A kind of outsole formula with high oil resistance, antistatic and high anti-slip function and preparation method thereof

An antistatic and antistatic agent technology, applied in the field of rubber sole production, can solve the problems of easy generation of static electricity, cause fire, high price, etc., and achieve the effect of good slip resistance and oil resistance

Active Publication Date: 2021-02-12
浙江中瑞橡胶高分子材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Now even if composite function outsole shoes can be bought on the market, its price is also very expensive
[0003] Moreover, ordinary polymer materials are insulating, and ordinary rubber soles are extremely prone to static electricity. When the charge on the soles accumulates to a certain amount, it is likely to cause a fire.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] An outsole formula with high oil resistance, antistatic and high anti-slip function, which is composed of the following materials in parts by weight: 70 parts of nitrile rubber; 15 parts of brominated butyl rubber; 15 parts of chlorinated polyethylene; 0.8 parts of stearic acid ; 5 parts of zinc oxide by indirect method; 1.5 parts of cross-linking agent; 0.5 parts of bridging agent; 40 parts of white carbon black; 4000 parts of polyethylene glycol; 4 parts of antistatic agent; 0.5 parts of accelerator TBBS; 2.2 parts of accelerator DM; 2 parts of dispersant; 2 parts of anti-aging agent.

[0046] The preparation method comprises the following steps:

[0047] (1) Put nitrile rubber, bromobutyl rubber, and chlorinated polyethylene into a 155L intermeshing internal mixer at 100°C for 60 seconds by weight;

[0048] (2) Mix stearic acid, indirect zinc oxide, polyethylene glycol, anti-slip agent, antistatic agent, anti-aging agent, antistatic agent, accelerator, accelerator D...

Embodiment 2

[0062] An outsole formula with high oil resistance, antistatic and high anti-slip function, which is composed of the following materials in parts by weight: 65 parts of nitrile rubber; 20 parts of brominated butyl rubber; 15 parts of chlorinated polyethylene; 1 part of stearic acid ; 5 parts of zinc oxide by indirect method; 1.2 parts of crosslinking agent; 0.8 parts of bridging agent; 35 parts of white carbon black; polyethylene glycol 4000: 3 parts; 6 parts of antistatic agent; 0.8 parts of accelerator TBBS; 1.5 parts of accelerator DM; 3 parts of dispersant; 2 parts of anti-aging agent.

[0063] The preparation method is the same as that of Example 1.

[0064] Test Data:

[0065] a. MARK II anti-slip coefficient: dry type 1.09; wet type 0.8; water: oil = 1:1 medium 0.58;

[0066] SRA: ceramic tile + sodium lauryl sulfate solution, EN20345-2011 anti-slip coefficient standard: heel 0.28, flat 0.32, the anti-slip coefficient of the outsole of the present invention: heel 0.35...

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Abstract

The invention discloses an outsole formula with high-oil-resistant, antistatic and high-antislip functions. The outsole is characterized by being composed of the following materials in parts by weight: 60-80 parts of nitrile butadiene rubber, 10-20 parts of brominated isobutylene-isoprene rubber, 10-20 parts of chlorinated polyethylene, 0.5-1 part of stearic acid, 4-5 parts of indirect method zincoxide, 1.5-2.0 parts of a cross-linking agent, 0.4-1.0 part of a bridging agent, 30-50 parts of white carbon black, 3-5 parts of polyethylene glycol 4000, 1-2 parts of an anti-wear agent Si-69, 3-6 parts of an antislip agent, 4-7 parts of an antistatic agent, 0.4-0.8 part of an accelerant TBBS, 1.0-2.2 parts of an accelerant DM, 2-3 parts of a dispersing agent, and 2-3 parts of an anti-aging agent. The method provided by the invention adopts the nitrile butadiene rubber as main rubber, and is combined with the brominated isobutylene-isoprene rubber and the chlorinated polyethylene to obtain the outsole with good oil resistance and antistatic high-antislip functions; and the outsole has optimally-balanced comprehensive performance.

Description

technical field [0001] The invention belongs to the field of making rubber soles, in particular to a formula for outsoles with high oil resistance, antistatic and anti-slip functions and a preparation method thereof. Background technique [0002] With the rapid development of society, the social division of labor is becoming more and more detailed, and the living and working environments are different, and social groups have higher and higher requirements for health and safety. As the daily necessities of shoes, in addition to the ordinary fashionable and beautiful wearing requirements, the functional requirements for adapting to the environment are becoming more and more intense. And now there are more and more varieties of shoes with a single function outsole, but shoes with a composite function outsole that can adapt to different environmental requirements have become a development trend. Even if composite function outsole shoes can be bought in the market now, its price...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L9/02C08L23/28C08K13/02C08K3/06C08K5/14
CPCC08K2201/017C08L9/02C08L2201/04C08L2205/03C08L2312/00C08L23/28C08L23/286C08K13/02C08K3/06C08K5/14
Inventor 刘锋马小平陈恺林浩然张颂扬王文强吴亨力李见刘锋平应祖列
Owner 浙江中瑞橡胶高分子材料股份有限公司
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