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A kind of polyethylene composition and application and laser sintering method and three-dimensional article

A laser sintering and polyethylene technology, which is used in manufacturing, solid material additive processing, additive processing, etc., can solve the problem of not meeting the mechanical performance test requirements of molded parts, the strength and rigidity of nylon-12 powder and polystyrene powder. Low, unable to meet the performance requirements and other problems, to achieve the effect of large tensile strain at break, smooth surface, high deformation temperature under load

Active Publication Date: 2020-01-17
CHINA PETROLEUM & CHEM CORP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, the strength and rigidity of nylon-12 powder and polystyrene powder are low, and the products formed by SLS technology cannot meet the mechanical performance test requirements of some molded parts or cannot meet the performance requirements for direct use as final products

Method used

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  • A kind of polyethylene composition and application and laser sintering method and three-dimensional article
  • A kind of polyethylene composition and application and laser sintering method and three-dimensional article
  • A kind of polyethylene composition and application and laser sintering method and three-dimensional article

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Embodiment approach

[0024] In the present invention, the particle size of the inorganic filler can vary within a wide range. According to a preferred embodiment of the present invention, the particle size of the inorganic filler is 6.5-23 μm, more preferably 6.5-18 μm. The particle size of the inorganic filler can also be in "mesh". For example, the particle size of the inorganic filler is 2.6-25 μm, and the corresponding particle size is 500-5000 mesh. The particle size of the inorganic filler is preferably 600-2000 mesh, more preferably 800-2000 mesh.

[0025] In the present invention, the particle size of the inorganic filler can be controlled by sieving. The means of sieving are well known to those skilled in the art. For example, the inorganic filler with a particle size of 500-5000 mesh can be sieved through a 500-mesh sieve first, and then sieved through a 5000-mesh sieve, and the inorganic filler left on the 5000-mesh sieve is Inorganic fillers that meet particle size requirements.

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Embodiment 1

[0049] This embodiment is used to illustrate the polyethylene composition provided by the present invention and its preparation method and application.

[0050] (1) Preparation of polyethylene composition

[0051] The ultra-high molecular weight polyethylene with a viscosity-average molecular weight of 3.5 million is air-selected to control the particle size of the ultra-high molecular weight polyethylene to 40-100 μm. The silicon dioxide is sieved to control the particle size of the silicon dioxide to be 6.5-18 μm. 9000 grams of ultra-high molecular weight polyethylene selected by wind, 1000 grams of silicon dioxide screened out, 10 grams of antioxidant 1010, and 20 grams of antioxidant 168 were mixed uniformly by a high-speed stirrer to prepare polyethylene Composition A1.

[0052] (2) Selective laser sintering

[0053] Selective laser sintering was carried out with polyethylene composition A1 as raw material. At the beginning of molding, the molding cylinder workbench i...

Embodiment 2

[0055] This embodiment is used to illustrate the polyethylene composition provided by the present invention and its preparation method and application.

[0056] (1) Preparation of polyethylene composition

[0057] The ultra-high molecular weight polyethylene with a viscosity-average molecular weight of 3 million is subjected to winnowing, and the particle size of the ultra-high molecular weight polyethylene is controlled to be 40-100 μm. The glass microspheres are sieved to control the particle size of the glass microspheres to be 6.5-18 μm. 9300 grams of ultra-high molecular weight polyethylene selected by wind, 700 grams of glass microspheres screened out, 15 grams of antioxidant 1010, and 10 grams of antioxidant 168 were mixed uniformly by a high-speed stirrer to prepare polyethylene Composition A2.

[0058] (2) Selective laser sintering

[0059] Selective laser sintering was carried out from polyethylene composition A2. At the beginning of molding, the molding cylinder...

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Abstract

The invention relates to the field of selective laser sintering, and discloses a polyethylene composition and application thereof, a laser sintering method and a three-dimensional product. The polyethylene composition contains granular super-macromolecular polyethylene and granular inorganic filler, wherein the viscosity average molecular weight of the super-macromolecular polyethylene is 1.5 to 5.0 millions; the particle size of the super-macromolecular polyethylene is 20 to 200mu m; the particle size of the inorganic filler is 2.6 to 25mu m. The polyethylene composition is subject to selective laser sintering to prepare the three-dimensional product, and the three-dimensional product has the advantages of smoother and more rigid surface, and strong abrasion-resistant property.

Description

technical field [0001] The invention relates to the field of selective laser sintering, in particular to a polyethylene composition and application, a laser sintering method and a three-dimensional product. Background technique [0002] Selective Laser Sintering (SLS) is one of the most widely used rapid prototyping technologies at present. It uses solid powder as raw material and adopts the layering-superposition principle to directly manufacture three-dimensional entities from CAD models. Theoretically, any Powders whose viscosity decreases when heated can be used as SLS sintering materials, and a wide range of materials is one of the important factors for the SLS process to be widely used in various fields. Repeated irradiation of newly applied layers in a constant sequence with this method enables easy and rapid fabrication of three-dimensional products. [0003] In addition, SLS products can obtain molded parts with high strength and good toughness without injection mo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08K3/36C08K7/20C08K5/134C08K5/526B33Y70/00B33Y10/00B29C64/153B33Y80/00
CPCB33Y10/00B33Y70/00C08K3/36C08K5/1345C08K5/526C08K7/20C08K2201/003C08L2201/08C08L2207/068C08L23/06
Inventor 张清怡张赪宗贵升李蕾衣惠君
Owner CHINA PETROLEUM & CHEM CORP