Method of rapidly achieving therapeutic concentrations of zolmitriptan for treatment of migraines and cluster headaches
A delivery system and coating technology, applied in the field of zolmitriptan and triptan delivery
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Embodiment 1
[0221] Example 1 - Zolmitriptan Coating Formulation, Characterization and Physical Properties
[0222] Zolmitriptan is a weak base with a pKa of 9.6. Solubility measurements were performed by adding excess zolmitriptan base to 0.5 ml of 0.1 M acid and rotating the suspension overnight at 2 to 8 °C. The suspension is then centrifuged. The supernatant was then collected and the concentration of dissolved zolmitriptan was subsequently determined. Table 2 presents the solubility results of zolmitriptan in various acids.
[0223] Table 2: Solubility of zolmitriptan in various acids at 2 to 8 °C
[0224] water solvent Solubility (mg / mL) citric acid 88.6 tartaric acid 63.3 maleic acid 50.5 Succinic acid 59.1 HCl 33.3 Deionized water 1.3
[0225] Zolmitriptan exhibits good solubility in various acids. It was noted that the rheological behavior of the zolmitriptan solution was affected by the counterion in the formulation used fo...
Embodiment 2
[0256] Example 2——Ex vivo human skin
[0257]The ex vivo Franz human skin finite dose model is a tool for studying transdermal absorption of topically applied drugs. The model uses isolated human torso skin mounted in a specially designed diffusion cell that maintains the skin at a temperature and humidity matching typical in vivo conditions. A limited dose (eg, 2 mg / cm 2 to 10mg / cm 2 A formulation of a semisolid, or transdermal delivery system) is applied to the outer surface of the skin, and drug absorption is measured by monitoring its rate of emergence in a receptor solution submerged on the inner surface of the skin. Data defining total absorption, absorption rate, and skin content can be determined in this model.
[0258] medication. The zolmitriptan patch was applied to ex vivo skin using an applicator. Immediately after dosing, the patch and skin were mounted on the Franz diffusion cell.
[0259] Dermal receptor medium. Standard phosphate buffered saline (pH 7...
Embodiment 3
[0283] Embodiment 3——M207 patch stability
[0284] The M207 patch assembly was irradiated by e-beam and gamma radiation at doses up to 25 kGy. The subsequently irradiated patch assembly was placed stably under storage conditions of 25°C / 60%RH and 40°C / 75%RH. Results for the e-beam and gamma irradiated M207 patches are shown in Tables 11-17.
[0285] Table 11: Purity of non-irradiated and e-beam irradiated zolmitriptan patches stored at 25°C / 60%RH and 40°C / 75%RH (L / N 203149)
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[0288] Table 12: ZP-Zolmitriptan content of non-irradiated and e-beam irradiated zolmitriptan patches stored at 25°C / 60%RH and 40°C / 75%RH (L / N 203149)
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[0290]
[0291] Table 13: Purity of gamma irradiated zolmitriptan patches stored at 25°C / 60%RH and 40°C / 75%RH (L / N203154)
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[0293] Table 14: ZP-Zolmitriptan content of non-irradiated and gamma-irradiated zolmitriptan patches stored at 25°C / 60%RH and 40°C / 75%RH (L / N 203154)
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