Spherical mesoporous composite material and supported catalyst and preparation method thereof
A supported catalyst and composite material technology, applied in the field of mesoporous materials, can solve problems such as poor thermal stability and hydrothermal stability, low ethylene polymerization activity, and affect the loading effect, so as to achieve stable mesoporous structure, improve fluidity, Apply handy effects
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[0033]The present invention also provides a preparation method of the spherical mesoporous composite material, which comprises the following steps:
[0034] (1) providing a mesoporous molecular sieve material having a one-dimensional hollow spherical channel structure or preparing a filter cake of the mesoporous molecular sieve material having a one-dimensional hollow spherical channel structure as component a;
[0035] (2) providing silica gel or a filter cake for preparing silica gel as component b;
[0036] (3) mixing the component a and the component b and performing the first ball milling, mixing the obtained first ball milling slurry with water to make a slurry, and then performing the second ball milling to obtain the second ball milling slurry, and The second ball mill slurry is spray-dried and then screened by cyclone separation technology;
[0037] Wherein, the above steps make the spherical mesoporous composite material have an average particle size of 21-29 micron...
Embodiment approach
[0047] The present invention has no particular limitation on the conditions of the first mixed contact. For example, the conditions of the first mixed contact generally include: the temperature may be 10-60° C., preferably 10-20° C.; the time may be 10-72° C. hours, preferably 10-30 hours; pH value can be 1-7, preferably 3-6. In order to be more conducive to the uniform mixing of various substances, according to a preferred embodiment of the present invention, the first mixing and contacting is performed under stirring conditions.
[0048] In the present invention, the crystallization conditions include: the temperature can be 30-150°C, preferably 40-80°C; the time can be 10-72 hours, preferably 20-30 hours. According to a preferred embodiment, the crystallization is carried out by hydrothermal crystallization.
[0049] In step (1), in the above-mentioned process of preparing the filter cake of the mesoporous molecular sieve material with one-dimensional hollow spherical pore...
Embodiment 1
[0086] This example is used to illustrate the spherical mesoporous composite material and the supported catalyst of the present invention and the preparation method thereof
[0087] (1) Preparation of spherical mesoporous composites
[0088] Add 1 g (0.00017 mol) of template agent P123 and 1.69 g (0.037 mol) of ethanol to 28 mL of pH=4.4 acetic acid and sodium acetate buffer solution, stir at 15°C until the template agent is completely dissolved, add 6 g (0.05 mol) of trisodium Methylpentane was added to the above solution, and after stirring at 15 °C for 8 hours, 2.13 g (0.014 mol) of tetramethoxysilane was added to the above solution. After stirring at 15 °C for 20 hours, the solution was transferred to the agate lining After being crystallized in an oven at 60 °C for 24 hours, the reaction kettle was filtered and washed with deionized water for 4 times, and then suction filtered to obtain a filter cake A1 of mesoporous molecular sieve material with a one-dimensional hollow ...
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