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Textile dye fixing agent and application thereof

A technology for textile dyes and color-fixing agents, applied in the field of textile printing and dyeing auxiliaries, can solve problems such as decreased color fastness, and achieve the effects of increased crosslinking density, excellent blister fastness, and improved blister fastness.

Active Publication Date: 2020-01-07
浙江新海天生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The conventional mercerizing process of cotton knitted fabrics is carried out before dyeing, but in the subsequent dyeing and finishing process, the mercerizing effect of cotton fabrics is significantly affected by long-term repeated physical friction, extrusion and chemical action. The superior performance of knitted fabrics improves product quality, and the processing route of cotton knitted fabrics that is dyed first and then mercerized has emerged as the times require. Alkali (NaOH200~280g / L) treatment, further hydrolysis of reactive dyes will cause floating color, therefore, the color fastness will be seriously reduced, and it needs to be fixed with a color-fixing agent with excellent tolerance, especially alkali resistance, to ensure the quality of the fabric promotion

Method used

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  • Textile dye fixing agent and application thereof
  • Textile dye fixing agent and application thereof
  • Textile dye fixing agent and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0104] This embodiment provides a textile dye fixing agent, which specifically comprises a mole of a copolymerization unit represented by formula (I-1), b mole of a copolymerization unit represented by formula (II-1), and c mole of a copolymerization unit represented by formula (II-1) and c mole of a copolymerization unit represented by formula Polymers of copolymerized units shown in (III-1):

[0105]

[0106] In the formula, the R 1 , R 2 , R 5 , R 6 are hydrogen, R 7 is-CH 2 CH 3 , R 11 is-CH 2 CH 2 OH, R 13 is -C(O)O CH 2 CH 3 ; the R 4 is-CH 2 CH 2 SH, R 12 is-CH 2 SH, R 14 is-CH 2 CH 2 CH 2 SH; the R 9 is-CH 3 , R 10 is-CH 2 CH 2 COOH; the R 3 Yes -C(O)O-, R 8 It is -C(O)NH-; said m and n are both 1; said Indicates the counter ion, all are Cl - .

[0107] In terms of molar weight, the molar ratio of a:b:c is 1:1.5:2; in terms of weight average molecular weight, the weight average molecular weight of the textile dye fixing agent is 30000~...

Embodiment 2

[0131] This embodiment provides item [1]: a textile dye fixing agent, which specifically comprises a mole of a copolymerization unit shown in the following formula (I-2), b moles of a copolymerization unit shown in the following formula (II-2) And the polymer of the copolymerization unit shown in c mole following formula (III-2):

[0132] The present embodiment also provides item [2]: as described in item [1], is used for the preparation method of the polymer of textile dye fixing agent, comprises polymerizing following formula (I'-2), (II) in the presence of initiator The monomer represented by '-2) and (III'-2), wherein the copolymerization unit as shown in formula (I-2) described in item [1] is derived from the following formula (I'-2), item [1] The described copolymerization unit shown in formula (II-2) is obtained by the following formula (II'-2), and the copolymerization unit shown in formula (III-2) described in item [1] is obtained by the following formula (III'-2) ) ...

Embodiment 3

[0151] Embodiment 3 is substantially the same as embodiment 2, except that (I'-2), (II'-2) and (III'-2), therefore, the copolymerization unit thereof is the corresponding copolymerization unit formed after the carbon-carbon double bond of the corresponding monomer is opened.

[0152]

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Abstract

The invention provides a textile dye fixing agent and application thereof, and belongs to the technical field of textile printing and dyeing assistants. Specifically, the textile dye fixing agent comprises a mole of at least one copolymerized unit shown as formula (I), b mole of at least one copolymerized unit shown as formula (II) and c mole of at least one copolymerized unit shown as formula (III); the beneficial effects are that: the textile dye fixing agent disclosed by the invention is a polymer; the preparation method is simple, the reaction is mild, the phenomena of implosion, gelling and the like are avoided, a new branched structure containing silicon-carbon chains, nitrogen-carbon chains, particularly silicon-oxygen chains is introduced, and sulfydryl is introduced and condensedinto disulfide bonds, so that the crosslinking density of the textile dye fixing agent is further increased, and the resistances such as wear resistance, water soaking resistance and the like are greatly improved.

Description

technical field [0001] The invention belongs to the technical field of textile printing and dyeing auxiliaries, and in particular relates to a textile dye fixing agent and its application. Background technique [0002] Cotton fabrics are widely loved by consumers because of their moisture absorption and breathability. After continuous development, the quality of cotton fabrics is increasingly catering to people's increasing wearing needs. Among them, mercerized cotton fabrics are one of the most popular products among consumers. Mercerized cotton fabric is not only comfortable to wear and has a silky luster, but also has stable dimensions, crispness, and good wrinkle resistance. It is widely used in products such as T-shirts, moisture-wicking fabrics, and high-end shirts. The conventional mercerizing process of cotton knitted fabrics is carried out before dyeing, but in the subsequent dyeing and finishing process, the mercerizing effect of cotton fabrics is significantly aff...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F226/02C08F230/08D06P5/08
CPCC08F226/02D06P5/08C08F230/08
Inventor 唐伟芹
Owner 浙江新海天生物科技有限公司
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