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Battery

A battery and electrolyte technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of not meeting the requirements of long-life batteries, poor battery cycle performance, serious battery flatulence, etc., to improve high-voltage cycle performance and high temperature. Storage performance, suppression of increase in impedance, effect of reducing erosion

Active Publication Date: 2019-03-05
CONTEMPORARY AMPEREX TECH CO
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Problems solved by technology

[0003] Ternary cathode materials have the advantages of high energy density, high discharge voltage, and good low-temperature performance, but there are generally two problems: one is that the cycle performance of the battery is poor, which cannot meet people's requirements for long-life batteries; During the high-temperature storage process, the flatulence is serious, which poses a safety risk. In addition, the capacity declines rapidly during the high-temperature storage process.

Method used

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preparation example Construction

[0100] (1) Preparation of electrolyte

[0101] In a glove box filled with argon (water content 6 ), after the lithium salt is completely dissolved, an electrolyte with a lithium salt concentration of 1 mol / L is obtained, which is the electrolyte.

[0102] (2) Preparation of positive electrode sheet:

[0103] The positive electrode active material, the conductive agent Super P, and the binder polyvinylidene fluoride (PVDF) are made into positive electrode slurry in N-methylpyrrolidone (NMP). The solid content in the positive electrode slurry is 50 wt%, and the mass ratio of the positive electrode active material, SuperP, and PVDF in the solid content is 6:2:2:2. The positive electrode slurry was coated on the current collector aluminum foil and dried at 85℃, then cold pressed, and then trimmed, sliced, and slit, then dried under vacuum at 85℃ for 4h to make a positive electrode sheet .

[0104] (3) Preparation of negative electrode sheet:

[0105] The graphite as the negative electrod...

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Abstract

The application relates to the field of the energy storage material, and specifically relates to a battery. The battery disclosed by the invention comprises a positive pole plate, a negative pole plate, an isolating membrane and electrolyte arranged between the positive pole plate and the negative pole plate; the positive pole plate contains the positive active material, the electrolyte comprisesorganic solvent, electrolyte and additives; the positive active material is the ternary positive material, and the additives comprise polyphosphazenes compound and fluorinated bis-oxalate phosphate. The electrolyte in the battery disclosed by the application can reduce the erosion on a positive interface by the HF and protect the positive interface, inhibit the impedance increasing of the positiveand negative interfaces, and improve the cyclic storage life, thereby improving the high-voltage circulating performance and high-temperature storage performance of the battery.

Description

Technical field [0001] This application relates to the field of energy storage materials, and specifically to a battery. Background technique [0002] In the rapidly developing information age, the demand for mobile phones, notebooks, cameras and other electronic products has increased year by year. As the working power source of electronic products, batteries, especially lithium ion secondary batteries, have the characteristics of high energy density, no memory effect, and high working voltage, and are gradually replacing traditional Ni-Cd and MH-Ni batteries. [0003] Ternary cathode materials have the advantages of high energy density, high discharge voltage, and good low-temperature performance, but there are two common problems: one is the poor cycle performance of the battery, which cannot meet people's requirements for long-life batteries, and the other is the battery The flatulence is more serious during high-temperature storage, and there is a safety risk. In addition, th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/525H01M4/505H01M10/0567H01M10/42
CPCH01M4/505H01M4/525H01M10/0567H01M10/4235Y02E60/10
Inventor 张翠平韩昌隆张明张浩
Owner CONTEMPORARY AMPEREX TECH CO
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