31 results about "Fluoran" patented technology

The invention discloses a thermo-sensitive paper coating suitable for a backing-paper-free label and a preparation method and application of the thermo-sensitive paper coating, and relates to the technical field of composite materials. According to the thermal-sensitive paper coating provided by the invention, a specific thermosensitive composition is adopted to construct a color developing substance of a color developing layer, 3-(3-methylureido) phenyl-4-methyl benzenesulfonate is compounded with a specific fluorane dye, and the obtained thermosensitive composition can form a covalent bond with silicone oil, so that the silicone oil can be promoted to be cured to form a compact coating, and the thermal-sensitive paper coating has the advantages that the thermal-sensitive paper coating has a good color developing effect; and the silicone oil isolation layer and the thermosensitive composition have excellent binding force, so that the coating provided by the invention has excellent color development performance and higher curing rate, the curing time is as low as 15 seconds or less, the glossiness is 46.7 GU or more, and the dynamic saturation color development performance is 0.96 or more.

The invention relates to the technical field of photochromic functional materials, in particular to a novel organic photochromic functional material and a preparation method thereof. The method comprises the following steps: S1, mixing a fluorane dye A with a molecular formula (1) and an alcohol protonation solvent B according to a volume ratio of 1: (1-5); s2, carrying out solvothermal reaction on the mixed solution at 150-200 DEG C to obtain a reactant, and collecting a precipitate; and S3, drying the precipitate in the step S2 to obtain the organic photochromic functional material. The novel organic photochromic functional material is simple in preparation process and green, and is yellow in darkness or a fluorescent lamp; under an ultraviolet lamp, the color is bright orange, and the yellow color and the bright orange color are reversibly interchanged.

The invention discloses thermochromic dye as well as preparation and application thereof, and belongs to the technical field of fine chemical engineering. The preparation method comprises the following steps: firstly, taking a fluorane dye as a raw material, and introducing an amino group into a fluorane dye structure by utilizing a reaction between lactone and alkyl diamine; and then preparing the thermochromic dye by utilizing the aldehyde amine reaction between the amino fluorane dye and the benzyloxy hydroxy benzaldehyde. The parent structure of the prepared thermochromic dye fluorane is connected with an alkyl chain and a benzylbenzaldehyde structure through a stable covalent bond, and latent heat of phase change comes from Van der Waals force between methylene on the alkyl chain and conformation overturning energy of the alkyl chain in the structure. And two benzene rings in the benzyloxy hydroxy benzaldehyde structure are used for hindering temperature crystallization below the melting point, so that the material melting and crystallization processes are regulated and controlled.

The present application relates to a kind of fluorane compound, thermosensitive dye dispersion and its preparation method, the fluorane compound has the structure shown in formula I, wherein, R is selected from 4-trifluoromethylphenyl, n-hexyl, aminomethyl, -CH2CH2OH, -CH2CH2Br, -CH2OCH3 Or one of esterified PEO groups.The fluorane compound of the present application can be used as thermosensitive dye, and the 1,2,3-triazole structure can enhance the color ability of fluoran mother nucleus.

The present invention provides a reversible thermochromic composition which exhibits black color upon coloration and colorless color upon discoloration, and has excellent light resistance, by using a fluoran derivative having a specific structure as an electron-donating chromogenic organic compound, and a reversible thermochromic microcapsule pigment containing the reversible thermochromic composition. The means for solving the problem is a reversible thermochromic composition comprising: (a) a fluoran derivative having a specific structure as an electron-donating chromogenic organic compound, (b) a compound having a specific structure as an electron-accepting compound, and (c) a reaction medium which allows the electron transfer reaction between the (a) component and the (b) component to occur reversibly in a specific temperature range, and a reversible thermochromic microcapsule pigment containing the reversible thermochromic composition.

The invention provides a scarlet pigment dye-derived carbon quantum dot and a preparation method and application thereof in the anti-counterfeiting field, and relates to the technical field of organic photochromic materials.The preparation method comprises the steps that scarlet pigment dye is dissolved in an organic solvent, then the scarlet pigment dye solution is subjected to a solvothermal reaction in a reaction kettle, and the scarlet pigment dye-derived carbon quantum dot is obtained; reacting to obtain a solution containing the carbon quantum dots; the bright red pigment dye is 6-(N-ethyl-4-toluidine)-2-methylfluorane, and the bright red pigment dye is 6-(N-ethyl-4-toluidine)-2-methylfluorane. According to the invention, the excitation and emission of the fluorescent substance are controlled by photostimulation, so that the fluorescent substance generates dynamic fluorescence color change, dynamic anti-counterfeiting is realized, and the anti-counterfeiting grade is improved.

