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Fluorescent temperature probe material

A technology of fluorescence temperature and fluorescence intensity, applied in the field of fluorescent temperature probe materials, can solve the problem of low sensitivity

Inactive Publication Date: 2018-08-21
CHINA JILIANG UNIV
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Problems solved by technology

However, there are certain limitations in this method at present, that is, when a single rare earth ion is used to emit light (Er 3+ of 2 h 11 / 2 and 4 S 3 / 2 thermal coupling energy level), the resulting sensitivity is relatively low; and when two different rare earth ions are selected, the fluorescence intensity needs to change sufficiently, otherwise it is easy to produce a large relative error

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Embodiment 1

[0017] Fluorescent temperature probe material, including nanocrystalline shell layer, nanocrystalline intermediate layer and nanocrystalline core, the nanocrystalline core is doped with Tm whose fluorescence intensity decreases with the increase of temperature 3+ ions, Er doped in the nanocrystalline shell whose fluorescence intensity increases with temperature 3+ ions, interlayer nanocrystals for Tm reduction 3+ ions and Er3+ ions cross-relaxed inert layer. The nanocrystalline core is Na 3 Hf 7 :xYbyTm, the nanocrystalline interlayer is the nanocrystalline interlayer is Na 3 Hf 7 , the nanocrystalline shell is Na 3 ZrF 7 :mYbnEr; the ion doping concentration of x is 20-80%, the ion doping concentration of y is 0.5-2%, the ion doping concentration of m is 20-80%, and the ion doping concentration of n is 20-40% .

[0018] New Fluorescent Temperature Probe Material Na 3 Hf 7 :YbTm@Na 3 Hf 7 @Na 3 ZrF 7 : YbEr, preparation method, comprises the steps: (1) 0.795 mill...

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Abstract

The invention belongs to the field of inorganic luminescent materials and provides a fluorescent temperature probe material. The fluorescent temperature probe material comprises a nanocrystal shell layer, a nanocrystal middle layer and a nanocrystal nucleus, wherein the nanocrystal nucleus is doped with Tm<3+> ions with fluorescence intensity which is reduced with temperature increase, the nanocrystal shell layer is doped with Er<3+> ions with fluorescence intensity which is increased with temperature increase, and the nanocrystal middle layer is an inert layer for reducing cross relaxation ofthe Tm<3+> ions and the Er<3+> ions. The fluorescent temperature probe material is beneficial to promoting further development of a non-contact temperature sensing technology.

Description

technical field [0001] The invention belongs to the field of inorganic up-conversion luminescent materials, and relates to a fluorescent temperature probe material. Background technique [0002] The theory and method of temperature measurement research based on the luminescence characteristics of rare earth ions have become increasingly mature, and a large number of temperature measurement methods have emerged in recent years. The use of rare earth ions in temperature measurement research belongs to non-contact temperature detection, that is, to disperse substances that have an optical response to temperature in the measured object or smear it on the surface of the measured object, and measure the temperature by measuring its luminous properties Way. The current temperature measurement methods mainly include intensity ratio temperature measurement, fluorescence lifetime temperature measurement, rising edge temperature measurement and absolute intensity temperature measureme...

Claims

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Application Information

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IPC IPC(8): C09K11/02C09K11/67B82Y40/00G01K11/20
CPCB82Y40/00C09K11/025C09K11/7773G01K11/20
Inventor 夏洁楠雷磊徐时清
Owner CHINA JILIANG UNIV
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