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Reusable water writing paper capable of realizing long-time keeping after color developing

A technology of water writing paper and color development, applied in special paper, papermaking, paper, etc., can solve the problems of unsuitable for long-term reading, short retention time, and non-recyclable paper

Active Publication Date: 2018-01-19
JILIN UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, although the existing water writing paper (such as Chinese patent 201610444113. X) can be reused, the handwriting and / or patterns written or printed will gradually disappear with the volatilization of water, resulting in too short a retention time, which is not suitable for long-term use. read and record
And Chinese patent (200410040260.8) reports a kind of water writing paper that can be maintained for a long time after color development, although the pattern and / or handwriting after color development can be maintained for a long time, but because it cannot fade away, the paper cannot be recycled.

Method used

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  • Reusable water writing paper capable of realizing long-time keeping after color developing
  • Reusable water writing paper capable of realizing long-time keeping after color developing
  • Reusable water writing paper capable of realizing long-time keeping after color developing

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene is used as hydrochromic fluoran dye, ethanol is used as organic solvent, and 1,3-propanediol is used as polyhydroxy Moisturizing additive, polyethylene glycol as binder, 2,4-dichloro-6-hydroxy-s-triazine sodium hardener as performance enhancing additive. Dissolve 0.0005g of fluorane hydrochromic dye 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene in 100mL of ethanol; 40g of 1,3-propanediol, Dissolve 20g of polyethylene glycol in 150g of water, then mix and stir the two evenly, and then add 2g of hardening agent 2,4-dichloro-6-hydroxy-s-triazine sodium salt to obtain a pink color developing solution;

[0051] The chromogenic solution is coated on the paper base with a passivation layer, and after the solvent evaporates, a white water writing paper can be obtained. After water writing, the displayed color is rose red, which can last for about 10 minutes.

[0052]The erasing process is through wetting-...

Embodiment 2

[0054] Use 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene as hydrochromic fluoran dye, ethanol as organic solvent, chitosan as polyhydric moisturizing additive , Polyethylene glycol is used as a binder, and 2,4-dichloro-6-hydroxy-s-triazine sodium salt hardening agent is used as a performance-enhancing additive. 0.0005g fluorane hydrochromic dye 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene was dissolved in 50mL ethanol; 20g chitosan, 20g poly Dissolve ethylene glycol in 150g of water, then mix and stir the two evenly, then add 2g hardening agent 2,4-dichloro-6-hydroxy-s-triazine sodium salt to obtain a pink color developing solution;

[0055] The chromogenic solution is coated on the paper base with a passivation layer, and after the solvent evaporates, a white water writing paper can be obtained. After water writing, the color of the display is rose red, which can last for about a day.

[0056] The erasing process is through wetting-heating treatme...

Embodiment 3

[0058] 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene is used as hydrochromic fluoran dye, ethanol is used as organic solvent, and glycerol is used as polyhydric moisturizing additive , polyethylene glycol as a binder, 2,4-dichloro-6-hydroxy-s-triazine sodium salt hardening agent as a performance-enhancing additive, and surfactant p-isozinc-based phenol polyoxyethylene ether as a performance-enhancing additive. Dissolve 0.002g of fluorane hydrochromic dye 5'-amino-9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthene in 100mL of ethanol; 40g of glycerol, 20g of poly Dissolve ethylene glycol in 150g of water, then mix the two evenly, then add 2g hardening agent 2,4-dichloro-6-hydroxy-s-triazine sodium salt, 3g p-isozincylphenol polyoxyethylene ether to get a pink color color developing solution;

[0059] The chromogenic solution is coated on the paper base with a passivation layer, and after the solvent evaporates, a white water writing paper can be obtained. After wa...

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PUM

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Abstract

The invention relates to reusable water writing paper capable of realizing long-time keeping after color developing. The water writing paper comprises a base material and a color developing layer covering the base material, wherein the base material is a known material such as paper, a polyester film, a polyvinyl chloride film or a polypropylene film which usually can be used for writing or printing. The reusable water writing paper is characterized in that the color developing layer is prepared from components in parts by weight as follows: 0.0005-2 parts of fluorane water-induced chromotropic dye, 100-300 parts of a solvent, 1-60 parts of a polyhydroxyl moisturizing additive, 0-10 parts of a functional aid and 0.01-20 parts of an adhesive; the fluorane water-induced chromotropic dye is shown in a formula in the description. The problem of short retention time of writing and / or patterns on conventional water writing paper is solved, the water writing paper can be recycled, and great contribution is made to saving of paper and sustained development of resources.

Description

technical field [0001] The invention relates to a reusable water writing paper which can be maintained for a long time after color development, and belongs to the field of reusable materials. Background technique [0002] Most writing or printing paper is discarded after being used once, causing serious waste. From the perspective of protecting the environment and reusing resources, the recycling of paper is particularly important. At present, reusable water writing paper is a very good way to solve the above problems because it replaces ink with water, is easy to operate, easy to carry and can be used many times. However, although the existing water writing paper (such as Chinese patent 201610444113.X) can be reused, the handwriting and / or patterns written or printed will gradually disappear with the volatilization of water, causing its retention time to be too short and not suitable for long-term use. Read and record. And Chinese patent (200410040260.8) reports a kind of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H27/00D21H19/42D21H21/28D21H21/30C09K9/02B41M5/50
CPCY02W30/80
Inventor 盛兰席冠张晓安陈俏男王洪泽李建平马超卢志凯
Owner JILIN UNIV
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