Polyphenylene ether resin composite material and its preparation method and application

A technology of polyphenylene ether resin and composite material, which is applied in the field of polyphenylene ether resin composite material and its preparation, can solve the problems of stress cracking and poor toughness of polyphenylene ether resin, and achieves stable performance, low cost and easily controllable conditions. Effect

Active Publication Date: 2021-02-12
SHENZHEN WOTE ADVANCED MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The purpose of the present invention is to provide a polyphenylene ether resin composite material and its preparation method and application, aiming to solve the problems of poor toughness and easy stress cracking of the existing polyphenylene ether resin in the application of preparing cold and hot water supply pipe valves

Method used

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  • Polyphenylene ether resin composite material and its preparation method and application
  • Polyphenylene ether resin composite material and its preparation method and application
  • Polyphenylene ether resin composite material and its preparation method and application

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preparation example Construction

[0054]Correspondingly, an embodiment of the present invention provides a method for preparing a polyphenylene ether resin composite material, the polyphenylene ether resin composite material includes the following components by weight:

[0055]

[0056]Wherein, based on the total weight of the functional masterbatch as 100%, the functional masterbatch includes the following components in the following weight percentages:

[0057]Resin base material 60-79%;

[0058]20-39% of fumed nano-silica with branched structure;

[0059]Coupling agent 1-3%;

[0060]And the coupling agent is coated on the surface of the fumed nano silica having a branched structure;

[0061]The preparation method of the polyphenylene ether resin composite material includes the following steps:

[0062]S01. Weigh the components according to the formula of the polyphenylene ether resin composite;

[0063]S02. Mixing the polyphenylene ether resin and the elastomer to obtain a first mixture;

[0064]S03. Mixing the polyolefin, flame retardant, fu...

Embodiment 1

[0088]A polyphenylene ether resin composite material whose formula composition is shown in Table 1, specifically: 70 parts polyphenylene ether resin (PPO), 5 parts elastomer, 8 parts flame retardant, 1 part polyolefin, 15.7 parts functional masterbatch , 0.2 part of primary antioxidant and 0.1 part of auxiliary antioxidant; wherein, based on the total weight of the functional masterbatch as 100%, the functional masterbatch includes the following components in the following weight percentages: polyphenylene 70% ether resin resin base, 28% fumed silica with branched structure, 2% coupling agent.

[0089]The preparation method of the polyphenylene ether resin composite material includes: 70 parts of polyphenylene ether resin (PPO) and 5 parts of elastomer are added from the mouth of the first loss-in-weight feeder, 8 parts of flame retardant, 1 part of polyolefin, and 15.7 parts Functional masterbatch, 0.2 part of main antioxidant and 0.1 part of auxiliary antioxidant are added from the m...

Embodiment 2

[0091]A polyphenylene ether resin composite material whose formula composition is shown in Table 1, specifically: 70 parts polyphenylene ether resin (PPO), 10 parts elastomer, 8 parts flame retardant, 1 part polyolefin, 10.7 parts functional masterbatch , 0.2 part of primary antioxidant and 0.1 part of auxiliary antioxidant; wherein, based on the total weight of the functional masterbatch as 100%, the functional masterbatch includes the following components in the following weight percentages: polyphenylene 68% ether resin resin base, 30% fumed silica with branched structure, 2% coupling agent.

[0092]The preparation method of the polyphenylene ether resin composite material includes: 70 parts of polyphenylene ether resin (PPO) and 10 parts of elastomer are added from the mouth of the first loss-in-weight feeder, 8 parts of flame retardant, 1 part of polyolefin, and 10.7 parts Functional masterbatch, 0.2 part of main antioxidant and 0.1 part of auxiliary antioxidant are added from the...

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Abstract

The invention provides a polyphenylene oxide resin composite material which comprises the following ingredients in parts by weight: polyphenylene oxide resin, an elastomer, a fire retardant, polyolefin, functional master batches, a primary antioxidant and an auxiliary antioxidant, wherein the 10% total weight of the functional master batches comprise the following ingredients by weight percentage:60-79% of resin binders, 20-39% of gas phase nano-silica with a branch structure and 1-3% of a coupling agent; the coupling agent is coated on the surface of the gas phase nano-silica with the branchstructure. On the basis that the excellent property of the polyphenylene oxide resin can be effectively maintained, the polyphenylene oxide resin composite material provided by the invention also hasexcellent high temperature and high pressure resistance and has obviously improved toughness and stress cracking resistance.

Description

Technical field[0001]The invention belongs to the technical field of polymer materials, and particularly relates to a polyphenylene ether resin composite material and a preparation method thereof.Background technique[0002]Polyphenylene ether resin alloy has many excellent properties, such as high modulus, high temperature resistance, creep resistance, self-flame retardant, etc., and is widely used in electronic appliances, auto parts, communication photovoltaics and other fields. The polyphenylene ether resin with the above-mentioned properties is also suitable for making valves for cold and hot water supply pipes. However, because polyphenylene ether materials have low impact strength, poor toughness, and poor resistance to stress cracking, they are prone to stress cracking when used in water pipe valves, which limits the application of polyphenylene ether materials in the field of water pipe valves.Summary of the invention[0003]The purpose of the present invention is to provide a ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L71/12C08L9/06C08L15/00C08L53/02C08L23/02C08K9/10C08K3/36C08J3/22
CPCC08J3/226C08J2371/12C08J2409/06C08J2415/00C08J2423/02C08J2453/02C08K3/36C08K9/10C08K2201/011
Inventor 杨瑞权吴宪何征徐春生谭目志
Owner SHENZHEN WOTE ADVANCED MATERIALS
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