Photochromic eye lens and preparation method thereof
A photochromic, ophthalmic lens technology, applied in glasses/goggles, color-changing fluorescent materials, chemical instruments and methods, etc., can solve problems such as single type
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[0014] see Figure 1 to Figure 4 , a preferred embodiment of the present invention provides a method for preparing a photochromic ophthalmic lens 100 . Wherein, the photochromic ophthalmic lens 100 may be frame glasses with photochromic function. Described preparation method comprises the steps:
[0015] Step one, see figure 1 , configure a photochromic coating solution 1, the photochromic coating solution 1 includes a photochromic compound-cyclodextrin clathrate, a crosslinking agent and a solvent.
[0016] The photochromic compound-cyclodextrin inclusion compound is a cyclodextrin enveloped with a photochromic compound. Specifically, since the inner cavity of the molecular structure of the cyclodextrin is hydrophobic, it can provide a hydrophobic binding site to envelop the photochromic compound. At the same time, photochromic compounds generally have hydrophobicity, while the outer edge of the molecular structure of cyclodextrin is hydrophilic, so cyclodextrin inclusion...
Embodiment 1
[0037] Prepare 100L of photochromic solution of chroman with a concentration of 0.01mol / L and 100L of cyclodextrin aqueous solution with a concentration of 0.01mol / L, mix the two to form clathrates and separate them from the mixed solution to prepare Obtain a photochromic compound-cyclodextrin inclusion compound; use the photochromic compound-cyclodextrin inclusion compound, methacrylic resin, TMSPMA, AIBN and ethanol solution to configure the photochromic coating solution 1 ( The mass percent of photochromic compound-cyclodextrin clathrate is 11.6%, the mass percent of methacrylic resin is 12.6%, the mass percent of TMSPMA is 3.85%, the mass percent of AIBN is 0.7%, the mass percent of ethanol solution is 71.25%); the ophthalmic lens body 10 is immersed in the photochromic coating solution 1 and heated, the heating temperature is 75 degrees centigrade, and the heating time is 60 minutes, so as to obtain the Photochromic ophthalmic lens 100.
Embodiment 2
[0039] Prepare 100L spiropyran photochromic solution with a concentration of 0.01mol / L and 100L cyclodextrin aqueous solution with a concentration of 0.01mol / L, mix the two to form clathrates and separate them from the mixed solution to obtain photochromic A color-changing compound-cyclodextrin inclusion compound; the photochromic coating solution 1 (photochromic The mass percentage of compound-cyclodextrin inclusion complex is 17.6%, the mass percentage of methacrylic acid resin is 11.3%, the mass percentage of TMSPMA is 4.85%, the mass percentage of Irgacure1173 is 1.2%, and the mass percentage of ethanol solution is 65.05% ); the ophthalmic lens body 10 is immersed in the photochromic coating solution 1 and irradiated with ultraviolet light, the light intensity of the ultraviolet light gradually changes along the extension direction of the ophthalmic lens body 10, and the wavelength of ultraviolet light 365nm, and the ultraviolet irradiation time is 10 minutes, so as to mak...
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