The invention relates to a fluorine-containing fluorane compound, a light-resistant thermosensitive dye and a preparation method and application thereof, belongs to the technical field of fine chemical engineering, and solves the problem of insufficient light resistance of a thermosensitive material of the existing thermosensitive dye. The molecular structure of the fluorane compound provided by the invention contains fluorine. The preparation method comprises the following steps: step 1, adding 2-(2-hydroxy-4-diethylaminobenzoyl) benzoic acid, 3, 5-bis (trifluoromethylphenol) and mixed strong acid into a reaction container, and carrying out condensation reaction; step 2, cooling, adding an organic solvent into a reaction system, then slowly adding an alkaline solution, heating, refluxing and stirring, and carrying out ring-closure reaction to obtain a reaction solution; and 3, separating the reaction liquid to obtain an organic phase, washing the organic phase to be neutral, separating the liquid, collecting the neutral organic phase, carrying out reduced pressure distillation to remove the organic solvent, and drying to obtain a fluorine-containing fluorane compound solid.

The present application relates to a kind of fluorine-containing fluorane compound, light-resistant thermosensitive dye and preparation method and application, belong to fine chemical technology field, solve the problem of insufficient light resistance of existing thermosensitive dye heat-sensitive material.The fluorane compound of the present application contains fluorine in molecular structure.Preparation method includes the following steps: step 1: 2-(2-hydroxy-4-diethylaminobenzoyl) benzoic acid, 3,5-bistrifluoromethylphenol and mixed strong acid are added to reaction vessel, condensation reaction occurs;Step 2: cooling, organic solvent is added to the reaction system, then slowly add alkaline solution, heating reflux stirring, ring-closing reaction occurs, to obtain reaction liquid;Step 3: the reaction liquid is separated, to obtain organic phase, water washing to neutral, separation, collect the organic phase of neutral, remove organic solvent by distillation under reduced pressure, dry, to obtain fluorine-containing fluorane compound solid.

The present invention discloses the preparation and application of a light-resistant fluoran-type color-changing dye, belonging to the field of fine chemical technology. The present invention optimizes the structure of commercial fluoran dyes to provide a method for preparing a full-color spectrum fluoran dye with excellent light resistance. While maintaining the color development, color change sensitivity, and color change fatigue resistance of the dye, the light resistance is improved, with the light resistance time increased by 8-28 hours, an increase of 50%-80%. This solves the main problem of the application of such temperature-sensitive materials in the field of functional textiles, expands the application field, and is beneficial to economic benefits.

The present invention discloses a method for preparing a highly sensitive, reversible thermochromic fluoran dye and a compound thereof, belonging to the fields of fine chemicals and materials science. The present invention designs a series of novel fluoran dyes and develops two-component reversible thermochromic dyes and microcapsules prepared based on these novel fluoran dyes. The resulting two-component reversible thermochromic dyes and microcapsules can achieve thermochromism without the addition of bisphenol A. Compared to traditional three-component color-changing systems, this avoids the effects of bisphenol A's oxidative properties on the color-changing system. While optimizing the cost structure, this achieves improved reversible thermochromic performance, promoting the application of thermochromic systems in high-precision, high-value-added fields.

The invention discloses a preparation method of a fadable ink ingot, and relates to the technical field of ink ingots. Comprising the following steps: step 1, taking a yellow fluorane dye 3, 6-dimethoxyfluorane, adding a color developing agent powder, and mechanically stirring until the color is developed to obtain a yellow fluorane pigment; step 2, taking cyan fluorane dye 3-diethylamino-6-methyl-7-phenylaminofluorane, adding the color developing agent powder, and mechanically stirring until the color is developed to obtain a cyan fluorane pigment; step 3, taking a red fluorane dye 6-(N-ethyl-4-toluidine)-2-methylfluorane, adding the color developing agent powder, and mechanically stirring until the color is developed to obtain a red fluorane pigment; 4, mixing the yellow fluorane pigment, the cyan fluorane pigment and the red fluorane pigment according to a certain proportion to obtain a mixed black pigment; 5, taking a certain amount of glue, heating to prepare a glue solution, sequentially adding a black pigment, an auxiliary agent and the like, and uniformly mixing to obtain a blank; and 6, rubbing the obtained blank into ink fruits according to specifications, pressing the ink fruits into an ink mold for forming, and airing to finally obtain the ink ingot. The defects that ink stains contaminate clothes and calligraphy practicing paper is difficult to decolor are overcome.

