The invention discloses a high-gloss thermo-sensitive paper and a production method thereof. The production method comprises the following steps of coating precoating paint on a body paper to obtain a precoated paper, compounding the precoated paper and a sheet material coated with color layer paint, drying, and separating the sheet material to obtain the high-gloss thermo-sensitive paper. The production method avoids a press polishing process. The high-gloss thermo-sensitive paper has a gloss degree higher than 40%. The precoating comprises molochite, calcium carbonate, an adhesive, a dispersing agent, a lubricant, a water repellent agent and a thickener. The color layer comprises a color agent, a color-developing agent, a sensitizer, a grinding assistant, a lubricant, an adhesive, molochite, calcium carbonate and a stabilizer. The high-gloss thermo-sensitive paper retains color-developing performances and aging resistance of the traditional thermo-sensitive paper, has excellent appearance and surface strength, a paper gloss degree more than 40% (at a temperature of 75 DEG C, GB/T8941-2007), and has high smoothness without press polishing and satisfactory thickness.