A spatula-based electrochemical biosensor
A biosensor and electrochemical technology, applied in the field of biosensing, can solve the problems of high cost, incompetence of detection instruments, large and complex instruments, etc., and achieve the effect of high accuracy and stable current
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Embodiment 1
[0057] image 3 H measured for the electrochemical biosensor of the present invention in embodiment one 2 o 2 Detection representation diagram. In this embodiment, an electrochemical workstation is used as a power source to detect the spatula sensor H 2 o 2 concentration test. image 3 H is shown using an electrochemical workstation and based on the electrochemical biosensor of the present invention 2 o 2 detected features. Use an electrochemical workstation to measure at 0.6V, place 200 μl of 50 mM buffer solution on the wearable sensor, and then add 10 μl of various concentrations of H 2 o 2 solution; let the mixture stand until the current stabilizes, then continue to add the next concentration of H 2 o 2 . image 3 Among them, C1~C8 are the concentration changes of the detected substances in the solution after the dropwise addition (the same below): C1:0.1mM, C2:0.2mM, C3:0.2mM, C4:0.5mM, C5:1.0mM, C6: 1.0mM, C7: 1.0mM, C8: 1.0mM. image 3 a shows the H 2 o ...
Embodiment 2
[0059] Figure 4 It is the glucose detection characterization graph measured by the electrochemical biosensor of the present invention in Example 2. In this embodiment, an electrochemical workstation was used as a power source to conduct a test for detecting glucose concentration using the electrochemical biosensor of the present invention. Figure 4 Shown is the time-current curve of using the electrochemical workstation as an instrument to detect lactic acid with the electrochemical biosensor of the present invention. Set the voltage of the electrochemical workstation to 0.6 V, then add 200 μl of 50 mM buffer solution, and add 10 μl of each concentration of glucose solution on top of the working electrode. After waiting for the current to stabilize, continue to drop the next concentration of lactic acid. Figure 4Among them, C1~C10 are the concentration changes of the detected substances in the solution after the dropwise addition (the same below): C1:0.1mM, C2:0.2mM, C3:0...
Embodiment 3
[0061] Figure 5 It is the glucose detection characterization graph measured by the electrochemical biosensor of the present invention in Example 3. In this embodiment, the glucose in the saliva of a real person is detected, and 180 μl of a healthy male saliva sample is taken as a buffer solution, and 20 μl of a glucose solution with a concentration of 1 mM is added dropwise thereto to increase the total glucose concentration by 0.1 mM, that is, 100 μM. The ability of the electrochemical biosensor of the present invention to distinguish saliva from healthy and diabetic patients was tested. The average current response of the electrochemical biosensor of the present invention to a glucose concentration change of 0.1 mM is 0.20 μA, the standard deviation is 0.011 μA, and the concentration detection value corresponding to the standard working curve is 93.1±5.1 μM.
[0062] The electrochemical biosensor based on spatula provided by the present invention can detect the glucose con...
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