Activation method of proton exchange membrane fuel cell

A proton exchange membrane, fuel cell technology, applied in fuel cells, electrochemical generators, circuits, etc., can solve problems such as shortening the activation time of ordered cells, reducing hydrogen consumption, poor membrane electrode performance, etc., to achieve improved activation. Efficiency, improved performance, efficient and stable performance

Active Publication Date: 2020-01-14
FAW JIEFANG AUTOMOTIVE CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] CN101582513B discloses a method for accelerating fuel cell activation, by cutting off the air supply of the air electrode, reducing the fuel cell voltage threshold level to 0.2V, or even lower 0-0.2V, to realize the activation of the fuel cell, and compared with the traditional The constant current activation mode, the activation time is greatly shortened, and the hydrogen consumption is relatively reduced; however, during the activation process, the voltage of the fuel cell is greatly reduced, which inevitably requires higher performance of the membrane electrode. In terms of control, if there is misoperation or Membrane electrode performance is not good, it is easy to cause damage to the membrane electrode
This method can complete the activation of proton exchange fuel cells in a short time, greatly shortening the activation time of ordered cells; but this method is only applicable to the activation of ordered proton exchange fuel cells, as known in the art, the Protons are formed by growth and have good order, but currently used fuel cells are seldom formed by growth, so this method has great limitations

Method used

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  • Activation method of proton exchange membrane fuel cell

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0074] This embodiment provides a method for activating a proton membrane exchange membrane fuel cell. The test object of this embodiment is that the effective active area is 50 cm 2 The monolithic battery comprises the following steps:

[0075] (1) The proton exchange membrane fuel cell to be activated is connected on the test bench, and the flow rate is 2L / min dry nitrogen for 5min to the anode side and the cathode side, and then the flow rate is 2L / min and the humidity is 60%RH. Humidify nitrogen, and adjust the operating temperature of the proton exchange membrane fuel cell to 70°C for 15 minutes;

[0076] (2) The flow rate of 0.03L / min and the humidity of 60%RH are passed into the anode side for 15s, and the flow rate of the cathode side is 0.2L / min and the humidity is 60%RH of humidified air for 15s, and then the proton exchange membrane fuel is set. The battery operates in constant voltage mode, so that the voltage of each single cell in the proton exchange membrane fu...

Embodiment 2

[0084] This embodiment provides a method for activating a proton membrane exchange membrane fuel cell. The test object of this embodiment is a single sheet with an effective active area of ​​50 cm 2 The stack consists of 5 single cells, including the following steps:

[0085] (1) The proton exchange membrane fuel cell to be activated is connected on the test bench, and the flow rate is 10L / min dry nitrogen for 15min to the anode side and the cathode side, and then the flow rate is 10L / min and the humidity is 100%RH. Humidify nitrogen, and adjust the operating temperature of the proton exchange membrane fuel cell to 60°C for 40 minutes;

[0086] (2) The flow rate of 0.15 L / min and humidity of 100% RH are passed into the anode side for 40 seconds, and the flow rate of 1 L / min into the cathode side is humidified air of 100% RH for 40 seconds, and then the proton exchange membrane fuel cell is set. Operate in constant voltage mode so that the voltage of each single cell in the pr...

Embodiment 3

[0094]This embodiment provides a method for activating a proton membrane exchange membrane fuel cell. The test object of this embodiment is a single sheet with an effective active area of ​​50 cm 2 The stack consists of 10 single cells, including the following steps:

[0095] (1) The proton exchange membrane fuel cell to be activated is connected on the test bench, and the flow rate is 30L / min dry nitrogen for 10min to the anode side and the cathode side, and then the flow rate is 30L / min and the humidity is 80%RH. Humidify nitrogen, and adjust the operating temperature of the proton exchange membrane fuel cell to 80°C for 10 minutes;

[0096] (2) The flow rate of 0.3L / min into the anode side is humidified hydrogen with a humidity of 80%RH for 10s, and the flow rate of 2L / min into the cathode side is humidified air with a humidity of 100%RH for 10s, and then the proton exchange membrane fuel cell is set Operate in constant current mode so that the voltage of each single cell ...

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Abstract

The invention provides an activation method of a proton exchange membrane fuel cell. The activation method of the proton exchange membrane fuel cell comprises the following steps: alternately applyingback pressure to the anode side and the cathode side of the proton exchange membrane fuel cell to form a pressure difference between the anode side and the cathode side so as to complete the activation process of the proton exchange membrane fuel cell. The activation method has high activation efficiency, less hydrogen consumption and high safety and can be used in proton exchange membrane fuel cells with different power levels. The pressure difference is formed on the two sides of the membrane electrode by repeatedly and alternately applying a suitable back pressure on the anode side and thecathode side of the proton exchange membrane fuel cell to improve the wetting of the membrane electrode, and the water generated by the reaction is utilized to quickly open up the water and gas transmission channel of the catalytic layer under the action of the pressure difference to remove impurities in the flow field and promote the formation of a gas, liquid and solid three-phase reaction interface so as to efficiently and stably improve the performance of the fuel cell and achieve the purpose of activating the cell.

Description

technical field [0001] The invention belongs to the field of fuel cells and relates to an activation method for a proton exchange membrane fuel cell. Background technique [0002] As a device that can directly convert chemical energy into electrical energy, and the only product is water, the proton exchange membrane fuel cell is unanimously considered to be the cleanest and most efficient energy technology in the 21st century. Proton exchange membrane fuel cells are usually composed of packaged end plates, collector plates, bipolar plates, membrane electrodes and some sealing parts. Three independent flow field channels are formed inside the assembled battery, namely the anode side flow field, cathode side flow field, and cathode side flow field. The flow field and the cooling flow field, among which, the anode side flow field and the cathode side flow field are separated by membrane electrodes, and hydrogen and air are respectively fed in as the reaction raw materials of th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/04223H01M8/04746H01M8/04828
CPCH01M8/04223H01M8/04783H01M8/04828Y02E60/50
Inventor 崔新然米新艳张克金李军泽王茁曹婷婷
Owner FAW JIEFANG AUTOMOTIVE CO
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