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Method used for preparing small particle size zinc thiazole

A thiazole zinc and particle size technology, applied in the field of agricultural chemistry, can solve problems such as industrialization difficulties, harsh centrifugal conditions, vacuum pressure conditions, and complex processing procedures

Active Publication Date: 2019-07-09
ZHEJIANG XINNONG CHEM CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

According to the content disclosed in this patent document, not only the processing procedure is complicated, but also because the centrifugal conditions and vacuum pressurization conditions used are too harsh, making industrialization very difficult.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Example 1: Effect of Mixing Speed ​​on the Nanoization of Zinc Thiazole Particles

[0030] Heat the zinc sulfate solution with a molar concentration of 4 mol / liter to 70°C, then pressurize it, and add it into the thiadiazole sodium solution with a hydraulic gun at an initial speed of 20 m / s, the thiadiazole sodium solution molar The concentration is 8 mol / liter, the temperature of the thiadiazole sodium solution is 75° C., and the thiadiazole sodium solution is in a stirring state, and the average water velocity achieved by stirring is 10 m / s.

[0031] After the thiazole zinc solution was added, the stirring speed and temperature were maintained to continue the reaction for 1 hour, and at the same time, ultrasonic vibration was performed on the reaction equipment. Then, the temperature was lowered at a rate of 20° C. / hour, and the stirring speed was kept constant during the temperature lowering.

[0032] The zinc thiazole particles prepared by the above method were sub...

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Abstract

The invention relates to a method used for preparing small particle size zinc thiazole. According to a raw material mixing method of the method, a zinc salt solution is added into a thiadiazole salt solution or the thiadiazole salt solution is added into the zinc salt solution, wherein in the process of adding the zinc salt solution into the thiadiazole salt solution, the zinc salt solution / thiadiazole salt solution initial relative speed is controlled to be 20 to 200m / s, or in the process of adding the thiadiazole salt solution into the zinc salt solution, the thiadiazole salt solution / zinc salt solution initial relative speed is controlled to be 20 to 200m / s. The method is capable of realizing preparation of small particle size zinc thiazole without using any auxiliary agent; the reaction mixing step is the key step; in the reaction mixing step, adding speed is accelerated, and with accelerating of the adding speed, the stirring speed is accelerated, so that the particle size of theprepraed zinc thiazole particles can be reduced to be lower than 2mm.

Description

technical field [0001] The invention belongs to the field of agricultural chemistry, and specifically relates to a preparation method of an antibacterial agent zinc thiazole, in particular to a method for preparing zinc thiazole with a small particle size. Background technique [0002] With the application of thiazole zinc in agriculture, especially the reduction of thiazole zinc particle size improves the activity of thiazole zinc and its good processing performance, there is an urgent need for the preparation of small particle size thiazole zinc. At present, the preparation of small particle size thiazole zinc The method generally stays in the preparation process of zinc thiazole by adding auxiliary agents, especially dispersants. However, the addition of dispersants is for reducing the particle size of zinc thiazole particles. On the one hand, there may be residual added exogenous Substances, on the other hand, add to the difficulty of disposal for the wastewater produced...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D285/135
CPCC07D285/135
Inventor 杨宏武应毅戴金贵徐群辉
Owner ZHEJIANG XINNONG CHEM CO LTD
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