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Tunable infrared transparent conductive film with photovoltaic function and preparation method thereof

A technology of transparent conductive film and transparent conductive layer, which is applied in photovoltaic power generation, semiconductor/solid-state device manufacturing, circuits, etc., can solve the problems of single function of infrared transparent conductive film and low transmittance in the infrared region of electrodes, and achieve effective photovoltaic power generation function, increase the range of options, and solve the effect of a single function

Inactive Publication Date: 2020-04-10
CHANGCHUN INST OF OPTICS FINE MECHANICS & PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] In order to solve the problem of low transmittance in the infrared region of the traditional ITO electrode and the single function of the traditional infrared transparent conductive film, the present invention provides a tunable infrared transparent conductive film with photovoltaic function and its preparation method, which is the application of the infrared transparent conductive film Field expansion provides new ideas

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  • Tunable infrared transparent conductive film with photovoltaic function and preparation method thereof
  • Tunable infrared transparent conductive film with photovoltaic function and preparation method thereof
  • Tunable infrared transparent conductive film with photovoltaic function and preparation method thereof

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preparation example Construction

[0041] The steps of the preparation method of the tunable infrared transparent conductive film with photovoltaic function of the present invention are as follows:

[0042] Step 1), preparing an infrared transparent conductive layer 2 on a flat substrate 1;

[0043] Step 2), preparing a photovoltaic functional layer 3 on the infrared transparent conductive layer 2;

[0044] Step 3), preparing a tunable infrared transparent conductive layer 4 on the photovoltaic functional layer 3;

[0045] The material of the infrared transparent conductive layer 2 is an indium cerium oxide transparent conductive film.

[0046] The material of the photovoltaic functional layer 3 is organic or perovskite material.

[0047] The material of the tunable infrared transparent conductive layer 4 is a multilayer transparent conductive film with a dielectric / metal / dielectric structure.

[0048] Specifically, the preparation method of the tunable infrared transparent conductive film with photovoltaic fu...

Embodiment 1

[0063] 1) Put the cleaned 1 mm thick glass plane substrate together with the strip mask into the electron beam vacuum coating equipment, and vacuumize it. When the vacuum degree is 2×10 -3 Pascal, set the substrate temperature to 300°C, adjust the ion source argon-oxygen pressure ratio to 2:1, evaporate at a rate of 0.5 nm / s, and evaporate an infrared transparent conductive layer of 150 nm indium cerium oxide transparent conductive film, wherein the content of cerium is 5 %.

[0064] 2) After the evaporation is completed and the substrate is cooled, take it out and place it in the ultraviolet ozone treatment equipment for 5 minutes. Then take it out and transfer it to the glove box, and place it on the bracket of the spin coater, drop the stirred organic solution evenly on the above-mentioned substrate, adjust the spin coater speed to 1000 rpm, and spin coat for 1 minute to obtain 80 The nanometer-thick photovoltaic functional layer was placed on a hot stage in a glove box an...

Embodiment 2

[0069] 1) Put the cleaned 1 mm thick glass plane substrate together with the strip mask into the electron beam vacuum coating equipment, and vacuumize it. When the vacuum degree is 2×10 -3 Pascal, set the substrate temperature to 300°C, adjust the ion source argon-oxygen pressure ratio to 2:1, evaporate at a rate of 0.5 nm / s, and evaporate an infrared transparent conductive layer of 150 nm indium cerium oxide transparent conductive film, wherein the content of cerium is 5 %.

[0070] 2) After the evaporation is completed and the substrate is cooled, take it out and place it in the ultraviolet ozone treatment equipment for 5 minutes. Then take it out and transfer it to the glove box, and place it on the bracket of the spin coater, drop the stirred organic solution evenly on the above-mentioned substrate, adjust the spin coater speed to 1000 rpm, and spin coat for 1 minute to obtain 80 The nanometer-thick photovoltaic functional layer was placed on a hot stage in a glove box an...

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Abstract

The invention provides a tunable infrared transparent conductive film with a photovoltaic function and a preparation method thereof. According to the invention, an indium cerium oxide transparent conductive film with high infrared transmittance is used as an infrared transparent conductive layer; a medium / metal / medium structure multilayer transparent conductive film is used as a tunable infrared transparent conductive layer, and an organic or perovskite material is used as a photovoltaic functional layer, so that the tunable infrared transparent conductive film capable of photovoltaic power generation is realized. By changing the structure of the medium / metal / medium multilayer structure transparent conductive film, the transmittance of an infrared region is effectively adjusted, so that the problem that a traditional infrared transparent conductive film is single in function is solved, the transmittance of the infrared transparent conductive film can be regulated and controlled according to specific requirements, and therefore the selectable range of the infrared transmission wavelength is widened.

Description

technical field [0001] The invention relates to the technical field of transparent conductive film materials, in particular to a tunable infrared transparent conductive film with photovoltaic function and a preparation method thereof. Background technique [0002] Transparent conductive film is an important photoelectric functional film, which is widely used in liquid crystal display, organic light emitting diode, touch screen, thin film solar cell and other fields. The most commonly used and commercialized transparent conductive film is indium tin oxide (ITO) film, which has high visible light transmittance and low resistivity, and is often used in organic solar cells and organic light-emitting diodes. And other optoelectronic devices as transparent electrodes. However, the transmittance of traditional ITO thin films drops sharply in the near-infrared region (0.7-2.5 μm), especially in the range of 1.5-2.5 μm, which cannot meet the requirements of transparent electrodes fo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/42H01L51/44H01L51/48
CPCH10K30/15H10K30/82Y02E10/549
Inventor 郭晓阳刘星元
Owner CHANGCHUN INST OF OPTICS FINE MECHANICS & PHYSICS CHINESE ACAD OF SCI