The invention relates to a static color development test method for thermo-sensitive paper, belongs to the technical field of fine chemical engineering, and solves the problem that a static color development test cannot be completed due to the fact that the proportion of a thermo-sensitive dye dispersion liquid, a color developing agent dispersion liquid and a sensitizer dispersion liquid adopted in an existing thermo-sensitive static color development test method is improper. The method comprises the following steps: a, respectively preparing a thermosensitive dye dispersion liquid, a color developing agent dispersion liquid and a sensitizer dispersion liquid; b, taking 8-12 parts of thermosensitive dye dispersion liquid, 12-18 parts of color developing agent dispersion liquid, 6-9 parts of sensitizer dispersion liquid, 5-10 parts of kaolin and 8-12 parts of deionized water, mixing and stirring to obtain mixed coating liquid; c, coating paper with the mixed coating liquid, carrying out a static color development test, and recording a color density value; in the step a, raw materials for preparing the thermosensitive dye dispersion liquid comprise fluorine-containing fluorane compounds with the structure shown in the formula I.

The invention provides an electrochromic material, a preparation method of an electrochromic device and the electrochromic device.The electrochromic material comprises a solvent, a black dye, an ionic conductive agent, electrogenerated alkali-producing molecules, a plasticizer, a high-molecular polymer and electrogenerated acid-producing molecules; the situation that the black fluorane dye moves to other film layers in the color changing process of the electrochromic device, and consequently the subsequent color changing reaction cannot be conducted can be prevented, and therefore the cycling stability of the electrochromic device can be improved.

The present invention relates to the technical field of fine chemicals. Disclosed are preparation and a use of a lightfast fluoran color-changing dye. According to the present invention, by optimizing the structure of a commercial fluoran dye, a preparation method for a full-color-spectrum fluoran dye having good lightfast performance is provided; and on the basis of keeping the properties of the dye, such as the color development and color changing sensitivity and the color changing fatigue resistance, the lightfast performance of the dye is improved, the lightfast duration is prolonged by 8-28 hours and is increased by 50%-80%, and the main problem of the use of such temperature-sensitive materials in the field of functional textiles is solved, thereby expanding the application field and increasing economic benefits.

The application discloses application of a fluorane-based discoloring dye in improving material light resistance, and belongs to the technical field of fine chemical industry.The application provides a series of fluorane-based discoloring dyes containing different electron-withdrawing groups, and the series of discoloring dyes has good light resistance performance.Therefore, the application mainly designs a fluorane dye containing electron-withdrawing substituents, that is, on the basis of an existing fluorane dye parent structure, electron-withdrawing groups such as nitro, fluorine, chlorine, bromine and iodine are introduced, the electron-withdrawing performance of the electron-withdrawing groups is utilized, the electron cloud distribution state of the dye molecular structure is changed, and the light resistance performance is improved.

The present application relates to the technical field of pigment material, and particularly relates to a water-caused fading pigment block and application thereof. The pigment block is in a solid block structure, and is prepared from leuco dye, anhydrous calcium sulfate, organic weak acid, water-soluble binder, humectant, dispersant, preservative, pH regulator and deionized water, wherein the leuco dye is a fluoran dye with a lactone ring closed structure, and the anhydrous calcium sulfate is used as an inorganic forming skeleton material. By controlling the component ratio and particle size range, the forming property of the pigment slurry and the system stability are considered. The pigment block can be coated on the surface of a water-impermeable substrate by kneading or externally applying oxalic acid aqueous solution, and can be removed by water wiping or washing. The pigment block has stable structure, simple preparation process, is suitable for use in a block form, and meets the requirements of repeated writing or coating and water washing removal.

The invention provides an electrochromic material, an electrochromic composition and an electrochromic device, and relates to the technical field of chemical materials. The electrochromic material has a viologen unit with electrochemical activity, the viologen unit is partially reduced under a negative voltage, the charge density is increased, fluorane containing different substituent groups is subjected to a ring closing reaction, and the electrochromic material is changed into a ring-closed colorless state in 35 ms from different colors shown by fluorane containing different substituent groups under the condition that a negative voltage of-1.8 V is applied to the electrochromic material. A standard electron transfer rate constant of a reaction of the viologen unit on the surface of an electrode is very large, the viologen unit is connected with a fluorane part, electrons can be further rapidly transferred to the fluorane part, the fast color changing speed is guaranteed, the electrochemical active viologen unit has very good oxidation reduction cycle stability, and the electrochemical activity of the viologen unit is improved. Therefore, the excellent cycling stability of the whole electrochromic material is ensured, and after 1000 times of cycling, the absorbance change attenuation can be less than 10%.

