Anti-yellowing bright uv paint and its production process

A production process and anti-yellowing technology, applied in the field of coatings, can solve the problems of not achieving high whiteness, yellowing of paint film, yellowing, etc., and achieve the effect of improving yellowing resistance, not easy to yellow, and small shrinkage

Active Publication Date: 2021-04-13
漳州市和兴涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The above-mentioned existing technical solutions have the following defects: there are unsaturated double bonds, peroxides, etc. in the UV paint. After long-term light, the unsaturated double bonds, peroxides, etc. of the UV paint will be oxidized and turn yellow. Later yellowing, resulting in yellowing of the paint film, which cannot meet the requirement of high whiteness

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Anti-yellowing bright UV paint, by weight, includes the following components, 41.2 parts of polyurethane acrylate, 20 parts of ethyl ester, 10 parts of butyl ester, 3 parts of photoinitiator, 15 parts of UV monomer, and 0.8 part of leveling agent , 10 parts of cellulose acetate butyrate, 1.5 parts of fluorescent whitening agent OB-1; among them, 7 parts of UV monomers including IBOMA and 8 parts of TMPTA.

[0036] The leveling agent is BYK-333, and the photoinitiator is photoinitiator 1173.

[0037] Fluorescent whitening agent OB-1 undergoes the following modification steps:

[0038] S1: Add fluorescent whitening agent OB-1 into water, and add 5mL of water for every 1g of fluorescent whitening agent OB-1, and ultrasonically disperse for 10min;

[0039] S2: Under the condition of uniform stirring, add water glass so that the mass concentration of water glass in the solution after adding water glass is 10%, then add concentrated sulfuric acid drop by drop to adjust the p...

Embodiment 2

[0050] The difference with embodiment 1 is:

[0051] Anti-yellowing bright UV paint, by weight, includes the following components, 35 parts of polyurethane acrylate, 15 parts of ethyl ester, 8 parts of butyl ester, 2 parts of photoinitiator, 11 parts of UV monomer, 0.4 part of leveling agent , 8 parts of cellulose acetate butyrate, 1 part of fluorescent whitening agent OB-1; among them, the UV monomer includes 6 parts of IBOMA and 5 parts of TMPTA.

[0052] In the modification treatment step S2 of fluorescent whitening agent OB-1, the mass concentration of water glass in the solution after adding water glass is 5%, then add concentrated sulfuric acid drop by drop to adjust the pH to 5, then heat it in a water bath to 40°C, and keep the temperature constant Heating for 4h, drying at 70°C for 8h, and calcining at 300°C for 8h.

[0053] In the production step S3 of the anti-yellowing bright UV paint, the temperature is raised to 80°C.

Embodiment 3

[0055] The difference with embodiment 1 is:

[0056] Anti-yellowing bright UV paint, by weight, includes the following components, 50 parts of polyurethane acrylate, 25 parts of ethyl ester, 12 parts of butyl ester, 5 parts of photoinitiator, 17 parts of UV monomer, and 1 part of leveling agent , 13 parts of cellulose acetate butyrate, 3 parts of fluorescent whitening agent OB-1; among them, UV monomers include 10 parts of IBOMA and 7 parts of TMPTA.

[0057] In the modification treatment step S2 of the fluorescent whitening agent OB-1, in S2, the mass concentration of water glass in the solution after adding water glass is 20%, then add concentrated sulfuric acid drop by drop to adjust the pH to 7, and then heat it in a water bath to 50 ℃, heated at constant temperature for 6h, dried at 80°C for 10h, and calcined at 300°C for 10h.

[0058] In the production step S3 of the anti-yellowing bright UV paint, the temperature is raised to 90°C.

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PUM

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Abstract

The invention relates to anti-yellowing bright UV paint, which belongs to the technical field of coatings, and comprises the following components in parts by weight, 35-50 parts of polyurethane acrylate, 15-25 parts of ethyl ester, 8-12 parts of butyl ester, photosensitive trigger 2-5 parts of UV monomer, 11-17 parts of UV monomer, 0.4-1 part of leveling agent, 8-13 parts of cellulose acetate butyrate, 1-3 parts of fluorescent whitening agent OB-1, and 1-3 parts of fluorescent whitening agent OB ‑1 undergoes the following modification steps: S1: Add the fluorescent whitening agent OB‑1 to water, and disperse it ultrasonically for 10 minutes; S2: Add water glass under constant stirring, and then add concentrated sulfuric acid drop by drop to adjust the pH to 5‑ 7. Then heat in a water bath to 40-50°C, heat at a constant temperature for 4-6h, suction filter after the reaction, dry at 70-80°C for 8-10h, and calcine at 300°C for 8-10h. The invention has the effect of improving the anti-yellowing performance in the later stage.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to an anti-yellowing bright UV paint and a production process. Background technique [0002] At present, UV paint is ultraviolet photocuring paint, also known as photoinitiated coating and photocuring coating. Unlike PU, PE, NC and other paints named after the film-forming substances, UV paints are named after the curing method of the paint. It is automatically rolled and sprayed onto the surface of the furniture board by machinery and equipment. Under the irradiation of ultraviolet light (wavelength 320-390nm), the initiator is decomposed, free radicals are generated, the resin is reacted, and the film is instantly cured. [0003] The main components of the existing UV paint are composed of photosensitive resin, active diluent, photoinitiator and auxiliary agent. The coating uses high-energy ultraviolet light as the curing energy, and the photoinitiator in the coating absorbs the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D175/14C09D5/22C09D5/33
CPCC08L2201/08C09D5/004C09D5/22C09D175/14C08L1/14C08K9/10
Inventor 刘水泉
Owner 漳州市和兴涂料有限公司
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