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A method for hydrotreating diesel oil

A technology for hydrotreating and diesel oil, applied in hydrotreating process, treating hydrocarbon oil, chemical instruments and methods, etc., can solve the problem of poor selectivity of monocyclic aromatic hydrocarbons, and achieve the improvement of activity and stability, high activity, prevention of Aggregate effect

Active Publication Date: 2020-09-22
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is the poor selectivity of single-ring aromatics in the conventional hydrorefining process of high-aromatic diesel feedstock

Method used

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  • A method for hydrotreating diesel oil
  • A method for hydrotreating diesel oil
  • A method for hydrotreating diesel oil

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Experimental program
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Effect test

Embodiment 1

[0080] use figure 1 The process shown is for diesel feedstock D. Diesel feedstock oil D enters the hydrogenation reactor from the feedstock oil inlet, and hydrogen enters the hydrogenation reactor from the hydrogen inlet. The first reaction zone and the second reaction zone are arranged in the hydrogenation reactor from top to bottom. In the first reaction zone Fill the hydrofinishing catalyst A, fill the hydrofinishing catalyst B in the second reaction zone, the reaction effluent I is discharged from the top of the hydrogenation reactor, the reaction effluent II is discharged from the bottom of the hydrogenation reactor, the reaction effluent I and the reaction After the effluent II is combined, it is separated to obtain the hydrogenated oil. The hydrogenation reaction conditions and product properties are shown in Table 2. It can be seen from Table 2 that the saturation rate of polycyclic aromatic hydrocarbons in the hydrogenated oil is 85.1%, and the selectivity of single-...

Embodiment 2

[0082] use figure 1 The process shown is for the treatment of diesel feed oil E. Diesel feedstock oil E enters the hydrogenation reactor from the feedstock oil inlet, and hydrogen enters the hydrogenation reactor from the hydrogen inlet. The first reaction zone and the second reaction zone are arranged in the hydrogenation reactor from top to bottom. In the first reaction zone Fill the hydrofinishing catalyst A, fill the hydrofinishing catalyst C in the second reaction zone, the reaction effluent I is discharged from the top of the hydrogenation reactor, the reaction effluent II is discharged from the bottom of the hydrogenation reactor, the reaction effluent I and the reaction After the effluent II is combined, it is separated to obtain the hydrogenated oil. The hydrogenation reaction conditions and product properties are shown in Table 2. It can be seen from Table 2 that the saturation rate of polycyclic aromatic hydrocarbons in the hydrogenated oil is 85.4%, and the select...

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Abstract

The invention provides a method for treating diesel through hydrogenation. The method comprises the following steps: diesel raw oil enters a hydrogenation reactor from a raw oil inlet, a first reaction area and a second reaction area are arranged in the hydrogenation reactor from top to bottom, the raw oil inlet is formed between the first reaction area and the second reaction area, a hydrogen inlet is formed in the bottom of the hydrogenation reactor, a reaction effluent I is discharged from the top of the hydrogenation reactor, a reaction effluent II is discharged from the bottom of the hydrogenation reactor, after the reaction effluent I is mixed with the reaction effluent II, the mixture is separated to obtain hydrogenation generation oil, and based on the diesel raw oil, the saturation factor of polycyclic aromatic hydrocarbons in the hydrogenation generation oil is 85%-90%, and the selectivity of monocyclic aromatic hydrocarbons is 80%-85%. In the method provided by the invention, the high-quality raw materials are provided for preparing a high-octane gasoline or BTX component through catalytic cracking or hydrogen cracking, and moreover, the hydrogen consumption in the hydrogenation process is reduced, and the process economy is beneficially improved.

Description

technical field [0001] The invention relates to a method for refining hydrocarbon oil in the presence of hydrogen, more specifically, a method for hydrotreating diesel oil. Background technique [0002] Catalytic cracking diesel has a relatively high proportion in my country's diesel products, accounting for about 1 / 3 of commercial diesel. As crude oil becomes worse and heavier, the quality of FCC diesel fractions is deteriorating day by day, mainly manifested by high content of sulfur, nitrogen and aromatics, low cetane number and poor stability. In recent years, with the wide application of high-severity catalytic cracking technology such as catalytic cracking technology (MIP) that produces more isoparaffins, the content of aromatics, especially polycyclic aromatics, in MIP catalytic diesel has further increased, and the cetane number has further decreased . With the continuous enhancement of environmental protection awareness, the country's clean quality requirements fo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G65/04B01J23/882B01J23/888
CPCB01J23/882B01J23/888C10G65/04C10G2300/70
Inventor 王哲习远兵鞠雪艳
Owner CHINA PETROLEUM & CHEM CORP