Disperse dye composition and preparation and application methods thereof

A technology for disperse dyes and compositions, applied in dyeing methods, organic dyes, textiles and papermaking, etc., can solve the problems of poor washing fastness and sublimation fastness of dyes, complicated production process, high production cost and market price, and achieve High washing fastness and sublimation fastness, simple synthesis steps, excellent performance improvement effect

Active Publication Date: 2019-03-19
SHAOXING UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the dye also has certain defects, which affect the actual use of the dye in production, as shown in:
[0005] (1) Poor fastness
Due to the small molecular weight (365.18) and molecular volume of the dye, it is easier for the dye to enter the "instant hole" produced by the fiber. Therefore, the softening degree of the polyester fiber molecular chain is low during dyeing. Although it is beneficial to low temperature dyeing (at the dyeing temperature It can be dyed slowly after exceeding 50°C), but in turn, it will also cause poor washing fastness and sublimation fastness of the dye, because the dye belongs to the "easy in and easy out" type on polyester fibers;
[0006] (2) Low lifting force
[0007] (3) There are environmental problems in raw materials and production process
Although it has not affected its production and application in the short term, there is always a certain risk of whether it will restrict the use of anthraquinone in the long run, so there is uncertainty about whether it will indirectly affect the products and output of C.I. Disperse Blue 56
[0008] (4) High cost and serious price rise
Due to the complex production process of dyes and the high pressure of environmental protection in production, the production cost and market price of dyes are much higher than that of azo dyes of the same color system, which also limits the large-scale application in production.

Method used

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  • Disperse dye composition and preparation and application methods thereof
  • Disperse dye composition and preparation and application methods thereof
  • Disperse dye composition and preparation and application methods thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Add 38.58g of component A, 10.80g of component B, 0.33g of component C, 0.62g of component D, 40g of diffusing agent NNO and 60g of dispersing agent MF, add 100g of water, stir and mix well, grind and disperse with a sand mill, Then spray-dry to obtain the blue disperse dye composition that the strength part is 295%.

[0051] Shade detection:

[0052] Use the blue disperse dye composition that above-mentioned method obtains, when its consumption is 0.32% o.w.f, can be dyed with the C.I. disperse blue 56 that consumption is 1.00% o.w.f on the polyester fabric consistent shade and color depth, as shown in table 1 below Show.

[0053] Table 1, Example 1 and C.I. Color contrast of disperse blue 56

[0054]

[0055] Note: the color data is a standard sample with C.I. disperse blue 56 (100%) dyed polyester fabric, and the blue dye composition of the present invention is a batch sample, which is obtained by testing on a Datacolor color measuring and matching instrument in...

Embodiment 2~8

[0058] According to the preparation method of the dye composition described in Example 1, adjust the amount of each component and additive, mix component A, component B, component C and component D with the additive evenly, add water to stir and grind to disperse, spray After drying, various blue disperse dye composition finished products (Table 1) were obtained. When they are dyed with C.I. Disperse Blue 56 (100%) adjusted to the same strength, the color difference with the latter is also shown in Table 2.

[0059] Table 2. Shade comparison under different components and additives

[0060]

[0061]

[0062] As can be further seen from Table 2, when the four components of the blue disperse dye of the present invention are blended with additives in different amounts in selected proportions, the finished dye compositions with different strengths are obtained, and these dye compositions are all It can dye the same shade as C.I. Disperse Blue 56, and the color difference va...

Embodiment 9

[0064] The polyester fabrics were dyed with the dye compositions described in Examples 1-8 respectively.

[0065] The dyeing method is as follows: put 500 kilograms of pure polyester knitted fabrics (pretreated) into a dyeing bath prepared at a liquor ratio of 1:10 at room temperature, run for 3-5 minutes, and add the blue disperse dye composition 5 of the present invention. kg, run for 5-10 minutes, adjust the pH value of the dyeing bath to 4.5-5.5 with glacial acetic acid, then raise the temperature to 80°C at a heating rate of 2°C / min, and then raise the temperature to 130°C at a heating rate of 1.0°C / min and run for 50 minutes. After the dyeing is completed, cool down to 80°C to drain the liquid, perform reduction cleaning, water washing, dehydration and drying.

[0066] According to the national standard GB / T3921.C3-2013, GB / T3920-2013, GB / T5718-2008 and GB / T8427-2008 respectively test the washing fastness, rubbing fastness and sublimation fastness of the polyester fabric...

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Abstract

The invention discloses a disperse dye composition and preparation and application methods thereof. The disperse dye composition is composed of a component A, a component B, a component C and a component D at a certain ratio, which are added with a certain quantity of additives. The prepared disperse dye composition has the same shade with C. I. disperse blue 56, and when applied to dyeing polyester and polyester blended fabric, has the advantages of being higher in washing fastness and sublimation fastness, better in built-up property, lower in price, safer and more environmentally friendly and accordingly can replace the C. I. disperse blue 56 for dyeing production of hydrophobic fabric, especially polyester.

Description

Technical field: [0001] The invention relates to a blue disperse dye composition and its preparation method and application, which is used to replace C.I. disperse blue 56, and is suitable for dyeing polyester fibers and blended fabrics thereof. Background technique: [0002] C.I. Disperse Blue 56, trade name Disperse Blue 2BLN, chemical name 1,5-diamino-2-chloro-4,8-dihydroxy-9,10-anthraquinone (see formula 1). This dye is an important part of the three primary colors of disperse dyes at low temperature. It has the advantages of bright shade, good level dyeing, low dyeing temperature, and good light fastness. It is one of the most widely used varieties of "blue anthraquinone" disperse dyes. The chemical structure of C.I. Disperse Blue 56 is shown in the following formula: [0003] [0004] However, the dye also has certain defects, which affect the actual use of the dye in production, as shown in: [0005] (1) Poor fastness. Due to the small molecular weight (365.18) ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09B67/38D06P1/16D06P3/36
CPCC09B67/008D06P1/16D06P3/36
Inventor 胡玲玲
Owner SHAOXING UNIVERSITY
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