High-effect composite polyurethane phase change material and preparation method thereof
A technology of composite polyurethane and phase change materials, applied in the field of high-efficiency composite polyurethane phase change materials and its preparation, can solve the problems of low tensile strength, long time required, poor energy conduction effect, etc., and achieve wide application and good performance Effect
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[0017] The invention provides a kind of preparation method of high-efficiency composite polyurethane phase change material, it is characterized in that comprising the following steps:
[0018] Step (1): Take 99.99%-88% polyol, add 0.01-5% catalyst and 0-7% chain extender, stir and react at constant temperature to obtain prepolymer A;
[0019] Step (2): Adding 5%-25% of di(poly)isocyanate to the prepolymer A obtained in step (1), stirring and reacting at a constant temperature to obtain prepolymer B;
[0020] Step (3): adding 0.1-10% of high-efficiency energy-conducting filler additives to the prepolymer B obtained in step (2), stirring and reacting at a constant temperature to obtain prepolymer C;
[0021] Step (4): Add 0-30% adhesive to the prepolymer C obtained in step (3), and keep stirring at constant temperature until it is completely dissolved.
[0022] The stirring reaction time of the step (1), step (2) and step (3) is 3min-120min, 1.5min-120min and 2min-120min respec...
Embodiment 1
[0034] 77.98% of the polyhexamethylene adipate polyol with a molecular weight of 3000 was heated to 80° C. with a constant temperature heating and stirring reaction ax, and stirred at a stirring rate of 350 rpm, and 0.02% dibutyltin dilaurate was added dropwise while stirring, Add 1% 1,6-hexanediol dropwise, and continue stirring at a constant temperature for 3 minutes after the addition; add 15% MD1 dropwise while stirring, continue stirring at a constant temperature for 1.5 minutes after the addition is complete, and then add 1% graphene , After the dropwise addition is completed, continue to stir at a constant temperature for 2 minutes, then add 5% polyurethane adhesive, and continue to stir at a constant temperature of 80°C until it is completely dissolved, so as to prepare the corresponding polyurethane phase change material and then evenly pour it into the production equipment to obtain a white polyurethane phase change material.
[0035] The prepared material conducts e...
Embodiment 2
[0037] The other content of this embodiment is the same as that of Example 1, the difference being that the heating constant temperature stirring temperature is 75°C, the polyhexamethylene adipate with a molecular weight of 3000 is used in a multi-component amount of 87.88, and the addition amount of dibutyltin dilaurate is 0.02%. The addition of hexamethylene diisocyanate is 12%, the addition of graphite is 0.1%, and the addition of adhesive is 0%. The same: stirring rate and stirring time unchanged.
[0038] The prepared material conducts energy and heat quickly after sensing the temperature for 25s-35s.
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