Cardable hydrophobic polyolefin fibres comprising cationic spin finishes
A technology of spinning oil and hydrophobicity, applied in the direction of single-component polyolefin rayon, fiber type, fiber treatment, etc., can solve problems such as poor antistatic properties
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Embodiment 1
[0140] Embodiment 1 (comparative example)
[0141] A kind of with anionic antistatic agent (neutralized C 16 ~C 18 alcohol phosphate, the majority of which is neutralized stearyl phosphate) spin finish treated silicone-free fibers. The cohesion length of the fiber web was 1.75 m.
[0142] A comparison of Example 1 with Examples 4, 5 and 7 shows the effect of changing the anionic antistatic agent to a cationic antistatic agent when the fibers were not treated with a silicone compound to improve their hydrophobicity. The liquid absorption time of the fibers increased from about 10 minutes (Example 1) to 1 hour to over 24 hours for the other Examples. For non-woven fabrics, the water repellency increased from 1.5 cm to 3-5 cm, and the penetration time increased from less than 10 seconds to more than 300 seconds (it should be noted that in all penetration tests, if the liquid does not penetrate the non-woven fabric after 300 seconds, it will aborted). It can be seen that the ...
Embodiment 2
[0143] Embodiment 2 (comparative example)
[0144] The fibers were treated with a second spin finish with an antistatic agent, which was very viscous (34mPa's) and formed a large amount of stable foam, so the finish could not be properly controlled. This also causes the uneven distribution of spinning oil on the surface of the fiber, which affects the hydrophobicity of the fiber (liquid absorption time) and the hydrophobicity of the nonwoven fabric (permeation time 11 seconds, water repellency 0.5cm). These values are much worse than, for example, the values of Examples 4 and 8, which have very low viscosity spin finishes.
Embodiment 3
[0145] Embodiment 3 (comparative example)
[0146] Silicone-containing fibers were prepared using the same anionic antistatic agent as in Example 1 and a large amount of silicone. The fibers have good hydrophobicity, but have limited web cohesion, so only moderate combability. At a "normal" carding speed of 100m / min, the hydrophobicity is good (breakthrough time 300 seconds), while when the carding speed is slightly higher, such as 151m / min, the breakthrough time is greatly reduced, only about 41 seconds, the reason The fiber distribution in the fiber web is uneven. The cohesion length of the fiber web was 1.75 m.
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