The invention firstly provides a structure of environment-friendly bottomless paper type thermo-sensitive paper. The structure comprises a base material, and a thermo-sensitive
coating and a
silicone oil layer which are sequentially laminated on one surface of the base material, the thermosensitive
coating comprises a color developing layer, a pre-
coating layer and a bottom coating layer which are laminated in sequence, and the bottom coating layer is laminated on one surface of the base material; secondly, a
coating system is provided, and a color developing agent comprises 4, 4 '-
sulfonyl diphenol; the invention also provides a preparation method which is used for preparing the thermo-sensitive paper by adopting the structure and the
coating system, and comprises the following steps: coating the color developing layer on the surface of the pre-coating layer by using
curtain coating; a novel structure is designed, a basis is provided for the self-
curling release performance of the thermo-sensitive paper, a
coating system uses 4, 4 '-sulfonyldiphenol, so that the
color saturation, the light resistance and the stability of the thermo-sensitive paper can be improved, the thermo-sensitive paper does not react with
silicone oil, the release performance is improved, a
curtain coating method is adopted based on the structure and the coating
system, and the self-
curling release performance of the thermo-sensitive paper is improved. And the coating uniformity, color development and other properties of the thermo-sensitive paper are effectively improved, and the environment-friendly thermo-sensitive paper which is fast in reaction, bright in color and high in definition during printing is integrally formed.