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Silicon-based polymer filling material for coal mines, and preparation method thereof

A silicon-based polymer and filling material technology, which is applied in the field of coal mine filling materials, can solve problems such as difficulty in meeting long-term plugging of leaks, flammable and toxic fumes, and difficulty in wall connection to the top, and achieves adjustable foaming ratio, The effect of adjustable curing time and low cost

Inactive Publication Date: 2019-07-26
SHANDONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, my country still mainly uses cheap inorganic materials (loess, masonry, cement, fly ash, etc.) in mine filling and plugging. Under the action of deep, high ground stress, large deformation roadway and mining, the rigid wall is often deformed by fracturing, and broken to form a certain air leakage channel, which is difficult to meet the long-term plugging of air leakage.
However, organic solidified foams generally have disadvantages such as high foaming temperature, high cost, flammability, and toxic fumes released by combustion, which limit their use in coal mines.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A method for preparing a silicon-based polymer filling material for coal mines is prepared by mixing components A and B at a mass ratio of 1.2:1.

[0032] Component A is made by mixing 90kg of sodium water glass with a Baume degree of 48, 2kg of AK-8805, 3kg of TX-10, 0.08kg of 1,6-hexanediol, and 0.25kg of dimethylcyclohexylamine.

[0033] Component B is made by mixing 50kg polymethylene polyphenyl polyisocyanate, 10kgTHPO and 20kgDOP.

[0034] Stir and mix the prepared component A and component B at a weight ratio of 1.5:1 to obtain the silicon-based polymer filling material for coal mines.

[0035] The prepared silicon-based polymer filling material for coal mines is naturally foamed at normal temperature and pressure, the expansion ratio is 15 times, the highest heat storage temperature is 78°C, and it is flame retardant according to the UL94 standard combustion test.

Embodiment 2

[0037] A method for preparing a silicon-based polymer filling material for coal mines is prepared by mixing components A and B at a mass ratio of 1.3:1.

[0038] Component A is made by mixing 95kg of sodium water glass with a Baume degree of 53, 4kg of AK-8805, 3kg of OP-10, 0.1kg of 1,4-butanediol, and 0.25kg of N,N-dimethylbenzylamine.

[0039] Component B is made by mixing 45kg polymethylene polyphenyl polyisocyanate, 8kg TCPP, and 20kg chlorinated paraffin-52.

[0040] Stir and mix the above components A and B at a weight ratio of 1.4:1 to obtain the silicon-based polymer filling material for coal mines.

[0041] The prepared silicon-based polymer filling material for coal mines is naturally foamed at normal temperature and pressure, the expansion ratio is 6 times, the highest heat storage temperature is 83°C, and it is flame retardant according to the UL94 standard combustion test.

Embodiment 3

[0043] A method for preparing a silicon-based polymer filling material for coal mines is prepared by mixing components A and B at a mass ratio of 1.4:1.

[0044] Component A is made by mixing 85kg of sodium water glass with a Baume degree of 45, 4.5kg of AK-8805, 5kg of TX-10, 0.12kg of 1,4-butanediol, and 0.25kg of N,N-dimethylbenzylamine.

[0045] Component B is made by mixing 45kg polymethylene polyphenyl polyisocyanate, 8kgDMMP and 25kgDOP.

[0046] Stir and mix the above-mentioned component A and component B at a weight ratio of 1.5:1 to obtain a silicon-based polymer filling material for coal mines.

[0047] The prepared silicon-based polymer filling material for coal mines is naturally foamed at normal temperature and pressure, the expansion ratio is 20 times, the highest heat storage temperature is 76°C, and it is flame retardant according to the UL94 standard combustion test.

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PUM

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Abstract

The invention discloses a silicon-based polymer filling material for coal mines, and relates to the technical field of filling materials for the coal mines. The silicon-based polymer filling materialis prepared from a component A and a component B through mixing, wherein the mass ratio of the component A to the component B is (1.2-1.6):1, the component A is prepared from water glass, a compositecatalyst, a foam stabilizer and a surfactant through mixing, and the component B is prepared from isocyanate, a flame retardant and a plasticizer through mixing. The invention also discloses a preparation method of the silicon-based polymer filling material for the coal mines. The silicon-based polymer filling material has the advantages of environment protection, adjustability in expansion times,low heat storage and self-extinguishing, solving the problems of poor environmental protection property, low tight-filling rate, high heat release and no flame retardance of current filling materialsfor the coal mines.

Description

technical field [0001] The invention relates to the technical field of filling materials for coal mines, in particular to a silicon-based polymer filling material for coal mines and a preparation method thereof. Background technique [0002] Coal spontaneous combustion is a major hidden danger hindering the safe mining of coal mines. One of the important causes of coal spontaneous combustion is air leakage in gobs or roadways. Therefore, the use of suitable filling and plugging materials is one of the main means to block air leakage and prevent spontaneous combustion of coal seams, which has huge economic and important social benefits for ensuring coal safety production. [0003] At present, my country still mainly uses cheap inorganic materials (loess, masonry, cement, fly ash, etc.) in mine filling and plugging. Under the action of deep, high ground stress, large deformation roadway and mining, the rigid wall is often deformed by fracturing, and broken to form a certain a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/38C08G18/32C08J9/08C08G101/00
CPCC08G18/3206C08G18/3895C08G2110/0083
Inventor 贺正龙陆伟李金亮秦传睿孔彪亓冠圣徐帅吴磊胡相明
Owner SHANDONG UNIV OF SCI & TECH
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