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Physical activation method for preparing platinum-modified porous carbon-based titanium dioxide photocatalyst for eliminating formaldehyde at room temperature

A formaldehyde elimination and physical activation technology, applied in the field of environmental protection, can solve the problems of lack of research reports, etc., and achieve the effect of simple preparation method, good performance and good porosity

Inactive Publication Date: 2018-10-16
NINGBO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still very few research reports on the preparation of platinum-modified porous carbon-based titania catalysts by physical activation.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] Weigh 0.4g of ZTOF-1 into a tube furnace, raise the temperature to 400°C at a rate of 10°C / min under argon flow, and keep it for 5h to prepare 0.19g of titanium-containing carbon-based composite material. According to the mass ratio of platinum and titanium-containing carbon-based composite material, the obtained titanium-containing carbon-based composite material was added to a chloroplatinic acid solution with a concentration of 4 g / L, and after immersion at 20 ° C for 24 hours, the precipitate was taken out. Vacuum bake at 80°C for 24 hours, put it into a tube furnace, raise the temperature to 600°C at a rate of 10°C / min under argon flow, and keep it warm for 3 hours, then raise the temperature to 950°C, pass in water vapor for activation for 2 hours, and obtain 0.17g Platinum-modified porous carbon-based titania catalyst with a specific surface area of ​​2886 m 2 / g, recorded as 1# catalyst.

[0013] The test process of the room temperature degradation formaldehyde...

Embodiment 2

[0015] Others are the same as catalyst 1#, the platinum-modified porous carbon-based titania catalyst is prepared at an activation temperature of 850°C, and 0.18g of a platinum-modified porous carbon-based titania catalyst is obtained with a specific surface area of ​​2950m 2 / g is recorded as 2# catalyst, and others are similar to Example 1. The room temperature degradation formaldehyde performance test process of 1# catalyst is also similar to Example 1. After 1 hour of catalytic degradation, the degradation rate of formaldehyde reached 93.7%.

Embodiment 3

[0017] Others are the same as catalyst 1#, the platinum-modified porous carbon-based titanium dioxide catalyst is prepared at an activation temperature of 750°C, and 0.19g of platinum-modified porous carbon-based titanium dioxide catalyst is obtained, and its specific surface area is 2593m 2 / g is recorded as 3# catalyst, and others are similar to Example 1. The room temperature degradation formaldehyde performance test process of 1# catalyst is also similar to Example 1. After 1 hour of catalytic degradation, the degradation rate of formaldehyde reached 88.4%.

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Abstract

The invention relates to the technical field of environmental protection, in particular to a physical activation method for preparing a platinum-modified porous carbon-based titanium dioxide photocatalyst for eliminating formaldehyde at room temperature. The method comprises the steps of: using a titanium-based metal organic framework compound as a precursor, preparing a titanium-containing carbon-based composite material through high-temperature carbonization firstly, performing soaking in a chloroplatinic acid solution, and then performing high-temperature calcination and activation so as toobtain the platinum-modified porous carbon-based titanium dioxide photocatalyst. The preparation method is simple and practical, regulation of the performance of the photocatalyst can be achieved bychanging the variety and activation temperature of the titanium-based metal organic framework compound, and the obtained platinum-modified porous carbon-based titanium dioxide photocatalyst has the advantages of good porosity, a controllable pore shape, good performance of oxidative decomposition of formaldehyde at room temperature, small pollution in the preparation process and the like, and canbe widely applied to air conditioning equipment, ventilation ducts, air purifiers and other devices.

Description

technical field [0001] The invention relates to the technical field of environmental protection, in particular to a method for physically activating a platinum-modified porous carbon-based titanium dioxide catalyst for eliminating formaldehyde at room temperature. Background technique [0002] Formaldehyde is a common indoor air pollutant, which is very harmful to people's health. According to the national standard of the People's Republic of China "Hygienic Standards for Formaldehyde in Indoor Air", the maximum allowable concentration of formaldehyde in indoor air is 0.08mg / m 3 , but the average concentration of newly installed houses in daily life is greater than 0.2mg / m 3 . In recent years, the use of air purifiers to deal with indoor formaldehyde pollution has become a relatively common means of household air purification. In the process of purifying the air, methods such as physical adsorption, chemical adsorption and photocatalysis are mainly used. Physical adsorpti...

Claims

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Application Information

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IPC IPC(8): B01J31/38B01J35/04B01J35/10B01J37/02B01J37/08B01J37/10B01D53/86B01D53/72
CPCB01D53/8668B01J31/38B01J37/0207B01J37/082B01J37/086B01J37/10B01D2259/4508B01J35/39B01J35/618B01J35/56
Inventor 陈高健徐清范冬梅张靖桢
Owner NINGBO UNIV