Gasoline engine tailing gas particle filtering device catalyst and preparation method thereof

A technology of exhaust particles and filters, which is applied in the field of gasoline engine exhaust particulate filter catalysts and its preparation, can solve the problems of exhaust back pressure drop and high back pressure, and achieve the effect of reducing exhaust back pressure

Active Publication Date: 2019-04-16
WUXI WEIFU ENVIRONMENT PROTECTION CATALYST
View PDF5 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The object of the present invention is to provide a catalyst for a gasoline engine exhaust particulate filter with low exhaust back pressure and a preparation method thereof, aiming at the disadvantage that the existing commercial gasoline engine exhaust particulate filter catalyst generally has relatively high back pressure. While ensuring particle filtration efficiency and catalytic performance, the exhaust back pressure is significantly lower than that of commercial catalysts

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Gasoline engine tailing gas particle filtering device catalyst and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A wall-flow cordierite honeycomb ceramic carrier with a specification of Φ118.4mm*127mm, a mesh number of 300 mesh, a pore wall thickness of 203.2μm, a porosity of 65%, an average pore diameter of 20μm and a volume of 1.398L was selected. The carrier is coated with a catalytic coating, and the coating amount of the catalytic coating is 50 g / L. The distribution ratio of the catalytic coating on the inner wall of the carrier channel is 90%. The mass ratio of cerium-zirconium rare earth composite oxide to γ-alumina in the catalytic coating is 0.5:1. The composition of the cerium-zirconium rare earth composite oxide in the catalytic coating is 25% CeO by mass percentage 2 , 70% ZrO 2 , 2% La 2 o 3 and 3% Pr 6 o 11 . The loaded amount of noble Pd in ​​the catalytic coating is 0.1g / L; the loaded amount of Rh is 0.05g / L.

[0027] The preparation method of gasoline vehicle exhaust particulate matter filter catalyst, the steps are as follows:

[0028] (1) Add cerium-zir...

Embodiment 2

[0037] A wall-flow cordierite honeycomb ceramic carrier with a specification of Φ118.4mm*127mm, a mesh number of 300 mesh, a pore wall thickness of 203.2μm, a porosity of 65%, an average pore diameter of 20μm and a volume of 1.398L was selected. The carrier is coated with a catalytic coating, and the coating amount of the catalytic coating is 120 g / L. The distribution ratio of the catalytic coating on the inner wall of the carrier channel is 95%. The mass ratio of cerium-zirconium rare earth composite oxide and γ-alumina in the catalytic coating is 5:1. The composition of the cerium-zirconium rare earth composite oxide in the catalytic coating is 35% CeO by mass percentage 2 , 60% ZrO 2 , 2% La 2 o 3 and 3% Nd 2 o 3 . The loaded amount of noble Pd in ​​the catalytic coating is 1.5g / L; the loaded amount of Rh is 0.5g / L.

[0038] The preparation steps of the gasoline vehicle exhaust particulate matter filter catalyst are as follows:

[0039] (1) Add cerium-zirconium rar...

Embodiment 3

[0048] A wall-flow cordierite honeycomb ceramic carrier with a specification of Φ118.4mm*127mm, a mesh number of 300 mesh, a pore wall thickness of 203.2μm, a porosity of 65%, an average pore diameter of 20μm and a volume of 1.398L was selected. The carrier is coated with a catalytic coating, and the coating amount of the catalytic coating is 100 g / L. The distribution ratio of the catalytic coating on the inner wall of the carrier channel is 95%. The mass ratio of cerium-zirconium rare earth composite oxide to γ-alumina in the catalytic coating is 4:1. The composition of the cerium-zirconium rare earth composite oxide in the catalytic coating is 25% CeO by mass percentage 2 , 67% ZrO 2 , 3% La 2 o 3 and 5% of Y 2 o 2 . The loaded amount of noble Pd in ​​the catalytic coating is 1.5g / L; the loaded amount of Rh is 0.5g / L.

[0049] A method for preparing a catalyst for a gasoline vehicle exhaust particulate filter, comprising the following steps:

[0050] (1) Add cerium-...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
pore sizeaaaaaaaaaa
porosityaaaaaaaaaa
Login to view more

Abstract

The invention relates to a gasoline engine tailing gas particle filtering device catalyst and a preparation method thereof. The catalyst comprises a carrier, the inner wall of a hole of the carrier iscoated with a catalytic coating layer, the coating mount of the catalytic coating layer is 50-120 g/L, the height of the catalytic coating layer in the axial direction is 100% of the height f the carrier, the catalytic coating layer comprises cerium-zirconium rare-earth oxides, gamma-aluminum oxides and precious metal active components, the precious metal active components comprise Pd and Rh, wherein the loading amount of Pd is 0.1-1.5 g/L, and the loading amount of Rh is 0.05-0.5 g/h. the catalyst has the advantages that through the improvement of a catalytic coating layer coating technology, the uniform dispersing distribution on the inner wall structure of the hole of the catalytic coating layer is achieved to significantly reduce the gas discharging back pressure of a particle filtering device catalyst, the effects of intercepting particles and converting gaseous pollutants are well achieved by the uniformly distributed catalytic coating layer, and therefore gas discharging back pressure is reduced by the prepared filtering device catalyst while the particle capturing rate and catalytic performance are not impacted by negative influences.

Description

technical field [0001] The invention relates to a gasoline engine tail gas particle filter catalyst and a preparation method thereof, belonging to the technical field of tail gas post-treatment. Background technique [0002] The National VI emission standard for light-duty vehicles will be implemented on July 1, 2020. This standard has strict regulations on the number of gasoline vehicle exhaust particles: in the WLTC test cycle, the particle number (PN) emission cannot exceed 6.0×1011 / km. At present, turbocharging and in-cylinder direct injection (GDI) technologies commonly used in domestic gasoline vehicle engines not only bring about improvements in combustion efficiency and power, but also increase the number of particulate matter emissions. With the imminent implementation of the National VI regulations, many OEMs choose to install gasoline engine exhaust particulate filter (GPF) catalysts to meet the PN emission requirements of the National VI regulations. [0003] ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/63B01J35/04B01J37/02B01D53/94
CPCB01D53/94B01J23/63B01J35/04B01J37/0217B01J37/0228
Inventor 孙亮潘其建岳军浦琦伟杨金王卫东贾莉伟
Owner WUXI WEIFU ENVIRONMENT PROTECTION CATALYST
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap