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Positive electrode lead plaster of lead acid storage battery and preparation method

A lead-acid battery, positive lead paste technology, applied in battery electrodes, circuits, electrical components and other directions, can solve the problems of decreased bonding force between active materials and grids, poor low temperature resistance of batteries, shortened battery life, etc. The effect of curing and forming time, low temperature starting ability, and prolonging service life

Inactive Publication Date: 2019-03-22
山东久力新能源集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the deep cold environment in the north, due to the increase of the viscosity of the vehicle lubricating oil, the lower the temperature, the higher the proportion of the electrolyte in the battery, the higher the internal resistance of the battery, the lower the starting output current of the battery, it is difficult to start the vehicle, and the low temperature resistance of the battery is poor. Difference
[0004] In order to improve the low-temperature starting performance of the battery, the concentration of dilute sulfuric acid is often increased during the manufacturing process of the positive plate, thereby increasing the porosity of the lead paste. As the number of times increases, the plate continues to expand and contract, and the binding force between the active material and the grid continues to decrease, thereby shortening the service life of the battery

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A positive lead paste for a lead-acid storage battery, comprising the following components in parts by weight: 1000 parts of lead powder, 110 parts of dilute sulfuric acid, 2.2 parts of graphite, 1.2 parts of tetrabasic lead sulfate, 0.6 part of short fiber, and 135 parts of water . Wherein, the graphite is heterosexual graphite, the fixed carbon content of the graphite is greater than 99.9%, the short fiber is polyester short fiber, the water is ionized water, and the particle diameter of the tetrabasic lead sulfate is 2.5 μm-4.5μm, the lead content of the tetrabasic lead sulfate is greater than 98%, and the concentration of the dilute sulfuric acid is 1.398-1.402g / cm 3 .

[0022] Concrete preparation method is:

[0023] (1) Weigh each component according to the above-mentioned composition of the positive electrode paste of the lead-acid battery, and set aside;

[0024] (2) Add graphite, short fiber, lead powder, and tetrabasic lead sulfate into the paste machine fo...

Embodiment 2

[0026] A positive lead paste for lead-acid battery, comprising the following components in parts by weight: 1000 parts of lead powder, 120 parts of dilute sulfuric acid, 3.2 parts of graphite, 2.2 parts of tetrabasic lead sulfate, 1.2 parts of short fiber, and 155 parts of water. Wherein, the graphite is heterosexual graphite, the fixed carbon content of the graphite is greater than 99.9%, the short fiber is polyester short fiber, the water is ionized water, and the particle diameter of the tetrabasic lead sulfate is 2.5 μm-4.5μm, the lead content of the tetrabasic lead sulfate is greater than 98%, and the concentration of the dilute sulfuric acid is 1.398-1.402g / cm 3 .

[0027] Concrete preparation method is:

[0028] (1) Weigh each component according to the above-mentioned composition of the positive electrode paste of the lead-acid battery, and set aside;

[0029] (2) Add graphite, short fiber, lead powder, and tetrabasic lead sulfate into the paste machine for dry mixin...

Embodiment 3

[0031] A positive electrode lead paste for a lead-acid storage battery, comprising the following components in parts by weight: 1000 parts of lead powder, 115 parts of dilute sulfuric acid, 2.7 parts of graphite, 1.7 parts of tetrabasic lead sulfate, 0.9 part of short fiber, and 145 parts of water. Wherein, the graphite is heterosexual graphite, the fixed carbon content of the graphite is greater than 99.9%, the short fiber is polyester short fiber, the water is ionized water, and the particle diameter of the tetrabasic lead sulfate is 2.5 μm-4.5μm, the lead content of the tetrabasic lead sulfate is greater than 98%, and the concentration of the dilute sulfuric acid is 1.398-1.402g / cm 3 .

[0032] Concrete preparation method is:

[0033] (1) Weigh each component according to the above-mentioned composition of the positive electrode paste of the lead-acid battery, and set aside;

[0034] (2) Add graphite, short fiber, lead powder, and tetrabasic lead sulfate into the paste ma...

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Abstract

The invention belongs to the technical field of lead acid storage batteries, and particularly relates to positive electrode lead plaster of a lead acid storage battery. The positive electrode lead plaster of the lead acid storage battery is prepared from the following components in parts by weight: 1000 parts of lead powder, 110 to 120 parts of diluted sulfuric acid, 2.2 to 3.2 parts of graphite,1.2 to 2.2 parts of tetrabasic lead sulfate, 0.6 to 1.2 parts of short fiber, and 135 to 155 parts of water. Compared with the traditional positive electrode lead plaster of the lead acid storage battery, the positive electrode lead plaster of the lead acid storage battery has the advantages that the low-temperature discharge property of the storage battery is improved, the utilization rate of active substances is improved, the curing and formation time of a pole plate is shortened, the service life of the battery is prolonged, the emission of acid mist is reduced, and the environment is protected.

Description

technical field [0001] The invention relates to the field of lead-acid batteries, in particular to a positive lead paste for lead-acid batteries and a preparation method thereof. Background technique [0002] Lead-acid battery is a kind of chemical power source. It is a device that directly converts chemical energy into DC electric energy. It is used as a starting power source for vehicles and is mainly composed of a shell, positive and negative plates, separators, and electrolyte. The active material of the battery positive plate is lead dioxide, which produces lead sulfate after discharge. When producing the positive plate of the battery, lead powder is mixed with water and dilute sulfuric acid to make a lead paste, which is filled on the grid and then chemically formed. [0003] In the deep cold environment in the north, due to the increase of the viscosity of the vehicle lubricating oil, the lower the temperature, the higher the proportion of the electrolyte in the batte...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/57H01M4/62
CPCH01M4/57H01M4/62H01M4/625H01M4/628Y02E60/10
Inventor 王超张永强张后英管重阳陈为霞
Owner 山东久力新能源集团有限公司
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