This invention provides an electrochromic material, an electrochromic composition, and an electrochromic device, relating to the field of chemical materials technology. The electrochromic material contains electrochemically active viologen units. These viologen units are reduced under a negative voltage, increasing their charge density and causing fluoranes with different substituents to undergo ring-closure reactions. The different colors exhibited by the fluoranes with different substituents in the electrochromic material change to a colorless state within 35 ms under a negative voltage of -1.8V. The viologen unit itself has a large standard electron transfer rate constant on the electrode surface. Connecting it to the fluorane moiety further enables rapid electron transfer to the fluorane moiety, ensuring a fast color change. The electrochemically active viologen unit itself has excellent redox cycle stability, thus ensuring the excellent cycle stability of the overall electrochromic material. After 1000 cycles, the absorbance change decreases by less than 10%.

A highly marketable reversibly thermochromic composition that provides a black color during color development by using a fluoran derivative having a specific structure as an electron-donating color-developing organic compound, turns colorless during decoloration, and is excellent in contrast between a colored state and a decolored state and a microcapsule pigment encapsulating the same. A reversibly thermochromic composition including: (a) a fluoran derivative having a specific structure as an electron-donating color-developing organic compound; (b) an electron-accepting compound; and (c) a reaction medium which reversibly induces an electron transfer reaction between the component (a) and the component (b) in a specific temperature range, and a reversibly thermochromic microcapsule pigment encapsulating the same.

The application discloses a gel color developing patch for indicating VOCs in a sickroom based on photocatalysis and a preparation method thereof. The gel color developing patch comprises, in percentage by mass, 1.4-2.0% of graphite phase carbon nitride g-C3N4, 0.2-1.0% of fluoran dye, 5.0-7.0% of polyvinyl alcohol (PVA) and 90.0-93.4% of distilled water. The polyvinyl alcohol is dissolved in deionized water to obtain a PVA solution; a nanometer flake aqueous solution of graphite phase carbon nitride g-C3N4 and the fluoran dye are added into the PVA solution, and the mixture is stirred at room temperature until uniform, to obtain a reaction liquid; the reaction liquid is transferred into a glass container and sealed, and is repeatedly frozen and thawed for multiple times, to obtain the gel color developing patch. The gel color developing patch is used for visual detection of VOCs in air in a sickroom of a hospital, and is helpful for monitoring emission of VOCs in a hospital room and finding a pollution source.

A highly marketable reversibly thermochromic composition that provides a black color during color development by using a fluoran derivative having a specific structure as an electron-donating color-developing organic compound, turns colorless during decoloration, and is excellent in contrast between a colored state and a decolored state and a microcapsule pigment encapsulating the same. A reversibly thermochromic composition including: (a) a fluoran derivative having a specific structure as an electron-donating color-developing organic compound; (b) an electron-accepting compound; and (c) a reaction medium which reversibly induces an electron transfer reaction between the component (a) and the component (b) in a specific temperature range, and a reversibly thermochromic microcapsule pigment encapsulating the same.

The application discloses a thermochromic dye and a preparation and application thereof, and belongs to the technical field of fine chemical industry. The application firstly introduces amino groups into a fluoran dye structure by using the reaction between a lactone and an alkyl diamine with the fluoran dye as raw material; and then, the aldehyde amine reaction between the amino fluoran dye and phenolic hydroxyl benzaldehyde is utilized to prepare a lactam thermochromic dye. The application utilizes the characteristics that the phenolic hydroxyl in the structure of the thermochromic dye releases protons at low temperature and obtains protons at high temperature, and utilizes the flexibility of the alkyl chain in the structure of the alkyl diamine, so that the ring-opening and ring-closing reactions of the lactam structure in the fluoran dye structure are caused, the size of the conjugated system of the dye is adjusted, and the color change of the dye is realized.

The invention belongs to the technical field of wood composite materials, and particularly relates to a polyurea color-changing agent microcapsule and a preparation method thereof, a formaldehyde-free compound adhesive, a reversible thermochromic formaldehyde-free recombined decorative veneer and a preparation method thereof. The preparation method comprises the following steps: mixing a water-soluble emulsifier with water to obtain a water phase; a compound color changing agent and a diisocyanate compound are mixed, an oil phase is obtained, and the compound color changing agent comprises thermosensitive fluorane dye, a color developing agent and an organic solvent; emulsifying the water phase and the oil phase to obtain an emulsion; and carrying out polymerization reaction on the low-activity polyamine compound and the high-activity polyamine compound and the emulsion to obtain the polyurea color-changing agent microcapsule. According to the color-changing agent, the microcapsules and the polymer are cross-linked, so that the interface bonding force and the dispersion stability are improved, the stability and the weather resistance of the color-changing agent are remarkably improved, and meanwhile, the damage to the microcapsules during high-pressure gluing of the recombined decorative material is reduced. According to the recombined decorative veneer, the thermochromic function is achieved, the decoration performance of the recombined decorative veneer is improved, intelligence and interactivity are improved, and zero addition of formaldehyde is achieved.

