Adhesive composition, adhesive agent, adhesive sheet and display
A display and adhesive technology, applied in the direction of adhesive type, ester copolymer adhesive, film/sheet adhesive, etc., can solve the problem that the touch panel cannot be driven normally, and achieve the effect of inhibiting migration
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[0073] (5) Preparation of adhesive composition
[0074] Adhesive composition P can be prepared by the following method: prepare (meth)acrylate polymer (A), the obtained (meth)acrylate polymer (A) and the silane coupling agent (B) ) and mix, while adding crosslinking agent (C) and additives as required.
[0075] The (meth)acrylate polymer (A) can be produced by polymerizing a mixture of monomer units constituting the polymer by a normal radical polymerization method. The polymerization of a (meth)acrylate polymer (A) can be performed by a solution polymerization method etc. using a polymerization initiator as needed. Examples of the polymerization solvent include ethyl acetate, n-butyl acetate, isobutyl acetate, toluene, acetone, hexane, methyl ethyl ketone, and the like, and two or more of them may be used in combination.
[0076] As a polymerization initiator, an azo compound, an organic peroxide, etc. are mentioned, and 2 or more types may be used together. Examples of az...
Embodiment 1
[0131] 1. Preparation of (meth)acrylate copolymer
[0132] A (meth)acrylate polymer (A) was prepared by copolymerizing 60 parts by mass of 2-ethylhexyl acrylate, 20 parts by mass of methyl methacrylate, and 20 parts by mass of 2-hydroxyethyl acrylate. When the molecular weight of this (meth)acrylate polymer (A) was measured by the method mentioned later, it was 600,000 in weight average molecular weight (Mw).
[0133] 2. Preparation of Adhesive Composition
[0134] 100 parts by mass of the (meth)acrylate polymer (A) obtained in the above step 1 (value converted into solid content; the same applies below), 3-mercaptopropane as a silane coupling agent (B) having a mercapto group Cocondensate of methyltrimethoxysilane and methyltriethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., trade name "X-41-1810", oligomer type, mercapto group equivalent: 450 g / mole ) 0.05 parts by mass, and 0.23 parts by mass of trimethylolpropane-modified toluene diisocyanate (manufactured by ...
Embodiment 2~10、 comparative example 1~10
[0150] Except that the type and ratio of the silane coupling agent (silane coupling agent (B) and other silane coupling agents with mercapto groups) and the ratio of the crosslinking agent (C) are changed as shown in Table 1, the same as in Example 1 An adhesive sheet was produced in the same manner. In addition, regarding Comparative Examples 7 to 10, N,N-bis(2-ethylhexyl)-(4 or 5)-methyl-1H-benzotriazole-1-methylamine (manufactured by BASF Corporation, trade name "IRGMET 39") was used as a rust inhibitor and was blended in the adhesive composition in the proportion shown in Table 1.
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