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Oil spilling repair agent, preparation method thereof, and oil spilling in-situ repair method

A restoration agent and oil spill technology, applied in separation methods, chemical instruments and methods, fixed on/in organic carriers, etc., can solve problems such as immobilized particles that do not mention floating microbe-degrading bacteria on the water surface, etc., achieve good results

Pending Publication Date: 2019-12-17
ZHEJIANG OCEAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the above patents do not mention the immobilized particles of the floating microbial degrading bacteria on the water surface.

Method used

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  • Oil spilling repair agent, preparation method thereof, and oil spilling in-situ repair method
  • Oil spilling repair agent, preparation method thereof, and oil spilling in-situ repair method
  • Oil spilling repair agent, preparation method thereof, and oil spilling in-situ repair method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038](1) Weigh 1000g of agar, add 50L of water, heat it to 90°C, then pass in 120°C of water vapor for heat melting, add 50L of normal temperature water and stir to adjust the temperature to 65°C, the concentration of agar at this time is 10g / L, and then add 1g of surfactant sodium lauryl sulfate, the concentration of which in the solution is 0.01g / L, stir at a speed of 10rpm for about 1h to make it evenly mixed, and keep the aqueous solution at 65°C for heat preservation.

[0039] (2) Use corn cob as the wood fiber carrier, crush and sieve with a pulverizer, adjust the size of the sieve, and take crushed particles with a size of 1 to 3mm, 4 to 6mm, 7 to 10mm, and 11 to 20mm in a ratio of 1:1: Mix 2:4, the total weight is 5KG, disperse the commercially available or self-made microbial agent with water to prepare 5KG of microbial agent suspension, pour the agent suspension evenly on the corncob particles, and roll and stir to complete Mix well, turn the particles over every t...

Embodiment 2

[0042] (1) Weigh 2000g of agar, add 50L of water, heat to 90°C and then pass through 120°C water vapor for thermal melting, add 50L of normal temperature water and stir to adjust the temperature to 35°C, the concentration of agar at this time is 20g / L, then add 200g soap powder as a surfactant, the concentration in the solution is 2g / L, stir at a speed of 50rpm for about 1h to make it evenly mixed, and keep the aqueous solution at 35°C for heat preservation.

[0043] (2) Use corn stalks, corn cobs, and sorghum stalks as wood fiber carriers, grind and sieve with a pulverizer, adjust the sieve size, take 10KG of crushed particles with a size of 5-20 mm, and mix commercially available or self-made microbial bacteria Disperse the agent with water to make 50KG of microbial agent suspension, pour the agent suspension evenly on the pulverized particles, and roll and stir to mix evenly, and the mixing time of the two is 10min.

[0044] (3) Wrap the pretreated particles with a total w...

Embodiment 3

[0046] (1) Weigh 3000g of agar, add 50L of water, heat it to 90°C, then pass in 120°C of water vapor for thermal melting, add 50L of normal temperature water and stir to adjust the temperature to 45°C, the concentration of agar at this time is 30g / L, then add 50g each of Tween-80 and octylphenol polyoxyethylene ether-100 as surfactants, the total concentration in the solution is 1g / L, stir at a speed of 20rpm for about 1h to make it evenly mixed, this aqueous solution is at 45 ℃ insulation.

[0047] (2) Use wheat straw and cotton straw as the wood fiber carrier, crush and sieve with a pulverizer, adjust the size of the sieve, take 20KG of crushed particles with a size of 2-10mm, and disperse the commercially available or self-made microbial agent with water. Prepare 80KG of microbial bacterial agent suspension, pour the bacterial agent suspension evenly on the pulverized particles, and roll and stir to mix evenly, and the mixing time of the two is 24 hours.

[0048] (3) Wrap...

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Abstract

The invention relates to an oil spilling repair agent, a preparation method thereof, and an oil spilling in-situ repair method. The preparation method of the oil spilling repair agent comprises the steps: a first carrier is provided and is a wood fiber carrier of a porous structure; a microbial agent suspension is provided, the first carrier is mixed with the microbial agent suspension to enable microorganisms to be adsorbed by the first carrier, and a second carrier is obtained; and an aqueous solution containing agar and a surfactant is provided, the second carrier and the aqueous solution are mixed in a container, thus the second carrier is wrapped with the agar to form an intermediate, the intermediate in the container is dispersed to form particles, the particles are blown away through airflow, and the oil spilling repair agent is obtained. The density of the oil spilling repair agent obtained through the preparation method is smaller than the density of water, thus the oil spilling repair agent can be dispersed and float on the water surface, with step-by-step crushing and degradation of the agar in the water environment, the microorganisms adsorbed by the wood fiber carrierare released step by step and make full contact with oil contamination on the water surface, and the good in-situ repair effect is achieved.

Description

technical field [0001] The invention relates to the technical field of ecological restoration, in particular to an oil spill restoration agent, a preparation method thereof, and an in-situ restoration method of oil spill. Background technique [0002] There have been many related researches on the oil spill restoration of oceans or rivers, such as: the invention patent CN201611121360.2 relates to an immobilized microbial oil spill restoration agent, which is based on sodium alginate-CaCl 2 -Bio-based activated carbon is made for the carrier to embed microorganisms. Invention patent CN201410190244.0 relates to an immobilized microbial oil spill restoration agent. The carrier components of the immobilized microbial oil spill restoration agent include mussel shells, sodium alginate, CaCl 2 . Invention patent CN201310016703.9 relates to an immobilized microbial oil spill restoration agent, which is based on sodium alginate-CaCl 2 -Peanut shell-based activated carbon is used a...

Claims

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Application Information

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IPC IPC(8): C12N11/12C12N11/10C02F3/34C02F1/40C02F101/32
CPCC12N11/12C12N11/10C02F3/343C02F3/344C02F1/40C02F2101/32
Inventor 王恒伟
Owner ZHEJIANG OCEAN UNIV