The present invention relates to a novel fluoran compound and a preparation method thereof, belonging to the technical field of thermosensitive dyes. The compound is intended to address at least one of the following problems with existing pink dyes: a high color development temperature, a dull color after development, low color density, a complex synthesis method, and low purity. The present invention synthesizes a novel fluoran compound having a conjugated structure with a parent core. The compound has a relatively low color development temperature, developing color at temperatures of approximately 70°C, enhancing the color development ability of the fluoran core, resulting in a pink color that is more vivid and has a higher color density.

The present invention aims to disclose an orange thermal colorant and a preparation method thereof. The orange thermal colorant is 3-dibutylamino-7-ethoxyacylfluoran. Compared with the prior art, the reaction raw materials are readily available, the production process is simple, and the product is stable. Not only can orange thermal paper, film, and thermal color-forming materials be produced, but also thermal color-forming materials of any color can be produced by color matching, thereby achieving the purpose of the present invention.

The invention discloses a preparation method of a high-sensitivity reversible thermochromic fluorane dye and a compound thereof, and belongs to the technical field of fine chemical engineering and material science. A series of novel fluorane dyes are designed, the bi-component reversible thermochromic dye and the microcapsule prepared on the basis of the novel fluorane dyes are developed, the obtained bi-component reversible thermochromic dye and the microcapsule can achieve thermochromism on the basis that bisphenol A is not added, and compared with a traditional three-component color changing system, the thermochromic effect is good. According to the invention, the influence of the oxidizability of bisphenol A on the color-changing system is avoided, the cost structure is optimized, the upgrading of the reversible thermochromic performance is completed, and the application of the thermochromic system in the fields of high precision and high added value is promoted.

The invention relates to the technical field of chemical engineering, in particular to an N, N-dihexyl-3-methoxyaniline pure product, a preparation method and application. According to the method, in a polar aprotic solvent, inorganic base is used as a catalyst, 3-methoxyaniline and alkyl halide are catalyzed to perform alkylation reaction to obtain a product, and then the product is purified; the polar aprotic solvent is one or more of N, N-dimethyl formamide, dimethyl sulfoxide, N-methyl pyrrolidone or acetonitrile; the inorganic base is one or more of carbonate or hydroxide; the alkyl halide is one or more of alkyl bromide, alkyl chloride or alkyl iodide. The method has the advantages of mild reaction conditions, good selectivity and few byproducts; a green and economic process route suitable for large-scale production is provided for efficient synthesis of the N, N-dihexyl-3-methoxyaniline, and a technical support is provided for industrialization of the high-color-density fluorane dye.

The invention relates to a light-resistant thermosensitive dye dispersion liquid as well as a preparation method and application thereof, belongs to the technical field of fine chemical engineering, and solves the problem that a thermosensitive material of the existing thermosensitive dye is insufficient in light resistance. The thermosensitive dye dispersion liquid is prepared from the following raw materials in parts by weight: 8 to 12 parts of fluorine-containing fluorane compounds, 1 to 5 parts of PVA-205 and 15 to 25 parts of deionized water, the fluorine-containing fluorane compound has a structure as shown in a formula I,

The present invention aims to disclose a green thermal colorant and a preparation method thereof. The green thermal colorant is 3-dibutylamino-7-dibenzylfluoran. Compared with the prior art, the reaction raw materials are readily available, the production process is simple, and the product is stable. Not only can green thermal paper, film, and thermal color-forming materials be produced, but also thermal color-forming materials of any color can be produced by color matching, thereby achieving the purpose of the present invention.

The invention discloses thermochromic dye as well as preparation and application thereof, and belongs to the technical field of fine chemical engineering. The preparation method comprises the following steps: firstly, by taking a fluorane dye as a raw material, introducing an amino group into a fluorane dye structure by utilizing a reaction between lactone and alkyl diamine; and then preparing the lactam thermochromic dye by utilizing an aldehyde amine reaction between the amino fluorane dye and the phenolic hydroxyl benzaldehyde. By utilizing the characteristics that phenolic hydroxyl groups in a thermochromic dye structure release protons at low temperature and obtain protons at high temperature and utilizing the flexibility of alkyl chains in an alkyl diamine structure, a lactam structure in a fluorane dye structure is subjected to ring opening and ring closing reactions, the size of a conjugated system of the dye is adjusted, and the color change of the dye is realized.