Negative plate and lithium ion battery

A technology of negative electrode and negative electrode, applied in the field of negative electrode and lithium ion battery, can solve the problem of poor cycle performance, achieve high liquid retention, ensure electronic conductivity, and good ionic conductivity.

Active Publication Date: 2019-08-20
ZHUHAI COSMX BATTERY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The object of the present invention is to solve the problem of poor cycle performance caused by the volume effect of the silicon-based negative electrode, and provide a negative electrode sheet and a lithium ion battery. The negative electrode sheet has high compaction and high capacity performance, and the preparation process is simple and convenient. The obtained lithium-ion battery has the advantages of high energy density and good cycle performance. At the same time, it can avoid lithium deposition on the surface of the negative electrode sheet under high-rate fast charging, which meets the needs of industry applications.

Method used

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specific Embodiment approach 1

[0014] Embodiment 1: This embodiment describes a negative electrode sheet, including a negative electrode current collector and a film layer coated on the current collector. The film layer is divided into two layers, and the first film layer is close to the current collector. The underlying graphite coating of the fluid, the coating has the characteristics of large compaction, small expansion of the coating after charging, and poor liquid storage capacity; the second film layer is the top silicon-containing coating far away from the current collector, and the coating has High gram capacity, large coating expansion after charging, and strong liquid storage capacity; among them, the proportion of silicon material in the top silicon-containing coating is 5wt.% ~ 30wt.%; the silicon material in the negative electrode sheet accounts for 10% of the total active material weight of the negative electrode sheet 5%~20%; After coating and drying, the thickness of the bottom graphite coati...

specific Embodiment approach 2

[0015] Specific embodiment two: a kind of negative electrode sheet described in specific embodiment one, adopts double-mode coating head extrusion coating machine, two kinds of slurries are coated on the negative electrode current collector at the same time, on the same side of the negative electrode current collector After forming a double-layer paste structure, prepare a silicon-containing coating on the top layer, and a silicon-free pure graphite layer on the bottom double-layer coating negative electrode sheet; after coating one side of the current collector, repeat the other side according to the above way to coat.

specific Embodiment approach 3

[0016] Embodiment 3: In the negative electrode sheet described in Embodiment 1, the negative electrode current collector is one of homogeneous copper foil, porous copper foil and copper foil with carbon coating.

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Abstract

The invention discloses a negative plate and a lithium ion battery, and belongs to the technical field of lithium ion batteries. The negative plate comprises a negative current collector and a film coated on the negative current collector; the film is divided into two layers, the first layer of coating is a bottom graphite coating close to the negative current collector, and the second layer of coating is a top silicon-containing coating layer far away from a copper foil. By adopting the technology of dual-layer coating, two types of slurry coats the negative current collector at the same time, after a dual-layer paste coating structure is formed on the same side of the negative current collector, a dual-layer coated negative plate with a silicon-containing coating on the top layer and a silicon-free pure graphite layer on the bottom layer is prepared, and the prepared negative plate has high compaction and high capacity performance, and the preparation method is simple and convenientin process; and the prepared lithium ion battery has the advantages of the high energy density and the good cycle performance, and can avoid lithium precipitation on the surface of the negative plateunder the condition of high-rate quick charging, so that the industrial application requirements are met.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a negative electrode sheet and a lithium ion battery. Background technique [0002] In recent years, with the continuous expansion of the industrial scale of lithium-ion batteries and the continuous development of related technologies, lithium-ion batteries have become energy storage devices for mainstream electronic products, and the uses of lithium-ion batteries have been greatly expanded. At the same time, people's performance requirements for lithium-ion batteries have also been further improved, requiring lithium-ion batteries to have high energy density and long cycle life. [0003] At present, one of the methods for improving the energy density of the negative electrode is to adopt technologies such as the combination of large and small particles to improve the compaction of the negative electrode, but high pressure compaction will lead to low por...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/133H01M4/134H01M4/36H01M4/38H01M4/587H01M10/0525
CPCH01M4/133H01M4/134H01M4/366H01M4/386H01M4/587H01M10/0525H01M2004/027Y02E60/10
Inventor 彭冲陈秀梅李俊义徐延铭
Owner ZHUHAI COSMX BATTERY CO LTD
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