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The environmental protection technology and equipment of the sour mist pollution during the rust removal of steel

A pickling and steel technology, applied in the field of steel rust removal and pickling process, can solve problems such as adverse effects on the survival of animals and plants, affecting the health of workers, and reducing the mechanical properties of steel, so as to improve the quality of pickling products, reduce potential safety hazards, The effect of saving hydrochloric acid

Active Publication Date: 2022-08-05
叶涛
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] However, due to the high concentration of hydrochloric acid in the prepared pickling solution in the current steel rust removal and pickling production process, and based on the consideration of the convenience of soaking the workpiece, the opening size of the designed pickling soaking tank must be large enough, so it is unavoidable in the production process. The emergence of a large amount of volatile acid mist
In addition to directly affecting the health of the staff and causing equipment loss, the acid fog will also cause acid deposition if it is discharged into the atmosphere, which will have a negative impact on the survival of crops and other animals and plants.
In addition, the reaction of hydrochloric acid and iron in the pickling solution will produce hydrogen, and a part of the hydrogen escapes. Since the hydrogen is a combustible gas, the escape will bring hidden dangers to production safety; the other part of the hydrogen diffuses into the steel matrix, resulting in a decrease in the mechanical properties of the steel. , and may cause defects such as pickling bubbles. For the volatile acid mist generated during the production process, acid mist absorption and treatment devices can be installed around the pickling soaking tank to reduce the acid mist. However, due to the large opening of the pickling soaking tank, it is difficult to Little effect, still can not avoid the escape of acid mist

Method used

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  • The environmental protection technology and equipment of the sour mist pollution during the rust removal of steel
  • The environmental protection technology and equipment of the sour mist pollution during the rust removal of steel
  • The environmental protection technology and equipment of the sour mist pollution during the rust removal of steel

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0111] 1) According to the ingredients and proportions listed in Table 1 and Table 2, mix the raw materials to obtain the acid wash and extender used.

[0112] 2) Pour 2L of pickling solution into the pickling soaking tank, and adjust the temperature of the pickling solution to the working temperature shown in Table 1 and Table 2.

[0113] 3) 5 pieces of 124X78mm stainless steel plates whose front and back surfaces were burned to black with a flame were weighed and then immersed in a pickling soaking tank for pickling. The pickling time for each stainless steel plate was 5 minutes. Take it out from the pickling solution, and manually add 200ml of supplement 1 to the pickling solution every 10 minutes during the pickling process;

[0114] 4) Use clean water to rinse the residual pickling solution attached to the surface of the stainless steel plate, then dry it with hot air to a constant weight and weigh it; observe the metal surface after pickling and calculate the pickling sp...

Embodiment 2

[0116] 1) According to the ingredients and proportions listed in Table 1 and Table 2, mix the raw materials to obtain the acid wash and extender used.

[0117] 2) Pour 2L of pickling solution into the pickling soaking tank 2, and adjust the temperature of the pickling solution to the working temperature shown in Table 1 and Table 2.

[0118] 3) Weigh 5 stainless steel plates with a size of 124 × 78 mm and burn them to black on both sides, and then immerse them in pickling solution in turn for pickling. The pickling time for each stainless steel plate is 5 minutes. Take it out from the pickling solution;

[0119] Use the automatic detection and control machine 1 to control the addition of the supplementary liquid through the time program. When the interval time set value specified in Table 1 and Table 2 is reached, the acid-resistant pump 4 is automatically turned on to control the extraction of supplementary liquid from the supplementary liquid tank 3. Throw in 200ml of suppl...

Embodiment 3-5

[0122] The test method is the same as Example 2, and its difference is that the composition of the pickling solution and / or the supplementary solution and the working temperature during the coordination and pickling are different, see Table 1 and Table 2 for details.

[0123] The observed results of the metal surface after pickling and the average pickling speed are recorded in Table 3.

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Abstract

The invention provides an environmental protection process and equipment for reducing acid mist pollution in the process of rust removal and pickling of steel, and the steps include preparing a mixed solution of hydrochloric acid and ferric chloride as pickling solution; Pickling; adding supplements to the pickling solution during the pickling process; taking out the steel parts after the pickling is completed. The equipment includes the following components: a pickling soaking tank for pickling steel; a replenisher tank for storing the supplement; a pump, the inlet of the pump is connected to the replenisher tank, and the outlet is connected to the acid The washing and soaking tank is connected, and the switch of the pump is controlled by an automatic detection and control machine; the automatic detection and control machine includes at least one controller, which is connected with the pump to control the switch of the pump through an electrical signal. This process effectively reduces acid mist pollution by using ferric chloride solution instead of part of hydrochloric acid for surface corrosion of steel.

Description

technical field [0001] The invention relates to a steel rust-removing and pickling process, in particular to an environmental protection process for reducing acid mist pollution during the steel rust-removing and pickling process. Background technique [0002] Pickling refers to a cleaning method that uses pickling solution to remove impurities such as oxide layer (main components are ferrous oxide, ferric oxide and ferric oxide) and rust on the surface of steel. Pickling is often required for surface impurity pretreatment before surface processing of steel. The pickling solution commonly used in the existing pickling process is concentrated hydrochloric acid. The pickling solution for steel has two functions, one of which is to remove the oxide layer (that is, rust) on the surface of the steel, and the other is to refresh the surface of the steel with a micro-corrosion reaction. [0003] When the pickling solution removes the oxide layer, the following reactions occur: ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23G1/08C23G3/00
CPCC23G1/08C23G3/00
Inventor 叶涛
Owner 叶涛