Unlock instant, AI-driven research and patent intelligence for your innovation.

High performance-price-ratio polycarboxylic acid water reducing agent

A cost-effective, polycarboxylic acid technology, used in the field of cement concrete admixtures, can solve the problems of increasing the amount of admixtures, reducing workability, and deteriorating concrete performance, and achieves reduction in reducing agent cost, ultimate cost reduction, and strong market competitiveness. Effect

Inactive Publication Date: 2019-11-12
山东银泰化学技术有限公司
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the extensive application of cement concrete materials, the demand for corresponding raw materials has increased. However, at present, not only the quantity of concrete raw materials is limited, but also the quality of raw materials is more prominent. There are also many problems, especially the insufficient supply of sand and gravel materials and excessive mud content. Seriously affect the workability of concrete preparation and the strength and durability of products
The most prominent performance deterioration of concrete is the reduction of workability. The current basic solutions are: first, increase the amount of admixtures, and second, purify sand and gravel. These measures will cause corresponding cost increases, which are unacceptable to relevant enterprises.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • High performance-price-ratio polycarboxylic acid water reducing agent
  • High performance-price-ratio polycarboxylic acid water reducing agent
  • High performance-price-ratio polycarboxylic acid water reducing agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A preparation method of a cost-effective polycarboxylate superplasticizer, using methallyl polyoxyethylene ether, acrylic acid, and itaconic acid as comonomers, and synthesizing basic building blocks under the action of reducing agent glucose; Auxiliary building blocks are added to the building blocks to obtain a cost-effective polycarboxylate superplasticizer.

[0024] The auxiliary building element is a mixture of water-retaining element, retarding element, early-strength element, air-entraining element and defoaming element.

[0025] The weight ratio of the basic building blocks to the auxiliary building blocks is 100:1.

[0026] The ratio of the methallyl polyoxyethylene ether to the acrylic acid is 1:3.

[0027] The amount of the comonomer is 3% of the total mass of the polymerized monomers.

[0028] The amount of the reducing agent is 0.2% of the total mass of the polymerized monomers.

[0029] The consumption of described water retention unit is 2% of the tota...

Embodiment 2

[0039] A method for preparing a cost-effective polycarboxylate water reducer, using methallyl polyoxyethylene ether, acrylic acid, and acrylamide as comonomers, and synthesizing basic building blocks under the action of reducing agent glucose; Auxiliary building blocks are added to the basic units to obtain a cost-effective polycarboxylate superplasticizer.

[0040] The auxiliary building element is a mixture of water-retaining element, retarding element, early-strength element, air-entraining element and defoaming element.

[0041] The weight ratio of the basic building blocks to the auxiliary building blocks is 100:7.

[0042] The ratio of the methallyl polyoxyethylene ether to the acrylic acid is 1:3.5.

[0043] The amount of the comonomer is 4% of the total mass of the polymerized monomers.

[0044] The amount of the reducing agent is 0.25% of the total mass of the polymerized monomers.

[0045] The consumption of described water retention unit is 2.5% of the total mass...

Embodiment 3

[0055] A preparation method of a cost-effective polycarboxylate superplasticizer, using methallyl polyoxyethylene ether, acrylic acid, and sodium styrene sulfonate as comonomers, and synthesizing basic building blocks under the action of reducing agent glucose; Auxiliary building blocks are added to the basic building blocks to obtain a cost-effective polycarboxylate superplasticizer.

[0056] The auxiliary building element is a mixture of water-retaining element, retarding element, early-strength element, air-entraining element and defoaming element.

[0057] The weight ratio of the basic building blocks to the auxiliary building blocks is 100:15.

[0058] The ratio of the methallyl polyoxyethylene ether to the acrylic acid is 1:4.

[0059] The amount of the comonomer is 5% of the total mass of the polymerized monomers.

[0060] The amount of the reducing agent is 0.3% of the total mass of the polymerized monomers.

[0061] The consumption of described water-retaining unit...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention belongs to the technical field of cement concrete admixtures, and particularly relates to a high performance-price-ratio polycarboxylic acid water reducing agent preparation method. According to the present invention, a basic constructing unit is synthesized by using methylallyl polyoxyethylene ether, acrylic acid and a comonomer as polymerization monomers under the action of a reducing agent, and an auxiliary constructing unit is added to the basic constructing unit to obtain the high performance-price-ratio polycarboxylic acid water reducing agent; the technology is guided by the concepts of molecular chemistry and supramolecular chemistry, establishes the basic constructing unit and the auxiliary constructing unit for the supramolecular assembly of GPCA products, and optimizes the supramolecular assembly; the test and application results prove that the related performances of the assembled high performance-price-ratio polycarboxylic acid water reducing agent meet the first grade standard requirements of the corresponding product, the consumption of the macromonomer in the product is reduced by 10-15% compared with the similar product, the coat of the initiation system can be reduced by 30-40%, the ultimate cost of the product is reduced by 8-15%, the adaptability is improved, and the product has strong market competitiveness.

Description

technical field [0001] The invention belongs to the technical field of cement concrete admixtures, and in particular relates to a preparation method of a cost-effective polycarboxylate water reducer. Background technique [0002] Concrete admixtures have become one of the main components of cement concrete materials, and water reducers are the most important components. Among the four basic properties of concrete durability, workability, strength and economy, admixtures are one of their indispensable and important components. With the extensive application of cement concrete materials, the demand for corresponding raw materials has increased. However, at present, not only the quantity of concrete raw materials is limited, but also the quality of raw materials is more prominent. There are also many problems, especially the insufficient supply of sand and gravel materials and excessive mud content. Seriously affect the workability of concrete preparation and the strength and ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/06C08F220/06C08F222/02C08F220/56C08F212/14C04B24/16C04B24/26C04B103/30
CPCC04B24/165C04B24/2658C04B24/267C04B2103/302C08F283/065C08F220/06C08F222/02C08F220/56C08F212/14
Inventor 王永本张栓红王惠忠
Owner 山东银泰化学技术有限公司