Polypropylene composition for improving surface flame treatment effect and preparation method of polypropylene composition

A polypropylene composition and a flame treatment technology are applied in the polypropylene composition and its preparation, the polypropylene composition for improving the surface flame treatment effect and the preparation field thereof, and can solve the problem that the improvement of the surface energy is not very obvious and the surface energy is not very obvious. It can improve the problems of limited improvement and poor surface flame treatment effect, so as to achieve the effect of good flame treatment surface and adhesive performance, and improve surface tension and wettability.

Inactive Publication Date: 2019-03-19
JIANGSU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the large variety of PP, which has a relatively broad molecular weight distribution and crystallinity, the surface flame treatment effect is often poor, resulting in adhesive failure.
At present, in the existing technology, the surface energy of the material system is enhanced by adding an elastomer with a certain polarity to the PP+Talc material system for compounding, thereby enhancing its surface polarity, although this method can increase to a certain extent Adhesion

Method used

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  • Polypropylene composition for improving surface flame treatment effect and preparation method of polypropylene composition
  • Polypropylene composition for improving surface flame treatment effect and preparation method of polypropylene composition
  • Polypropylene composition for improving surface flame treatment effect and preparation method of polypropylene composition

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Example Embodiment

[0045] Compared with Example 1 and Example 4, Example 2 with Example 5, and Example 3 with Example 6, at the same addition amount, the surface contact angle of SBS after flame treatment was smaller , The surface tension is greater and the surface oxygen content is higher.

[0046] Compared with Example 1, in Comparative Example 5, the content of POE is reduced. In the case of the same SBS content, Comparative Example 5 has a better surface treatment effect.

[0047] Compared with Example 4, in Comparative Example 4, the content of POE is reduced. When the SIS content is the same, Comparative Example 4 has a better surface treatment effect.

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Abstract

The invention discloses a polypropylene composition for improving a surface flame treatment effect and a preparation method of the polypropylene composition. The composition is prepared from, by weight, 40-70 parts of polypropylene resin, 10-20 parts of POE, 5-15 parts of a styrenic block copolymer, 10-30 parts of filler, 3-5 parts of maleic anhydride grafted polypropylene, 0.5-2.0 parts of pigments and 0.2-2.0 parts of auxiliary agents. By introduction of the styrenic block copolymer with a main chain containing unsaturated double bonds into a conventional polypropylene and filler system, thesurface double bond content is increased, and polymer surface polarity is improved; since the double bonds can be easily oxidized by high-temperature flame, more oxygen-containing functional groups can be introduced, surface tension and wettability are improved, the surface flame treatment effect can be evidently improved by the prepared polypropylene composition, and the polypropylene composition can be used for preparation of automobile full-plastic tail door outer plates and spoilers and has great surface flame treatment and adhesion performances.

Description

technical field [0001] The invention relates to a polypropylene composition and a preparation method thereof, in particular to a polypropylene composition for improving the surface flame treatment effect and a preparation method thereof, and belongs to the technical field of modified polymer materials. Background technique [0002] Polypropylene PP is a semi-crystalline plastic with the characteristics of low density and easy processing, and has become the most widely used variety of automotive plastics. The all-plastic tailgate is one of the current trends in the development of lightweight vehicles. The all-plastic tailgate mainly includes an inner panel, an outer panel and a spoiler, among which the outer panel and the spoiler are made of PP+Talc material, and different parts are connected by adhesive. However, polypropylene is a non-polar resin with low surface energy, poor adhesive performance, low adhesive strength and prone to interfacial degumming. [0003] In order...

Claims

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Application Information

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IPC IPC(8): C08L23/14C08L23/08C08L53/02C08L51/06C08K13/02C08K3/34C08K3/04C08K5/134C08K5/526
CPCC08L23/14C08L2205/025C08L2205/035C08L23/0815C08L53/02C08L51/06C08K13/02C08K3/34C08K3/04C08K5/1345C08K5/526
Inventor 付大炯麻卫军孙晓莲安朋谢正瑞孙刚杨波陈桂吉陈延安张超罗忠富
Owner JIANGSU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD
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