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A stretchable high-performance zn-MNO 2 Preparation method of battery

A high-performance, battery technology, applied in battery electrodes, secondary batteries, climate sustainability, etc., can solve the problems of complex preparation process, inability to large-scale production, and high cost, and achieve simple preparation process, low cost, and high efficiency. The effect of stretchability

Active Publication Date: 2019-10-11
JIAXING HENGWEI BATTERY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] Based on the above, on the premise of obtaining excellent battery performance, the present invention proposes the following technical scheme to solve the current problems of complex preparation process, high cost and impossibility of large-scale production, in order to obtain a stretchable high-performance Zn -MnO 2 Battery

Method used

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  • A stretchable high-performance zn-MNO  <sub>2</sub> Preparation method of battery
  • A stretchable high-performance zn-MNO  <sub>2</sub> Preparation method of battery
  • A stretchable high-performance zn-MNO  <sub>2</sub> Preparation method of battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Take some commercial sponges, first clean them with deionized water, and then dry them in an oven to obtain sponges with a clean surface; then put them into the prepared PDDA solution with a concentration of 0.1% for stirring, and stir for 10 minutes Finally, take out the sponge and turn it over in the oven so that PDDA is evenly coated on the surface of the sponge. Put the coated sponge into silver nanowires with a concentration of 1mg / ml and 0.2 mg / ml graphene mixed solution, after stirring for 1 hour, remove the sponge and transfer it to an oven for continuous rotation, so that the silver nanowires and graphene are evenly coated on the surface of the sponge; finally, the above coated The sponge was coated with a layer of MnO on its surface by conventional soaking and electrodeposition methods respectively. 2 and Zn, after the experiment is completed, the obtained coating is dried and then transferred to a vacuum oven for PDMS permeation encapsulation to obtain the fi...

Embodiment 2

[0023] Take some commercial sponges, first clean them with deionized water and then dry them in an oven to obtain sponges with a clean surface; put the cleaned sponges into a concentration of 1 mg / ml prepared at a volume ratio of 1:1 In the mixed solution of copper nanowires and 0.2mg / ml graphene, after stirring for 1h, remove the sponge and transfer it to an oven for continuous rotation, so that the silver nanowires and graphene are evenly coated on the surface of the sponge; finally, The above-mentioned coated sponge is coated with a layer of MnO on its surface by conventional soaking and electrodeposition methods respectively. 2 and Zn, after the experiment is completed, the obtained coating is dried and then transferred to a vacuum oven for PDMS permeation encapsulation to obtain the final product. After performance testing, it was found that the battery capacity was stable at 94.1% of the initial capacity when the deformation amount reached 100% at a tensile rate of 0.1mm...

Embodiment 3

[0025] Take some commercial sponges, first clean them with deionized water, and then dry them in an oven to obtain sponges with a clean surface; then put them into the prepared PDDA solution with a concentration of 0.5% for stirring, and stir for 60 minutes Finally, take out the sponge and turn it over in the oven so that PDDA is evenly coated on the surface of the sponge. Put the coated sponge into silver nanowires with a concentration of 5 mg / ml and 0.5 mg / ml prepared at a volume ratio of 1:1. mg / ml of graphene mixed solution, after stirring for 4 hours, remove the sponge and transfer it to the oven for continuous rotation, so that the silver nanowires and graphene are uniformly coated on the surface of the sponge; finally, the coated The sponge was coated with a layer of MnO on its surface by conventional soaking and electrodeposition methods respectively. 2 and Zn, after the experiment is completed, the obtained coating is dried and then transferred to a vacuum oven for PD...

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Abstract

The invention relates to the field of energy storage, in particular to a stretchable high-performance Zn-MnO 2 The preparation method of the battery specifically includes the following steps. First, the commercial sponge is treated, and then the PDDA surface is coated and modified to change its surface electrical properties, and then the electrostatic force is used to make the sponge surface coated with a layer of conductive network, and then functionalize the sponge coated with a conductive network, use the method of soaking and electrodeposition to prepare the electrode of the battery, and finally perform a performance test after it is packaged. This method has the advantages of low cost, simple process and high product performance. The excellent characteristics make the battery have a wide range of application prospects in wearable devices, smart devices, energy storage and other fields.

Description

technical field [0001] The invention relates to the field of manufacturing energy storage equipment, in particular to a stretchable high-performance Zn-MnO 2 The technical field of battery preparation. Background technique [0002] At present, there is a serious contradiction between the increasing consumption and depletion of traditional fossil raw materials and the huge energy demand caused by the continuous development of society and the rapid growth of population. Great destruction, greenhouse effect, land desertification, glacier melting and other environmental disasters emerge one after another. Although all kinds of clean energy are being vigorously developed at present, there are still problems in various aspects of clean energy, such as the utilization of wind energy, and a large part of wind energy It cannot be directly connected to the grid for transmission and needs to be stored in a certain battery and then converted for use, which puts forward higher requireme...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/38H01M4/38H01M4/50
CPCH01M4/38H01M4/50H01M10/38Y02E60/10Y02P70/50
Inventor 韩金玲吕振瑞
Owner JIAXING HENGWEI BATTERY