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A fast fluidized bed reactor, device and method for preparing propylene and C4 hydrocarbons from oxygen-containing compounds

A fluidized-bed reactor and the technology of the reactor are applied in the direction of producing hydrocarbons from oxygen-containing organic compounds, carbon compound catalysts, chemical instruments and methods, etc., and can solve the problems of low reaction rate of ethylene alkylation and the like

Active Publication Date: 2021-12-31
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0012] The present invention aims at the problem of low ethylene alkylation reaction rate in the process of preparing propylene and C4 hydrocarbons from methanol, and provides a new method and device for increasing the ethylene alkylation reaction rate

Method used

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  • A fast fluidized bed reactor, device and method for preparing propylene and C4 hydrocarbons from oxygen-containing compounds

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Experimental program
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Embodiment 1

[0061]This case is a comparative case, using figure 1 The device shown, but reactor gas-solid separator 1 (4) is not included in the fast fluidized bed reactor (1), and the regeneration riser (24) is directly connected to the dilute phase of the fast fluidized bed reactor (1) Area.

[0062] The fast fluidized bed reactor (1) contains 3 reactor feed distributors (3-1~3-3), the reactor heat collector (6) is placed outside the reactor shell (2), and the reactor steam The level of the inlet of lifter (8) is at the height of 2 / 3 dense phase zone. The reaction conditions in the dense phase zone of the fast fluidized bed reactor (1) are: the apparent linear velocity of the gas is about 3.0m / s, the reaction temperature is about 400°C, the reaction pressure is about 150kPa, and the bed density is about 80kg / m 3 .

[0063] The reaction conditions in the regeneration zone of the fluidized bed regenerator (14) are: the apparent linear velocity of the gas is about 1.0m / s, the regenerati...

Embodiment 2

[0070] use figure 1 In the shown device, the fast fluidized bed reactor (1) contains 3 reactor feed distributors (3-1~3-3), and the reactor heat collector (6) is placed in the reactor shell (2) Externally, the level of the inlet to the reactor stripper (8) is at the level of 2 / 3 of the dense phase zone. The reaction conditions in the dense phase zone of the fast fluidized bed reactor (1) are: the apparent linear velocity of the gas is about 3.0m / s, the reaction temperature is about 400°C, the reaction pressure is about 150kPa, and the bed density is about 80kg / m 3 .

[0071] The reaction conditions in the regeneration zone of the fluidized bed regenerator (14) are: the apparent linear velocity of the gas is about 1.0m / s, the regeneration temperature is about 650°C, the regeneration pressure is about 150kPa, and the bed density is about 350kg / m 3 .

[0072] The catalyst contains SAPO molecular sieve, the carbon content of the spent catalyst is about 7%, and the carbon conten...

Embodiment 3

[0079] use figure 1 In the shown device, the fast fluidized bed reactor (1) contains 4 reactor feed distributors (3-1~3-4), and the reactor heat collector (6) is placed in the reactor shell (2) Externally, the level of the inlet to the reactor stripper (8) is at the level of 3 / 4 of the dense phase zone. The reaction conditions in the dense phase zone of the fast fluidized bed reactor (1) are: the apparent linear velocity of the gas is about 5.0m / s, the reaction temperature is about 360°C, the reaction pressure is about 200kPa, and the bed density is about 50kg / m 3 .

[0080] The reaction conditions in the regeneration zone of the fluidized bed regenerator (14) are: the apparent linear velocity of the gas is about 1.2m / s, the regeneration temperature is about 700°C, the regeneration pressure is about 200kPa, and the bed density is about 300kg / m 3 .

[0081] The catalyst contains SAPO molecular sieve, the carbon content of the spent catalyst is about 8%, and the carbon conten...

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Abstract

The invention relates to a fast fluidized bed reactor, device and method for preparing propylene and C4 hydrocarbons from oxygen-containing compounds. The unit consists of a fast fluidized bed reactor and a fluidized bed regenerator for regenerating the catalyst. The method comprises: a) passing the raw materials containing oxygenated compounds from n reactor feed distributors into the dense-phase zone of the fast fluidized bed reactor, contacting with the catalyst to generate the stream containing the target product and the carbon-containing treated Raw catalyst; b) The stream containing the target product flowing out from the fast fluidized bed reactor is sent to the product separation system to separate and obtain components such as propylene, C4 hydrocarbons, light components, and more than 70wt.% of the light components are obtained by fast The reactor feed distributor at the bottom of the fluidized bed reactor returns to the dense phase area of ​​the fast fluidized bed reactor, and ethylene and oxygen-containing compounds undergo alkylation reaction under the action of the catalyst to produce propylene and other products. The method and device of the invention increase the reaction rate of ethylene alkylation, and the production capacity per unit volume of the reactor is high.

Description

technical field [0001] The invention relates to the field of chemical catalysis, in particular to a method and a device for preparing propylene and C4 hydrocarbons from oxygen-containing compounds. Background technique [0002] Propylene and butadiene are important chemical raw materials, which are generally obtained from naphtha cracking and steam cracking. The main source of propylene is ethylene co-production of propylene and refinery by-product propylene, while the main source of butadiene is the further processing of C4 by-products produced in the ethylene cracking process. In recent years, methanol-to-olefin (MTO) technology, methanol-to-propylene (MTP) technology, ethane dehydrogenation to ethylene technology, and propane dehydrogenation to propylene technology have achieved rapid development, and the global olefin raw material has a clear trend of lightening. This will lead to a tight supply of C4 resources, so it is necessary to develop a process that can produce p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J8/24B01J8/26C07C1/20C07C11/06C07C11/16
CPCB01J8/0055B01J8/1836B01J8/1863B01J8/228B01J8/24B01J8/26C07C1/20C07C2529/85B01J2208/00017B01J2208/00991B01J2208/00911B01J2208/00539C07C11/06C07C11/16Y02P20/584Y02P30/20Y02P30/40
Inventor 叶茂张涛何长青张今令王贤高唐海龙贾金明赵银峰刘中民
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI