6-hydroxy-s-triazine sodium salt hardening agent as a performance-enhancing additive, and surfactant p-isozinc-based phenol polyoxyethylene ether as a performance-enhancing additive. Dissolve 0.002g of fluorane hydrochromic dye 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene in 100mL of ethanol; 40g of glycerol, 20g of poly Dissolve ethylene glycol in 150g of water, then mix the two evenly, then add 2g hardening agent 2,4-dichloro-6-hydroxy-s-triazine sodium salt, 3g p-isozincylphenol polyoxyethylene ether to get a pink color color developing solution;
[0059] The chromogenic solution is coated on the paper base with a passivation layer, and after the solvent evaporates, a white water writing paper can be obtained. After wa...
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